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1.
《Advanced Powder Technology》2020,31(12):4585-4597
Focussing on visible light active ferrites for high performance removal of noxious pollutants, we report the synthesis of Mg0.5NixZn0.5-xFe2O4 (x = 0.1, 0.2, 0.3, 0.4, & 0.5) ferrite nanoparticle for degradation of reactive blue-19 (RB-19). Lattice parameters calculated using intense X-ray diffraction (XRD) peaks and Nelson-Riley plots (N-R plot) are in well agreement with each other. The sample Mg0.5Ni0.4Zn0.1Fe2O4 (M5N4) exhibits best performance with 99.5% RB-19 degradation in 90 min under visible light. Photoluminescence (PL) results confirm that recombination of charge carriers is highly reduced in the photocatalyst. Scavenging experiments suggest that O2− radicals were the dominant species responsible for photocatalytic performance. The photocatalytic mechanism was explained in terms of dopant driven shifting of conduction bands and valence bands (calculated by Mott-Schottky plots). The thermodynamic probability of radical generation along with role of redox cycles of metal ions has been discussed in the mechanism. The dye degradation was ascertained by detection of intermediates via mass spectrometry analysis and a possible degradation route was also predicted. The findings in this work provide intriguing opportunities to modify the electronic band structure of spinel ferrites for visible and solar light photocatalytic activity for environmental detoxification. 相似文献
2.
Hoang V. Le Phuong T. Pham Ly T. Le Anh D. Nguyen Ngoc Quang Tran Phong D. Tran 《International Journal of Hydrogen Energy》2021,46(44):22852-22863
WO3 is a potential material candidate for construction of photoanode for solar driven water splitting. In this work, μm-thick porous WO3 photoanode is prepared by depositing a stable ink made of WO3 nanoparticles and Aristoflex velvet polymer in water using the doctor blade technique, followed by a sintering in air. The nature of WO3 nanoparticles, its loading mass on F-doped tin oxide electrode as well as sintering temperature are examined in order to optimize the photocatalytic activity of the resultant WO3 photoanode. The operation of WO3 photoanode is investigated by varying the light illumination direction and light incident intensity as well as changing the nature of the electrolyte. Dissolved tungsten in electrolyte is quantified by ICP-MS providing insights into the influences of electrolyte nature and operating conditions to the corrosion of WO3. It is proposed that the H2O2 and OH. radical generated as by-products of the photo-driven water oxidation on the photoanode surface are harmful species that accelerate the dissolution of WO3. 相似文献
3.
K.M. Srinivasamurthy Jagadeesha Angadi V S.P. Kubrin Shiddaling Matteppanavar D.A. Sarychev P. Mohan Kumar Haileeyesus Workineh Azale B. Rudraswamy 《Ceramics International》2018,44(8):9194-9203
Ferrites may contain single domain particles which gets converted into super-paramagnetic state near critical size. To explore the existence of these characteristic feature of ferrites, we have performed magnetization(M-H loop) and Mössbauer spectroscopic studies of Ni2+ substitution effect in Co1-xNixFe2O4 (where x?=?0, 0.25, 0.5, 0.75 and 1) nanoparticles were fabricated by solution combustion route using mixture of carbamide and glucose as fuels for the first time. As prepared samples exhibit spinel cubic structure with lattice parameters which decreases linearly with increase in Ni2+ concentration. The M-H loops reveals that saturation magnetization(Ms), coercive field(Hc) remanence magnetization(Mr) and magnetron number(ηB) decreases significantly with increasing Ni2+ substitution. The variation of saturation magnetization has been explained on the basis of Neel's molecular field theory. The coercive field(Hc) is found strongly dependent on the concentration of Ni2+ and decrease of coercivity suggests that the particles have single domain and exhibits superparamagnetic behavior. The Mössbauer spectroscopy shows two ferrimagnetically relaxed Zeeman sextets distribution at room temperature. The dependence of Mössbauer parameters such as isomer shift, quadru pole splitting, line width and hyperfine magnetic field on Ni2+ concentration have been discussed. Hence our results suggest that synthesized materials are potential candidate for power transformer application. 相似文献
4.
碱法造纸黑液驱油研究 总被引:2,自引:0,他引:2
在玻璃细珠充填柱人造岩心模型上进行了碱法造纸黑液驱替稠油的实验研究,考察了稠油酸值、盐、温度、岩心渗透率、注入量和注入方式的影响。在实验条件下碱法造纸黑液驱稠油的采收率较水驱提高25% 相似文献
5.
Microstructures of hundreds of micron thick poly(styrene-block-isoprene) copolymer films solution-cast in a cylindrical tube with the solvent evaporation controlled were investigated by transmission electron microscope (TEM), small angle X-ray scattering (SAXS) and optical microscope (OM). In a block copolymer with cylindrical polyisoprene microdomains, the orientation of the cylinders was varied along radial direction of the cylindrical tube. Highly aligned hexagonal arrays of in-plane polyisoprene cylinders were formed with their cylindrical axis parallel to the circumference of the tube in the regimes close to the wall edge. In contrast randomly ordered microdomains were observed at the center of the tube. We have also found that the orientation depends on the solvent evaporation rate and an intermediate rate (∼2.3 nL/s) provides the best orientation. In the case of a block copolymer with a bicontinuous double gyroid structure, we obtained a globally ordered microstructure where [111] crystallographic direction was parallel to the circumference of the tube. For both block copolymers, the area of highly ordered arrays of nanoscopic domains is over 1 mm2. Development of the orientation was explained by coupling two orthogonal fields: (1) The flow of a solution induced by strong capillary force at a meniscus between the cylindrical tube wall and the block copolymer solution and (2) the solvent evaporation. 相似文献
6.
岩盐钻井水溶双井连通开采工艺的研究与推广 总被引:1,自引:0,他引:1
文章就全国井矿盐采区多年的开采工艺技术,进行了系统的研究与总结,并提出了岩盐钻井水溶开采双井连通的各种开采工艺及其关键技术,具有很强的适用性和推广价值。 相似文献
7.
Mushroom-like ZnO microcrystals have been prepared via a solution calcination route, using Zn(NO3)2 as Zn source in the absence of any surfactants, templates or catalysts. This is the first example to prepare mushroom-like crystals as semiconductors, which are expected to show particular physical properties. The ZnO products were investigated by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy and photoluminescence (PL) spectrum measurements. A suitable concentration of Zn(NO3)2 solution was important for the growth of the mushroom-like products. The reported synthetic procedure is straightforward and inexpensive, and thus can be readily adopted to produce large quantities of mushroom-like ZnO microcrystals. 相似文献
8.
智能小区中的网络和布线设计解决方案——智能建筑学术讨论系列文章之七 总被引:1,自引:0,他引:1
当前小区信息网络建设中存在多种实施方案。笔者分析比较了常用的几种典型方案的优劣。讨论了目前建设中的一些解决方法,提出了兼顾现状,适度超前的设计实施原则。 相似文献
9.
固定化酵母粒子中生产乙醇的定态分岔行为研究 总被引:4,自引:0,他引:4
运用变分原理和打靶法将分布参数系统的非线性边值问题转化为集总参数系统的初值问题,基于延拓算法,研究了固定床中球形固定化酵母粒子表面乙醇和葡萄糖浓度随参数的变化关系,得出了单颗粒固定化酵母生产乙醇的多定态特性。结果表明:随系统尺度三的变化,方程出现分岔点;方程的解与液相主体浓度有关。在某些条件下酵母粒子表面浓度有三个定态:在多定态区域,随三的增加,方程一个解支的乙醇浓度迅速增加,从而可以在固定床中通过控制粒径而使反应器达到较高的产率。研究结果为固定床反应器的开工及控制提供了重要的理论依据。 相似文献
10.
本文介绍了VAc/BA/MMA三元共聚的两种方法,并通过实验证实:聚合方法对三元共聚物的粘接强度有明显的影响。 相似文献