Theoretical investigation of solvent effects on the selective hydrogenation of furfural over Pt(111)

It was well known that solvent effect plays a very important role in the catalytic reaction. There are many theoretical studies on the solvent effect in homogeneous catalysis while there are few theoretical studies on the solvent effect in the heterogeneous catalytic reaction and there has been no work to investigate the solvent effect on furfural transformation in heterogeneous catalysis. In the present work, both the density functional calculations and the microkinetic analysis were performed to study the selective hydrogenation of furfural over Pt(111) in the presence of methanol as well as toluene and compared with that in the gas condition. The present results indicated that the methanol can enhance the adsorption strength of furfural and other oxygen-containing reaction species due to its relatively strong polarity properties and this can be a main reason for solvent-induced high activity and selectivity. Another reason is that reaction paths study showed that the presence of methanol solvent makes the dehydrogenation of furfural less thermochemical due to the fact that furfural is more stabilized than that of dehydrogenation species, and methanol also has an inhibition effect on the dehydrogenation of furfural in the kinetic aspect, and further energetic span theory proves highest activity and selectivity for hydrogenation in methanol solvent of vapor, methanol and toluene. Moreover, microkinetic model simulation demonstrated that the activity and selectivity of hydrogenation in methanol is both higher than that in vapor and toluene. The much higher activity in methanol is due to the stabilized adsorbed reactants in the surface, which leads to a higher surface coverage of furfural. It might be proposed based on the present work that a solvent with relatively strong polarity may be favorable for the high selective hydrogenation of furfural.     

土木工程施工课程线上平台教学实践

土木工程施工课程作为土木工程及工程管理专业的学科基础课和核心专业课程,在疫情防控期间"停课不停教""停课不停学"的要求下,通过线上平台进行授课。由于土木工程施工课程内容庞杂、综合性强、实践性强,且章节之间关联性较弱,探究既能使学生快速适应,又能保证教学质量的在线教学方法至关重要。以华南某高校土木工程施工课程为例,基于中国大学MOOC、建筑云课、腾讯课堂、QQ群等线上平台讲授教学内容,并运用问卷调查对课程线上教学效果进行评价。结果表明,线上教学为学生提供了丰富灵活的学习方式,显著提高了学生的自主学习能力,扩大了学生的知识面,达到了较好的学习效果。     

Tuning effect of silicon substitution on magnetic and high frequency electromagnetic properties of R2Fe17 and their composites

In this work, we report the tuning effect of the Si substitution on the magnetic and high frequency electromagnetic properties of R₂Fe₁₇ compounds and their paraffin composites. It is found that the introduction of Si can remarkably improve the magnetic and electromagnetic properties of the R₂Fe₁₇ compounds, making the R₂Fe_17–xSi_x-paraffin composites excellent microwave absorption materials (MAMs). By introducing the Si element, their saturation magnetizations decrease slightly, while much higher Curie temperatures are obtained. Furthermore, better impedance match is reached due to the decrease of the high-frequency permittivity ε′ by about 40%–50%, which finally enhances the performance of the microwave absorption. The peak frequency (f_RL) of the reflection loss (RL) curve moves toward high frequency domain and the qualified bandwidth (QB, RL ≤ ?10 dB) increases remarkably. The maximum QB of 3.3 GHz (12.0–15.3 GHz) is obtained for the Sm_1.5Y_0.5Fe₁₅Si₂-paraffin composite (d = 1.0 mm) and the maximum RL of ?53.6 dB is achieved for Nd₂Fe₁₅Si₂-paraffin composite (d = 2.2 mm), both surpassing most of the reported MAMs. Additionally, a distinguished dielectric microwave absorption peak is observed, which further increases the QB in these composites.     

Alpha induced reactions on Sn: An experimental study of excitation functions and possible production pathways

In the frame of a systematic study of light ion induced threshold reactions on natural tin (Sn) excitation functions for alpha particles induced reactions are presented in a 12–38 MeV energy domain. Using a stacked foil activation method the following radioisotopes were identified: ¹¹⁶Te, ¹¹⁷Te, ¹¹⁸Te, ¹¹⁹Te, ¹²¹Te, ¹²³Te, ¹¹⁷Sb, ¹¹⁸Sb, ¹²⁰Sb, ¹²²Sb, ¹²⁴Sb, ¹²⁶Sb, ¹¹⁷Sn, ¹¹¹In. The experimental cross sections for these isotopes are presented for the first time in this energy range and a direct comparison with values calculated with the ALICE-IPPE code is discussed. Possible use of these data for production of some isotopes relevant in nuclear medicine is suggested.     

核磁共振谱的岩石孔喉结构分析

刘堂宴 ,王绍民 ,傅容珊 ,周明顺 ,李艳华 ,罗曼 .核磁共振谱的岩石孔喉结构分析 .石油地球物理勘探 ,2 0 0 3,38(3) :32 8～ 333岩心核磁共振 T2 谱和压汞分析数据均在一定程度上反映了岩石的孔喉结构 ,理论分析表明 ,这两组数据具有相关性。应用岩心核磁共振 T2 谱研究岩石孔喉结构 ,关键是确定 T2 与 Pc的转换系数。但以前的方法在 T2与 Pc 的转换过程中 ,需要涉及某些岩石特性参数 ,实用中有一定困难。本文直接利用岩心核磁共振 T2 谱和压汞分析数据之间的相关性 ,客观地确定 T2 与 Pc之间的转换系数 ,避免了确定岩石特性参数的困难。应用本文方法 ,对 6块岩心的多种核磁共振分析数据进行了对比分析 ,做出了 NMR (Nuclear Magnetic Resonance,简称NMR) T2 毛管力曲线和孔喉半径分布 ,并将这些结果与压汞分析的结果进行了对比。结果表明 ,岩心 NMR T2谱在实用性和评价精度上均略显优势 ;至少是在饱含油的条件下 ,岩心的 NMR T2 谱可以用于研究孔喉结构分布 ,油气的弛豫特性作为影响背景值存在 ,对于评价结果没有明显的影响 ;在全部 6块岩心中 ,T2 与 Pc 的转换系数位于 2 5 0 0～ 4 0 0 0μs· MPa之间。     

高校人事制度改革探讨

市场经济条件下高校人事制度改革是一项综合性的皋杂工作，涉及人事体制、人力资源配置、制度建设等多方面改革，本文阐述了改革的基本思路，并就如何实施进行了探讨。     

What are the key elements of a sustainable university?

Nowadays, the principles of sustainable development are becoming increasingly important and universities are acting as agents in promoting these principles within society. In the future, universities will inevitably play crucial role in propagating these principles. This paper highlights important documents and discusses definitions of the term education for sustainable development. Elements, based on continuous feedback loop (Deming spiral) are discussed, in order to incorporate sustainability principles into university activities. The University of Maribor has been used as a case study to test the effectiveness of the proposed integration of sustainable development principles.     

高校电视台节目漫谈

结合高校校园电视台的职能和特点 ,深刻剖析了高校电视台几种类型节目的特点以及对高校校园文化的作用。     

EFFECT OF HYDROGEN ON THE MICROSTRUCTURE OF SUPER-α2 ALLOY WITH β SOLUTION AND AGEING TREATMENT

借助透射电镜和Ｘ射线衍射仪探讨了氢对Ｓｕｐｅｒ－α２合金β固溶后时效组织的影响，结果表明，氢使时效组织显著细化，使析出相呈细小板条状规则排布，此外，氢还促进Ｂ２相转变为Ｏ相。     

Formation of uniform GaAs multi-atomic steps with 20–30 nm periodicity and related structures on vicinal (111)B planes by MBE

We studied morphology of GaAs surfaces and the transport properties of two-dimensional electron gas (2DEG) on vicinal (111)B planes. Multi-atomic steps (MASs) are found on the vicinal (111)B facet grown by molecular beam epitaxy, which will affect electron transport on the facet. We also studied how the morphology of GaAs epilayers on vicinal (111)B substrates depends on growth conditions, especially on the As₄ flux. The uniformity of MASs on the substrates have been improved and smooth surfaces were obtained when the GaAs was grown with high As₄ flux, providing step periodicity of 20 nm. The channel resistance of the 2DEG perpendicular to the MASs is reduced drastically with this smooth morphology. These findings are valuable not only for fabricating quantum devices on the (111)B facets but also those on the vicinal (111)B substrates.