全文获取类型
收费全文 | 13112篇 |
免费 | 1260篇 |
国内免费 | 206篇 |
专业分类
电工技术 | 291篇 |
综合类 | 597篇 |
化学工业 | 9057篇 |
金属工艺 | 212篇 |
机械仪表 | 496篇 |
建筑科学 | 870篇 |
矿业工程 | 177篇 |
能源动力 | 82篇 |
轻工业 | 266篇 |
水利工程 | 150篇 |
石油天然气 | 803篇 |
武器工业 | 52篇 |
无线电 | 73篇 |
一般工业技术 | 1192篇 |
冶金工业 | 99篇 |
原子能技术 | 56篇 |
自动化技术 | 105篇 |
出版年
2024年 | 48篇 |
2023年 | 117篇 |
2022年 | 241篇 |
2021年 | 359篇 |
2020年 | 288篇 |
2019年 | 215篇 |
2018年 | 302篇 |
2017年 | 337篇 |
2016年 | 391篇 |
2015年 | 366篇 |
2014年 | 755篇 |
2013年 | 767篇 |
2012年 | 912篇 |
2011年 | 818篇 |
2010年 | 647篇 |
2009年 | 659篇 |
2008年 | 526篇 |
2007年 | 754篇 |
2006年 | 755篇 |
2005年 | 690篇 |
2004年 | 539篇 |
2003年 | 575篇 |
2002年 | 546篇 |
2001年 | 492篇 |
2000年 | 429篇 |
1999年 | 381篇 |
1998年 | 347篇 |
1997年 | 236篇 |
1996年 | 224篇 |
1995年 | 179篇 |
1994年 | 143篇 |
1993年 | 114篇 |
1992年 | 90篇 |
1991年 | 91篇 |
1990年 | 74篇 |
1989年 | 51篇 |
1988年 | 25篇 |
1987年 | 10篇 |
1986年 | 8篇 |
1985年 | 25篇 |
1984年 | 21篇 |
1983年 | 14篇 |
1982年 | 16篇 |
1978年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
2.
Piyawadee Luangchuang Narong Chueangchayaphan Muhammad Azwadi Sulaiman Wannarat Chueangchayaphan 《Polymer International》2021,70(1):154-161
The aim of this study was to develop high dielectric constant flexible polymers with a highly efficient and cost‐effective approach using acrylonitrile butadiene rubber (NBR) as the polymer matrix and barium titanate (BT) as the high dielectric constant filler. The BT powder was synthesized with a solid‐state reaction and was characterized using a particle size analyzer, XRD, SEM and Fourier transform infrared spectroscopy. NBR/BT composites were fabricated using an internal mixer with various BT loadings up to 160 phr. The influence of BT loading on the cure characteristics and mechanical, dynamic mechanical, thermal, dielectric and morphological properties was determined. The incorporation of BT in the NBR matrix shortened scorch time and increased delta torque. The mechanical properties, thermal stability and dielectric constant were greatly improved and increased with BT loading. The results suggest that the reinforcement effect was achieved due to strong hydrogen bonding or polar–polar interactions between NBR matrix and BT filler. This is further corroborated by the good dispersion of BT filler in the NBR matrix observed with SEM imaging. These findings can be applied to produce high‐performance dielectric elastomers. © 2020 Society of Industrial Chemistry 相似文献
3.
Nitrile rubber (NBR) blends with excellent performance have always been a hot research topic in petroleum field. Due to the excellent performance and compatibility of polyamide 6 (PA6), it provides an opportunity for the preparation of high-performance NBR/PA6 blends. In this article, NBR/PA6 blends were prepared by the three-step molding process. Experimentally, it was found that PA6 has a prominent reinforcement effect in NBR matrix. The variation of this mechanical property was investigated from different aspects of the crystal structure, crystallinities, phase morphology, and so on. It can be cleared that the formation of fibrous structure of PA6 phase is the main factor for reinforcement of the polymer blends. Meanwhile, the formation mechanism of the special phase structure induced by the three-step process is deeply expounded and its structural evolution schematic is established. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47472. 相似文献
4.
Global decrease in crude oil resources and frequent crude oil leaks cause the energy crisis and ecological pollution. The absorption and release of leaked crude oil through absorption materials are a necessary process for environmental protection and recycling. In this article, a CO2-responsive olefin copolymer was obtained by copolymerization of styrene and an amine-containing olefin monomer. The structure of resultant copolymer was characterized by FTIR; thermal properties and CO2-responsive morphology changes were determined by DSC/TGA and SEM, respectively. Copolymers had certain absorption capacity for toluene with absorption rate up to 180.0%. The absorbed toluene could be released upon CO2 stimulation with desorption rate up to 84.6%. The CO2-responsive copolymer could be regenerated through a simple heating process and showed stable absorption–desorption performance even after being recycled for 4 times. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47439. 相似文献
5.
A highly transparent and thermally stable copolymer of 1‐adamantyl methacrylate and styrene
下载免费PDF全文
![点击此处可从《Polymer International》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Thermal and optical properties of copolymers of 1‐adamantyl methacrylate (AdMA) and styrene (St) prepared by free radical polymerization in the bulk are investigated. The copolymer forms an azeotrope when the composition is AdMA/St = 55/45 mol%. The glass transition temperature and decomposition temperature of the azeotropic copolymer are 170 and ca 340 °C, respectively. The refractive index increases nonlinearly with St content from 1.522 to 1.591. The light scattering loss at 633 nm is 28.1 dB km?1, which is less than half of that of polystyrene. The total optical loss including molecular vibrational absorption, which is evaluated using a copolymer‐based optical fiber, is 292–645 dB km?1 at 500–700 nm. These values correspond to transmittances of 86–93% for a 1 m optical path length. © 2014 Society of Chemical Industry 相似文献
6.
High‐performance thermosets with tailored properties derived from methacrylated eugenol and epoxy‐based vinyl ester
下载免费PDF全文
![点击此处可从《Polymer International》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Yuehong Zhang Yuzhan Li Vijay Kumar Thakur Zhenhua Gao Jiyou Gu Michael R Kessler 《Polymer International》2018,67(5):544-549
A renewable chemical, eugenol, is methacrylated to produce methacrylated eugenol (ME) employing the Steglich esterification reaction without any solvent. The resulting ME is used as a low‐viscosity co‐monomer to replace styrene in a commercial epoxy‐based vinyl ester resin (VE). The volatility and viscosity of ME and styrene are compared. The effect of ME loading and temperature on the viscosity of the VE–ME resin is investigated. Moreover, the thermomechanical properties, curing extent and thermal stability of the fully cured VE–ME thermosets are systematically examined. The results indicate that ME is a monomer with low volatility and low viscosity, and therefore the incorporation of ME monomer in VE resins allows significant reduction of viscosity. Moreover, the viscosity of the VE–ME resin can be tailored by adjusting the ME loadings and processing temperature to meet commercial liquid molding technology requirements. The glass transition temperatures of VE–ME thermosets range from 139 to 199 °C. In addition, more than 95% of the monomer is incorporated and fixed in the crosslinked network structure of VE–ME thermosets. Overall, the developed ME monomer exhibits promising potential for replacing styrene as an effective low‐viscosity co‐monomer. The VE–ME resins show great advantages for use in polymer matrices for high‐performance fiber‐reinforced composites. This work is of great significance to the vinyl ester industry by providing detailed experimental support. © 2018 Society of Chemical Industry 相似文献
7.
Shogo Mamada Naoyuki Yaguchi Masanori Hansaka Masafumi Yamato Hirohisa Yoshida 《应用聚合物科学杂志》2015,132(15)
This study was addressed to the influence of an electric field strength applied at fabrication process and matrix properties, such as the dielectric constant and the Young's modulus, on “pseudo‐1‐3 piezoelectric ceramic/polymer composite” in order to further enhance the piezoelectricity of that. The pseudo‐1‐3 piezoelectric ceramic/polymer composite consists of linearly ordered piezoelectric ceramic particles in polymer material. Silicone gel, silicone rubber, urethane rubber, and poly‐methyl‐methacrylate, which exhibit different dielectric constants and Young's modulus, were used as matrices to evaluate the matrix influence. The piezoelectricity of the pseudo‐1‐3 piezoelectric ceramic/polymer composite was evaluated using the piezoelectric strain constant d33. The d33 is one of the indices of the piezoelectric properties for piezoelectric materials. As a result, it was confirmed that d33 of the pseudo‐1‐3 piezoelectric ceramic/polymer composite increased with the increase of the electric filed strength applied at fabrication process, though, it reached a constant value at a certain strength value. Further it was confirmed that dielectric constant of the matrix had a small influence on d33 of the pseudo‐1‐3 piezoelectric ceramic/polymer composite, however, in case of matrix of lower Young's modulus, d33 was increase. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41817. 相似文献
8.
研究了具有新型结构的双膦胺镍配合物N,N-双(二苯膦基)-对甲氧基苯胺二氯化镍-甲基铝氧烷(PNP-N i-MAO)催化体系对苯乙烯聚合的催化性能,考察了聚合温度、n(A l)∶n(PNP-N i)、PNP-N i的浓度和苯乙烯的浓度对催化活性、苯乙烯转化率、聚苯乙烯相对分子质量及其分布的影响,并用核磁共振和凝胶色谱对聚苯乙烯的结构进行了表征。实验结果表明,在聚合温度25℃、聚合时间1h、n(A l)∶n(PNP-N i)=300、c(苯乙烯)=2.3m ol/L、c(PNP-N i)=0.4mm ol/L、甲苯为溶剂的适宜条件下,苯乙烯的转化率可达95%以上,催化活性达到5×105g/(m ol.h)左右。核磁共振和凝胶色谱表征结果显示,所得聚苯乙烯为无规结构,重均相对分子质量约为1×104,相对分子质量分布Mw/Mn约为2。 相似文献
9.
10.