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1.
《Ceramics International》2022,48(13):18793-18802
The luminescence center energy transfer, crystal field strength, and covalency are limited by the crystal structure of the host and subsequently affect the luminescence efficiency, color, and intensity. Here, we report an excellent red phosphor BaLaLiWO6:0.40Eu3+ and the dependence between symmetry and luminous performance. A model for changing symmetry is drawn by analyzing the Coulomb potential and structure for the application of a double-perovskite phosphor BLLWO: Dy3+, Eu3+ in white light LEDs. The addition of Dy3+/Eu3+ makes the W-O bond formed by the B-site and oxygen ion longer and the Li-O bond shorter, and the difference between the eight octahedral around the A-site is reduced, increasing the symmetry of the A-site. Local symmetry was successfully modulated by changing the Eu3+ concentration to control the Y/B ratio of Dy3+ and the R/O ratio of Eu3+ and smoothly achieved (0.382, 0.373) warm white light color coordinate. The phosphor has excellent thermal stability and still has 92.3% intensity at 475 K. The above results show that the wavelength composition of the luminescence is tunable by changing the symmetry of the environment in which the doped ions are located. It applies to single hosts for the regulation of white light emission. 相似文献
2.
The ways in which environmental priorities are framed are varied and influenced by political forces. One technological advance--the proliferation of government open data portals (ODPs)--has the potential to improve governance through facilitating access to data. Yet it is also known that the data hosted on ODPs may simply reflect the goals and interests of multiple levels of political power. In this article, I use traditional statistical correlation and regression techniques along with newer natural language processing and machine learning algorithms to analyze the corpus of datasets hosted on government ODPs (total: 49,066) to extract patterns that relate scales of governance and political liberalism/conservatism to the priorities and meaning attached to environmental issues. I find that state-level and municipal-level ODPs host different categories of environmental datasets, with municipal-level ODPs generally hosting more datasets pertaining to services and amenities and state-level ODPs hosting more datasets pertaining to resource protection and extraction. Stronger trends were observed for the influences of political conservatism/liberalism among state-level ODPs than for municipal-level ODPs. 相似文献
3.
4.
In different computer models, shape is represented using different methodologies, to varying degrees of precision. This paper examines two approaches to shape representation, and their effects on accuracy in the context of cylindrical particle packing. Two discrete element method (DEM) based software packages are used. A X-ray CT scan of a packed bed provides the experimental measurements for comparison. Eight sphere-composite representations of the same cylindrical pellet were tested. Two of these gave results that quantitatively follow experimental measurements. A range of factors that in theory could affect accuracy of the simulation results are examined, including edge roundedness, surface roughness and restitutional behaviour as a function of sphere-composite representations. The conclusion is that, for packing at least, matching the object's overall shape and dimensions is not enough. Only when a high enough resolution is applied to corners and edges, could the sphere-composite approach possibly match the experimental data quantitatively. 相似文献
5.
The Vehicle Routing Problem with Simultaneous Pickup and Delivery (VRPSPD) is an extension to the classical Vehicle Routing Problem (VRP), where customers may both receive and send goods simultaneously. The Vehicle Routing Problem with Mixed Pickup and Delivery (VRPMPD) differs from the VRPSPD in that the customers may have either pickup or delivery demand. However, the solution approaches proposed for the VRPSPD can be directly applied to the VRPMPD. In this study, an adaptive local search solution approach is developed for both the VRPSPD and the VRPMPD, which hybridizes a Simulated Annealing inspired algorithm with Variable Neighborhood Descent. The algorithm uses an adaptive threshold function that makes the algorithm self-tuning. The proposed approach is tested on well-known VRPSPD and VRPMPD benchmark instances derived from the literature. The computational results indicate that the proposed algorithm is effective in solving the problems in reasonable computation time. 相似文献
6.
Combination of X-ray Digital Industrial Radiography (DIR) and Particle Tracking Velocimetry (PTV) techniques for local liquid velocity measurement (VLL) has been newly developed and successfully applied for trickle bed reactor (TBR). The technique was validated against newly developed fiber optical probe technique. This work attempts to highlight the applicability of this newly developed technique on a liquid–solid packed bed reactor. In this work, liquid was represented by water and solids were represented by EPS beads. The EPS beads were chosen because of its low density property. Three superficial liquid velocities (VSL) were applied to the system. The experiment was replicated four times. The digital industrial radiography (DIR) consists of a complementary metal oxide semiconductor (CMOS) digital detector and X-ray source. Results of this work suggest that the technique has been successfully applied and comparable with previous work that has been done in the literature. It also suggests that there will be a maximum measurable interstitial liquid velocity when it travel inside the packed bed. The measured VLL can have a maximum range that is between 4 and 4.7 times that of its VSL. For VSL=0.42±±2%, the VLL-Max is in between 1.7 cm/s and 1.9 cm/s, VSL=0.84±±2%, the VLL-Max is in between 3.6 cm/s and 4.0 cm/s, and for VSL=1.11±±2%, the VLL-Max is in between 4.3 cm/s and 4.8 cm/s. 相似文献
7.
The paper considers the problem of stabilization of systems possessing a multiple zero eigenvalue at the origin. The controller that we propose, uses multiple delayed measurements instead of derivative terms. Doing so, we increase the performances of the closed loop in presence of system uncertainties and/or noisy measurements. The problem formulation and the analysis is presented through a classical engineering problem which is the stabilization of an inverted pendulum on a cart moving horizontally. On one hand, we perform a nonlinear analysis of the center dynamics described by a three dimensional system of ordinary differential equations with a codimension-three triple zero bifurcation. On the other hand, we present the complementary stability analysis of the corresponding linear time invariant system with two delays describing the behavior around the equilibrium. The aim of this analysis is to characterize the possible local bifurcations. Finally, the proposed control scheme is numerically illustrated and discussed. 相似文献
8.
Lake Chivero: A management case study 总被引:1,自引:0,他引:1
C. H. D. Magadza 《Lakes & Reservoirs: Research and Management》2003,8(2):69-81
Lake Chivero in Zimbabwe was shown to be hypereutrophic. Historical data showed that the eutrophication process had been arrested in the late 1970s. However, a combination of poor planning, multiplicity of jurisdiction, mismatch between rate of urbanization and waste management investment, recent changes in the local climate and a permissive, immature political system that called for no public accountability resulted in environmental management breakdown leading to hypereutrophication of the lake. The case of Lake Chivero is presented as an example of a wider global issue regarding the status of environmental management in competition with other priorities in emerging democracies. 相似文献
9.
Quality of service (QoS) support for multimedia services in the IEEE 802.11 wireless LAN is an important issue for such WLANs
to become a viable wireless access to the Internet. In this paper, we endeavor to propose a practical scheme to achieve this
goal without changing the channel access mechanism. To this end, a novel call admission and rate control (CARC) scheme is
proposed. The key idea of this scheme is to regulate the arriving traffic of the WLAN such that the network can work at an
optimal point. We first show that the channel busyness ratio is a good indicator of the network status in the sense that it
is easy to obtain and can accurately and timely represent channel utilization. Then we propose two algorithms based on the
channel busyness ratio. The call admission control algorithm is used to regulate the admission of real-time or streaming traffic
and the rate control algorithm to control the transmission rate of best effort traffic. As a result, the real-time or streaming
traffic is supported with statistical QoS guarantees and the best effort traffic can fully utilize the residual channel capacity
left by the real-time and streaming traffic. In addition, the rate control algorithm itself provides a solution that could
be used above the media access mechanism to approach the maximal theoretical channel utilization. A comprehensive simulation
study in ns-2 has verified the performance of our proposed CARC scheme, showing that the original 802.11 DCF protocol can
statically support strict QoS requirements, such as those required by voice over IP or streaming video, and at the same time,
achieve a high channel utilization.
Hongqiang Zhai received the B.E. and M.E. degrees in electrical engineering from Tsinghua University, Beijing, China, in July 1999 and January
2002 respectively. He worked as a research intern in Bell Labs Research China from June 2001 to December 2001, and in Microsoft
Research Asia from January 2002 to July 2002. Currently he is pursuing the PhD degree in the Department of Electrical and
Computer Engineering, University of Florida. He is a student member of IEEE.
Xiang Chen received the B.E. and M.E. degrees in electrical engineering from Shanghai Jiao Tong University, Shanghai, China, in 1997
and 2000, respectively, and the Ph.D. degree in electrical and computer engineering from the University of Florida, Gainesville,
in 2005. He is currently a Senior Research Engineer at Motorola Labs, Arlington Heights, IL. His research interests include
resource management, medium access control, and quality of service (QoS) in wireless networks. He is a Member of Tau Beta
Pi and a student member of IEEE.
Yuguang Fang received a Ph.D degree in Systems and Control Engineering from Case Western Reserve University in January 1994, and a Ph.D
degree in Electrical Engineering from Boston University in May 1997.
From June 1997 to July 1998, he was a Visiting Assistant Professor in Department of Electrical Engineering at the University
of Texas at Dallas. From July 1998 to May 2000, he was an Assistant Professor in the Department of Electrical and Computer
Engineering at New Jersey Institute of Technology. In May 2000, he joined the Department of Electrical and Computer Engineering
at University of Florida where he got the early promotion with tenure in August 2003 and has been an Associate Professor since
then. He has published over one hundred (100) papers in refereed professional journals and conferences. He received the National
Science Foundation Faculty Early Career Award in 2001 and the Office of Naval Research Young Investigator Award in 2002.
He is currently serving as an Editor for many journals including IEEE Transactions on Communications, IEEE Transactions on
Wireless Communications, IEEE Transactions on Mobile Computing, and ACM Wireless Networks. He is also actively participating
in conference organization such as the Program Vice-Chair for IEEE INFOCOM’2005, Program Co-Chair for the Global Internet
and Next Generation Networks Symposium in IEEE Globecom’2004 and the Program Vice Chair for 2000 IEEE Wireless Communications
and Networking Conference (WCNC’2000). 相似文献
10.