合成吡啶类化合物用催化剂的再生行为研究

对合成吡啶类化合物用的失活催化剂上的结焦物进行了元素分析 ,并着重对失活催化剂的再生行为进行了研究。得到了不同失活程度催化剂的再生曲线及相同失活程度、不同再生条件下的再生曲线。经回归求得了一简单的再生反应动力学经验方程式 ,其中反应级数为碳含量的 1.16 5级 ,活化能为 4 2 .5 72kJ/mol,计算值与实验值的平均相对误差为 6 .5 %。     

Steric requirements for coal swelling by amine bases

A set of six coals ranging in rank from lignite to hvA bituminous was swollen with a series of alkyl-substituted pyridines and a smaller set of 4-alkylanilines. The size and branching of the alkyl groups was varied and the effect of this variation on the dissolution of the amines in the coal and the resulting coal swelling was measured volumetrically. In a few cases, substituents which hindered the amine nitrogen were studied. The lignite and subbituminous coal have a much higher tolerance to branched, bulky groups than do the bituminous coals. The presence of tertiary groups in a solute strongly inhibits their dissolution in bituminous coals. Bituminous coals behave as if extensive parallel packing of structures occurs. Often, they can accept very large planar groups but have a low capacity for branched groups.     

大变量逻辑函数最佳覆盖问题研究

逻辑函数的最佳覆盖，一直是逻辑综合领域的关键环节。尤其是大变量逻辑函数最佳覆盖，对复杂的逻辑综合更为重要，但也更加困难。本文在对逻辑覆盖算法研究的基础上，提出了适合大变量逻辑函数最佳覆盖的Beister改进算法。经过大量算题的测试表明，改进的列覆盖算法在时间复杂度和选择效果方面均优于Beister算法。     

The influence of various reaction parameters on the performance of (α‐diimine)nickel(II) catalysts in ethylene oligomerization reactions

Modified (α‐diimine)nickel(II) catalysts are suitable for ethylene oligomerization reactions. Due to the mechanism (“chain running”), the formation of double‐bond isomers and branched olefins can be observed. The obtained oligomer mixtures show a Schulz–Flory distribution. Increasing ethylene pressure favors the selectivity of α‐olefin formation. The same effect can be observed when Lewis bases like thiophene or furane are added to the oligomerization reaction mixture. These results can be related to an interaction of the additives with the catalytic active species during the oligomerization process. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1356–1361, 2003     

水中爆炸加载金属套管胀形的研究

本文运用爆炸动力学对水中爆炸加载金属套管胀形进行了力学分析，得出了井上与井下的药量关系。具有一定的实用价值。     

基于小波基优化和动态比特分配的数字音频压缩编码方案

提出了一种新颖的基于自适应小波基优化选择和心理声学模型相结合的数字音频信号的透明质量编码方法，保证固定失真水平上使每帧信号的变换系数的动态分配的比特数最少，并且利用动态码本的方法来消除音频信号的统计冗余，进一步压缩比特率，对于抽样率为４４．１ｋＨｚ每样值用１６比特线性码表示的光盘单声道音乐信号可以压缩到６４ｋＢＰＳ左右。     

A computational study of LP-based heuristic algorithms for two-dimensional guillotine cutting stock problems

In this paper we develop and compare several heuristic methods for solving the general two-dimensional cutting stock problem. We follow the Gilmore-Gomory column generation scheme in which at each iteration a new cutting pattern is obtained as the solution of a subproblem on one stock sheet. For solving this subproblem, in addition to classical dynamic programming, we have developed three heuristic procedures of increasing complexity, based on GRASP and Tabu Search techniques, producing solutions differing in quality and in time requirements. In order to obtain integer solutions from the fractional solutions of the Gilmore-Gomory process, we compare three rounding procedures, rounding up, truncated branch and bound and the solution of a residual problem. We have coded and tested all the combinations of algorithms and rounding procedures. The computational results obtained on a set of randomly generated test problems show their relative efficiency and allow the potential user to choose from among them, according to the available computing time. Rceived: January 9, 2001 / Accepted: December 10, 2001     

Synthesis and Spectral Properties of Mixed-Ligand Complexes of Lanthanide Perchlorate with Bis-(phenylsulfinyl)ethane and Organic Lewis Bases

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A branch-and-price algorithm to solve the molten iron allocation problem in iron and steel industry

The molten iron allocation problem (MIAP) is to allocate molten iron from blast furnaces to steel-making furnaces. The allocation needs to observe the release times of the molten iron defined by the draining plan of the blast furnaces and the transport time between the iron-making and steel-making stages. Time window constraints for processing the molten iron must be satisfied to avoid freezing. The objective is to find a schedule with minimum total weighted completion time. This objective reflects the practical consideration of improving steel-making efficiency and reducing operation cost caused by the need for reheating. Such a problem can be viewed as a parallel machine scheduling problem with time windows which is known to be NP-hard. In this paper, we first formulate the molten iron allocation problem as an integer programming model and then reformulate it as a set partitioning model by applying the Dantzig–Wolfe decomposition. We solve the problem using a column generation-based branch-and-price algorithm. Since the subproblem of column generation is still NP-hard, we propose a state-space relaxation-based dynamic programming algorithm for the subproblem. Computational experiments demonstrate that the proposed algorithm is capable of solving problems with up to 100 jobs to optimality within a reasonable computation time.     

Characteristics of the reactive distillation column with a novel internal

A new catalyst loading method, in which catalyst particles are packed in a reactor with a novel internal, has been studied by measuring pressure drop, RTD, liquid holdup and mass transfer. It can be inferred from experimental results that the internal changes the conventional gas and liquid counter-current flow into a new cross-current flow, so the problems of excessive pressure drop and “flooding” are avoided. When pressure drop, liquid holdup, RTD and mass transfer coefficient are similar, the catalyst loading fraction of the new method is much higher than that of conventional methods. Furthermore, the reactive distillation reactor with the novel internal has advantages such as simple structure, low operating cost, and convenience for installation and removal of the catalyst.