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1.
Mitsuo Miyazawa Hideki Kawazoe Mitsuro Hyakumachi 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(6):620-625
The microbial transformation of l‐menthol ( 1 ) was investigated by using 12 isolates of soil‐borne plant pathogenic fungi, Rhizoctonia solani (AG‐1‐IA Rs24, Joichi‐2, RRG97‐1; AG‐1‐IB TR22, R147, 110.4; AG‐1‐IC F‐1, F‐4, P‐1; AG‐1‐ID RCP‐1, RCP‐3, and RCP‐7) as a biocatalyst. Rhizoctonia solani F‐1, F‐4 and P‐1 showed 89.7–99.9% yields of converted product from 1 , RCP‐1, RCP‐3, and RCP‐7 26.0–26.9% and the other isolates 0.1–12.0%. In the cases of F‐1, F‐4 and P‐1, substrate 1 was converted to (?)‐(1S,3R,4S,6S)‐6‐hydroxymenthol ( 2 ), (?)‐(1S,3R,4S)‐1‐hydroxymenthol ( 3 ) and (+)‐(1S,3R,4R,6S)‐6,8‐dihydroxymenthol ( 4 ), which was a new compound. Substrate 1 was converted to 2 and/or 3 by RRG97‐1, 110.4, RCP‐1, RCP‐3 and RCP‐7. The structures of the metabolic products were elucidated on the basis of their spectral data. In addition, metabolic pathways of the biotransformation of 1 by Rhizoctonia solani are discussed. Finally, from the main component analysis and the differences in the yields of converted product from 1 , the 12 isolates of Rhizoctonia solani were divided into three groups based on an analysis of the metabolites. Copyright © 2003 Society of Chemical Industry 相似文献
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基于Android平台与SMS技术,设计并实现了智能家居能量管理系统设计方案。在文中描述了该系统的总体设计框图、终端软件设计、智能电表设计、智能插座设计。对该系统进行了验证,实验结果表明,该方案能够快捷地实现对家居设备等能量消耗单元的控制,成本很低,适合入门者使用。 相似文献
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研究了工作流中时间分配问题。在具体活动基础上增加标记活动,以记录所在路由分支的资源使用情况; 将时间看作一种不可更新资源,并将时间资源分为私有资源、公有资源和双重资源三类; 提出了一种路由结构的时间资源分析方法和分配算法,根据不同路由分支的特点及初始分配资源在实际执行过程中的使用情况,通过裂变与聚合进行时间资源再分配,保证整个工作流的顺利完成。通过实例说明工作流图中时间资源分配过程。 相似文献
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文章中,我们分析了基于多波形的超宽带传输参考脉冲无线电系统的性能。在不考虑帧间干扰和多径干扰的情况下,我们得出了误符号率的闭式解。接着我们又讨论了多波形传输参考系统的抗帧间干扰能力。通过对比仿真结果,我们发现在有帧间干扰的环境中,多波形传输参考系统能够达到比单波形系统更好的误码率性能。 相似文献
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针对IDMA下行链路中用户端接收设备复杂度比较高的问题,提出了一种基于时分双工(TDD)模式和时间反转(TR)技术的IDMA下行传输及简化接收方法.该方法通过时分双工获得信道冲激响应,基站发射端利用信道冲激响应的时间反转预处理发射信号.在时间反转及多输入单输出(MISO)技术作用下,利用不同用户信道冲激响应之间的弱相关性以及时间反转处理的空间和时间压缩特性,削弱多用户干扰、共道干扰和符号间干扰.从而使用户接收端只需一个简单的单径接收机即可完成信号的检测,避免了复杂的码片级迭代多用户检测,同时将信道估计器也从用户端转移到基站端,进而使用户端接收设备复杂度大大简化. 相似文献
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This paper presents a new Transmitted Reference (TR) Ultra-WideBand (UWB) receiver based on Spatial Diversity (SD), which employs Multi-Antenna Technology (MAT) to improve the performance of TR-UWB receiver. According to the amplitude of correlator output of every antenna branch, this paper analyzed the performances of the proposed TR-UWB receiver employing three different kinds of combina-tion strategies, i.e., Maximum Ratio Combination (MRC), Equal Gain Combination (EGC), and Selective Combination (SC), which are different from conventional ones, and theoretically proved that the performance of EGC is better than MRC. Simulation results verify that when EGC is adopted and BER=10–3, increasing three antennas provides Signal to Noise Ratio (SNR) gain of about 3 dB in CM4 channel and SNR gain of about 2 dB in CM2 channel. 相似文献
10.
David F. Sanders Ruilan Guo Zachary P. Smith Qiang Liu Kevin A. Stevens James E. McGrath Donald R. Paul Benny D. Freeman 《Polymer》2014
Thermal rearrangement of polyimides with ortho-position groups to polybenzoxazoles and related structures has been of recent interest for producing gas separation membranes. This study explores the influence of synthesis route and ortho-position functional group on the thermal rearrangement process and the fractional free volume of thermally rearranged (TR) polymers produced from polyimides derived from 3,3′-dihydroxy-4,4′-diamino-biphenyl and 2,2′-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (HAB–6FDA). Acetate, propanoate, and pivalate ortho-position functional groups were considered. Thermogravimetric analysis (TGA) was used to study thermal rearrangement at temperatures between 350 and 450 °C, and evolved gases from TGA were analyzed via mass spectrometry to characterize the byproducts of thermal rearrangement and thermal degradation. CO2 was the major byproduct of thermal rearrangement for all samples, and its evolution began well before the onset of thermal degradation. When non-hydroxyl ortho-position groups were present in the polymers, several byproducts other than CO2 were also observed due to the loss of these ortho-position groups before thermal rearrangement. Free volume generally increased with increasing extent of thermal rearrangement, but precise values of free volume could not be accurately determined for polymers with propanoate and pivalate ortho-position functional groups due to uncertainties in the chemical structure of partially converted materials. For polymers with acetate and hydroxyl ortho-position groups, free volume could be determined within the uncertainty of density measurements. Thermal rearrangement behavior and free volume results for acetate containing polymers synthesized via different routes were very similar. Based on these results, the chemical structure of the ortho-position functional group has a larger impact on TR polymer properties than the polyimide precursor synthesis route. 相似文献