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排序方式: 共有3962条查询结果,搜索用时 15 毫秒
1.
Yin-Feng Wang Meng Li Jin-Ming Teng He-Ye Zhou Chuan-Feng Chen 《Advanced functional materials》2021,31(49):2106418
Recently, circularly polarized organic light-emitting diodes (CP-OLEDs) fabricated with thermally activated delayed fluorescence (TADF) emitters are developed rapidly. However, most devices are fabricated by vacuum deposition technology, and developing efficient solution-processed CP-OLEDs, especially nondoped devices, is still a challenge. Herein, a pair of triptycene-based enantiomers, (S,S)-/(R,R)-TpAc-TRZ, are synthesized. The novel chiral triptycene scaffold of enantiomers avoids their intermolecular π–π stacking, which is conducive to their aggregation-induced emission characteristics and high photoluminescence quantum yield of 85% in the solid state. Moreover, the triptycene-based enantiomers exhibit efficient TADF activities with a small singlet-triplet energy gap (ΔEST) of 0.03 eV and delayed fluorescence lifetime of 1.1 µs, as well as intense circularly polarized luminescence with dissymmetry factors (|gPL|) of about 1.9 × 10−3. The solution-processed nondoped CP-OLEDs based on (S,S)-/(R,R)-TpAc-TRZ not only display obvious circularly polarized electroluminescence signals with gEL values of +1.5 × 10−3 and −2.0 × 10−3, respectively, but also achieve high efficiencies with external quantum, current, and power efficiency up to 25.5%, 88.6 cd A−1, and 95.9 lm W−1, respectively. 相似文献
2.
To improve the convertibility of reconfigurable manufacturing system (RMS), the concept of delayed reconfigurable manufacturing system (D-RMS) was proposed. RMS and D-RMS are both constructed around part family. However, D-RMS may suffer from ultra-long system problem with unacceptable idle machines using generic RMS part families. Besides, considering the complex basic system structure of D-RMS, machine selection of D-RMS should be addressed, including dedicated machine, flexible machine, and reconfigurable machine. Therefore, a system design method for D-RMS based on part family grouping and machine selection is proposed. Firstly, a part family grouping method is proposed for D-RMS that groups the parts with more former common operations into the same part family. The concept of longest relative position common operation subsequence (LPCS) is proposed. The similarity coefficient among the parts is calculated based on LPCS. The reciprocal value of the operation position of LPCS is adopted as the characteristic value. The average linkage clustering (ALC) algorithm is used to cluster the parts. Secondly, a machine selection method is proposed to complete the system design of D-RMS, including machine selection rules and the dividing point decision model. Finally, a case study is given to implement and verify the proposed system design method for D-RMS. The results show that the proposed system design method is effective, which can group parts with more former common operations into the same part family and select appropriate machine types. 相似文献
3.
针对国内某炼油厂延迟焦化加热炉三点注汽问题,采用热负荷自动调节的算法进行了研究。运用该模型方法,分析了三点注汽量对加热炉热负荷和炉管结焦系数的影响,发现三点注汽量的改变均会对热负荷和炉管结焦系数产生影响,主要表现为提高注汽量将会提高热负荷,同时降低结焦系数;第1点注汽量和第2点注汽量对热负荷和结焦系数的影响较强,第3点注汽量对热负荷和结焦系数的影响较弱。在实际操作中,加热炉中的结焦程度既不能太强也不能太弱,合适的结焦系数能够保证正常开工周期里炉管不结焦,也能保证瓦斯、注汽量等参数的合理分配。通过对热负荷、注汽量的智能分配,可得到不同原料油加工负荷条件下更加合理的装置运行方案。 相似文献
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6.
相干源二维波达方向估计 总被引:4,自引:0,他引:4
本文分析了平面阵接收信号的协方差矩阵,发现它可分解为一个广义对称矩阵与一个非广义对称矩阵之和,利用信号协方差矩阵的这一结构特征,重点研究了相干源二维波达方向(DOA)估计.该方法通过构造一个差矩阵,求出其本特征值对应的任一特征向量,利用谱函数估计相干源二维DOA.简要分析了二维DOA估计的分维处理。 相似文献
7.
Guangyan Li W. Ian Hamilton Ged Morrisroe Theresa Clarke 《Cognition, Technology & Work》2006,8(1):30-40
A study was carried out using simulation to investigate driver responses to lineside signals and signs at various approach
speeds. The objectives of the study were: (1) to find out whether train speed would significantly affect signal/sign reading;
(2) to examine at which point certain types of signs or signals could be detected or recognised, and (3) to determine a speed
cut-off level above which certain types of signs or signals are no longer recognisable or detectable. Fifty-seven train drivers
from 12 Train Operating Companies in the UK participated in the trials. Twenty different types of lineside signs and ten types
of signals were tested under six different approach speeds ranging from 100 to 350 km/h (62–218 mph). Driver performance measures
were ‘time remaining to the signal/sign’ at the point of detection or recognition, and reading error rate. The results showed
a significant influence of train speed on driver responses to lineside signals/signs and demonstrated a non-linear relationship
between driver responses to signals/signs and approach speed. This has been used to estimate a maximum approach speed limit
within which a specific signal or sign can be correctly detected or recognised. The findings and implications of the study
are discussed in the paper. 相似文献
8.
根据延迟焦化流程的特点,分析了延迟焦化装置扩大生产能力的瓶颈,探讨了基于能量综合优化的装置扩能解除瓶颈的策略方法,基于过程能量综合优化,运用流程模拟技术,通过配套的加热炉优化,分馏塔操作优化,换热网络柔性设计等手段,实现了装置扩大生产能力的目的,并运用所提出的策略对某延迟焦化装置进行了基于能量系统优化的扩能改造,在原流程与设备的基础上,装置处理量增大18.2%,装置物耗,能耗大幅度降低,改造设备投资少,说明能量综合优化对工艺装置扩能改造具有重要意义。 相似文献
9.
叙述了国产的延迟树脂与进口DOWEX-11-A8树脂在腈纶厂NaSCN回收模拟装置上的比较试验,由试验数据可得出;国产的延迟树脂NVI脱除率性能略优于美国DOWEX-11-A8树脂,并可替代DOWEX-11-A8树脂应用于腈纶厂延迟装置中。 相似文献
10.
采用延迟破胶技术,在压裂施工过程中加入不同浓度的胶囊破胶剂,利用它的延缓释放特性,使植物胶压裂液耐温、耐剪切稳定性增强,并且可以在不造成压裂液的流变性、滤失性和携砂性等过早丧失的前提下高浓度使用胶囊破胶剂。该技术与常规破胶技术相比,延缓释放率达50%,能更有效地清除液体残渣,减少压裂液对储层的伤害。同时由于有延缓破胶的特性,放喷采用相应的措施,可以降低支撑剂沉降速度,形成较好的沉砂剖面,提供高的裂缝导流能力,并且可以降低滤饼和压裂液残渣的伤害。 相似文献