静态水热脱铝处理对HZSM-5分子筛的结构、酸性和催化性能的影响

开发了一种静态水热脱铝的方法。HZSM-5经此法处理后,正戊烷的裂解活性增加,脱氢和芳构化性能加强。可用改变处理温度的方法来控制脱铝的程度。用XRD和吡啶吸附红外技术进行了研究。HZSM-5分子筛催化剂性能的变化用非骨架铝产生的强L酸中心来解释。     

Ammoxidation of methylaromatics over vanadium phosphate catalysts II. Catalyst formation, active sites and reaction mechanism

The interactions of VOHPO₄· 0.5H₂O and (VO)₂P₂O₇ with the ammoxidation feed and the single components such as ammonia, oxygen, water and component mixtures were studied in detail using XRD and temperature-programmed reaction spectroscopy. The aim of this work was to improve the knowledge of the formation of the active phases or active sites of the catalysts from their precursors under the condition of the ammoxidation reaction. Similar catalytic properties of various applied VPO materials were discussed in terms of the presence of similar structure elements (domains of adjacent edge-sharing VO₆ octahedra-units and P-O-NH₄ groups).     

福禄宫“蝼蜂窠”制作技术初探

福禄宫位于湖南长沙市城西区,始建于清代光绪年间。解放后,福禄宫因未及时修理维护,朽损情况严重,1983年底被拆毁。通过对残留木制装修构件拼凑,推算出该建筑的蝼蜂窠部分测绘图。福禄宫蝼蜂窠类似于北方斗栱中的平身科,是一种装饰性构件。福禄宫的昂嘴采用翼龙飞凤交错排列的形式,部分昂嘴端部另加雕饰花板。蝼蜂窠采用层层叠置出踩的形式,其表面只施以桐油或光油等透明涂料,未施其它色漆及彩绘。     

Propane oxydehydrogenation reaction on a VPO/TiO2 catalyst. Role of the nature of acid sites determined by dynamic in-situ IR studies

A VPO/TiO₂ catalyst tested in the oxydehydrogenation reaction (ODH) of propane between 300 and 400°C shows satisfactory performances (up to 80% of propene selectivity at 2% of propane conversion at 300°C or 56% of propene selectivity at 9% of propane conversion at 400°C). Addition of water or pyridine in the feed gas tends to decrease the propane conversion and enhances the propene selectivity. It is shown that water increases the number of Brönsted surface acid sites by dissociative adsorption which, in turn, enhances propene selectivity at the expense of the CO_x selectivity. These results are in good agreement with spectroscopic IR observations performed under catalytic conditions showing that the Lewis acid sites are linked to CO_xformation, whereas it seems that Brönsted sites would rather be linked to propene formation.     

Nucleation and crystallization of polypropylene by mineral fillers: relationship to impact strength

The mechanical properties of mineral-filled polypropylene (PP) are determined not only by the size, shape and modulus of the filler particles, but also by microstructure. For example, poor impact strength is correlated with a high capacity for nucleation of crystallization. In the present study, optical microscopy has been used to measure the growth rate of spherulites in PP. In tandem with this, isothermal d.s.c. measurements have been made of the crystallization of the PP filled with talc, calcium carbonate and stearate-coated carbonate at different loading levels. Computer simulation of spherulite growth has been used to derive the number of nucleating sites per unit volume of polymer and, using surface area measurements, the number of sites per unit area of mineral surface was obtained. Values for talc were, as expected, considerably higher than those for carbonate (and especially coated carbonate) fillers. The presence of filler affects not only the nucleation and kinetics of the crystallization process but also the crystallinity and orientation indices and the proportion of β-phase crystallites present. The connection between these factors and impact strength is discussed. It is concluded that impact properties are determined by inter alia crack pinning and blocking by filler particles, stress concentrations at the edges of the filler particles, and the nucleating ability of the filler.     

Aligning principal and agent’s incentives: A principal–agent perspective of social networking sites

The viability of networked communities depends on the creation and disclosure of user-generated content and the frequency of user visitation (Facebook 10-K Annual Report, 2012). However, little is known about how to align the interests of user and social networking sites. In this study, we draw upon the principal-agent perspective to extend Pavlou et al.’s uncertainty mitigation model of online exchange relationships (2007) and propose an empirically tested model for aligning the incentives of the principal (user) and the agent (service provider). As suggested by Pavlou et al., we incorporated a multi-dimensional measure of trust: trust of provider and trust of members. The proposed model is empirically tested with survey data from 305 adults aged 20-55. The results support our model, delineating how real individuals with bounded rationality actually make decision about information disclosure under uncertainty in the social networking site context. There is show little to no relationship between online privacy concerns and information disclosure on online social network sites. Perceived benefits provide the linkage between the incentives of principal (user) and agent (provider) while usage intensity demonstrated the most significant impact on information disclosure. We argue that the phenomenon may be explained through Communication Privacy Management Theory. The present study enhances our understanding of agency theory and human judgment theory in the context of social media. Practical implications for understanding and facilitating online social exchange relationships are also discussed.     

Determinants of users’ continuance of social networking sites: A self-regulation perspective

Social networking sites (SNS) have transformed how individuals interact, build and maintain social relationships. We proposed a research model on the determinants of user continuance using Bagozzi's framework of self-regulation as the theoretical foundation. Following the process of appraisal → emotional reactions → coping responses, we developed the model by leveraging findings from social presence and IS continuance research. Based on survey data from Facebook users, we found that appraisal factors (pleasure, awareness, connectedness, and system quality) were strong determinants of emotional reaction (user satisfaction and sense of belonging). User satisfaction and sense of belonging together positively influenced continuance intention.     

基于JSP的社交网站设计

由于有关网络的科技发展,用户对于网络有了越来越多的需求,这时和社交有关的网站就成了热点,本系统是从学习、交流、分享,还有大范围的社交需求中产生的,用到B/S（Browser/Server）结构,使获取数据在浏览器中显示,而处理却在服务器中运行,用户只要一个浏览器就够了。现今社交网站的界面设计非常漂亮,主要是因为用到了jquery、ext等流行的JavaScript框架。开发中选择了SSH三大框架,dao层＋service层＋action层＋jsp显示层的mvc分层这样的开发模式,适用于简单的用户需求。     

基于弹性网络模型的蛋白质结构-功能关系

蛋白质结构-功能关系研究是结构生物学领域的热点问题之一,具有重要的理论和实际应用价值.弹性网络模型(elastic network model,ENM)是获取蛋白质结构本身固有动力学性质,进而揭示其生物学功能的有效方法,在蛋白质结构-功能关系研究中得到了广泛应用.简要介绍了ENM的基本原理及其在蛋白质结构-功能关系中的应用,主要包括蛋白质功能性运动分析和关键位点识别等.     

Understanding the intentions of users to ‘stick’ to social networking sites: a case study in Taiwan

Social networking sites (SNSs) are the most popular social platforms for developing personal networks. They provide multiple interactive functions for users to create and use large social networks. To determine why people exhibit ‘stickiness’ to SNSs, this study uses the uses and gratifications theory as an underlying structure and builds the research model with factors of motivational needs and interactivity. Our results showed that social needs, information needs, human–message interaction, and human–human interaction are crucial factors that affect the ‘stickiness’ of users to SNSs. The implications of these findings are presented in this paper.