Process Intensification of Living Cationic Polymerization of Isobutylene by a Flow Reaction System

Increasing the reaction temperature of the living cationic polymerization of isobutylene is crucial for industrial production due to the cost of refrigeration. The reaction temperature increase was achieved with an accelerated reaction rate using a flow reaction system. The polymerization conditions, including the flow reactor design, were based on the results of kinetic studies. Utilizing a milli‐scale flow reactor, polyisobutylene, which has a narrow molecular weight distribution, was obtained within a considerably short residence time at a high temperature. Furthermore, it was confirmed that the value of M_w/M_n correlates with the product of the Reynolds number and the angle of collision.     

非线性编辑实验室的构建与实验教学

以计算机为操作平台的非线性编辑系统广泛应用于电视节目的制作 ,学校相关专业开设非线性编辑课程也需要配置非线性编辑系统作为学生实验用机。主要介绍一种学生实验用非线性编辑系统及实验室的配置方案以及该非线性编辑系统在实验教学中的性能特征。     

~(131)I-Lym-2单克隆抗体实验研究

不同浓度的~(131)I-Lym-2 MoAb与ARH-77和CEM细胞进行结合试验,结果表明:随浓度增大,结合值均升高;实验组裸鼠模型9只获得动力学数据。实验组和对照组注射~(131)I-Lym-2 MoAb后144h解剖,进行生物学分布(％D/g)测定,实验组肿瘤为16.88±12.64,肌肉为0.72±0.56。结果表明,~(131)I-131-Lym-2MoAb对临床B细胞淋巴瘤的放射免疫分析、显像有良好的效果。     

舰船导航信号发生器虚拟化设计

介绍了基于PC总线的便携式舰船导航信号发生器虚拟化设计，着重叙述该仪器硬件设计、基于虚拟仪器开发平台LabWindows／CVI的软件设计。     

生活污水用于园林绿化的实验

通过对11种在天津石化公司有代表性的绿化植物10年来应用生活污水的跟踪调查及进行的相关实验证明,直接应用生活污水浇灌绿化植物,对绿化植物生长及对环境造成的负面影响不大.根据实验结果认为,生活污水可以有条件地用于园林绿化,并应注意密切跟踪调查.     

城市生活性街道的空间营造——以天津市鞍山道北段为例

生活性街道是城市居民在城市生活中不可缺少的场所。文章以天津市和平区鞍山道北段为例,通过实地详细调研,运用街道空间理论分析其空间结构、细部要素及市民活动,探讨如何才能营造出宜人的城市生活性街道环境。     

基于Web的高职院校实训室管理系统的设计与实现

讨论实训室管理系统的设计目标．利用Struts＋Spring＋Hibernate技术架构对其进行设计与实现,并给出系统的功能设计、体系结构设计和数据库设计。通过上述J2EE架构实现的实训室管理系统具有较好的扩展性、稳定性和良好的用户体验。     

The application of ionizing radiation in reversible addition-fragmentation chain transfer (RAFT) polymerization: Renaissance of a key synthetic and kinetic tool

Ionizing radiation, such as γ, ultraviolet, microwave and X-ray radiation, has long been used in polymer chemistry as a means of initiating polymerization, crosslinking gels and decomposing particular polymer components. More recently, ionizing radiation has found application in tandem with living radical polymerization to form novel polymeric materials with defined molecular weight and narrow molecular weight distribution. In particular, γ-rays and ultraviolet light both have shown promise as sources of initiation in reversible addition-fragmentation chain transfer (RAFT) polymerization. The ability to apply these sources of initiation at low temperatures is useful in applications where elevated temperature is likely to be detrimental to the system, for instance, in preparing protein-polymer conjugates. Similarly, the use of these initiating sources at low temperature is particularly suitable for some monomers, such as allyl compounds, which have not been synthesized using any other living radical approach. The current review examines the development of ionizing radiation as a tool in RAFT polymerization, with particular reference to the elucidation of the polymerization mechanism, the synthesis of high functionality polymers and probing the kinetic parameters of the RAFT process.     

The beneficial effect of small amount of water in the ambient temperature atom transfer radical homo and block co-polymerization of methacrylates

ATRP of several methacrylates viz. methyl methacrylate (MMA), ethyl methacrylate (EMA), n-butyl methacrylate (nBMA), t-butyl methacrylate (tBMA), benzyl methacrylate (BzMA) and (N,N-dimethylamino)ethyl methacrylate (DMAEMA) has been studied in neat as well as aqueous (up to 12 vol% water) acetone at 35 °C using CuCl/bipyridine (bpy) catalyst and ethyl 2-bromoisobutyrate as the initiator. Addition of water significantly enhances the rate of polymerization without losing control. Unlike CuCl/bpy the CuBr/bpy catalyst gives poor control which is attributed to the lower solubility and consequent heterogeneity in the latter case. Of the other ligands used with the CuCl catalyst viz. o-phenanthroline (o-phen), 1,1,4,7,7-pentamethyldiethylenetriamine (PMDETA), 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA), Me₆TREN only o-phen offers reasonably good control. The CuCl/bpy catalyst system has been used also in preparing some di- and tri-block copolymers with reasonably low polydispersity index (PDI) at ambient temperature (35 °C) using aqueous acetone as the solvent. The following block copolymers have been prepared PMMA-tBMA, PMMA-b-tBMA-b-MMA, PMMA-DMAEMA, by this method.     

Synthesis of well-defined poly(styrene)-b-poly(p-tert-butoxystyrene) multiblock copolymer from poly(alkoxyamine) macroinitiator

The stepwise insertion reaction of styrene (St) and p-tert-butoxystyrene (BOSt) into poly(alkoxyamine) macroinitiator was carried out to provide well-defined poly(St)-b-poly(BOSt) multiblock copolymers. Structural confirmation of the multiblock copolymers was accomplished by NMR and IR measurements. The model reaction also supported that the monomer insertion into the macroinitiator proceeded in accordance with a living fashion.