Kinetics of two-step anionic polymerization

This article deals with the kinetics of two-step anionic polymerization by way of a non-steady state method. Several molecular parameters can be evaluated using the formulae developed. A bimodal molecular weight distribution function for the resulting polymer is derived from the set of kinetic differential equations, which is in agreement with the experimental data reported.     

Electrochemical mass transfer between an impinging jet and a rotating disk in a confined system

This paper presents the mass transfer results from an impinging liquid jet to a rotating disk. The mass transfer coefficients were measured using the electrochemical limiting diffusion current technique (ELDCT). Rotational Reynolds number (Re_r) in the range of 3.4 × 10⁴–1.2 × 10⁵, jet Reynolds number (Re_j) 1.7 × 10⁴–5.3 × 10⁴ and non-dimensional jet-to-disk spacing (H/d) 2–8 were taken into consideration as parameters. It was found that the jet impingement resulted in a substantial enhancement in the mass transfer compared to the case of the rotating disk without jet.     

CO2 emissions in Greece for 1990–2002: A decomposition analysis and comparison of results using the Arithmetic Mean Divisia Index and Logarithmic Mean Divisia Index techniques

This paper deals with the decomposition analysis of energy-related CO₂ emissions in Greece from 1990 to 2002. The Arithmetic Mean Divisia Index (AMDI) and the Logarithmic Mean Divisia Index (LMDI) techniques are applied and changes in CO₂ emissions are decomposed into four factors: income effect, energy intensity effect, fuel share effect and population effect. The period-wise and time series analyses show that the biggest contributor to the rise in CO₂ emissions in Greece is the income effect; on the contrary, the energy intensity effect is mainly responsible for the decrease in CO₂ emissions. A comparison of the results of the two techniques gave an insight in the intricacies of energy decomposition. Finally, conclusions and future areas of research are presented.     

Practical method for generation expansion planning based on dynamic programming

This paper presents an efficient method which provides the optimal generation mix and the optimal generation construction process. The approximation method in which the dynamic programming technique and gradient method are combined is applied to determine the optimal generation mix with hydropower generation technologies. The successive approximations dynamic programming (SADP) technique, which is very suitable for high-dimensional multistage decision process problems, is used for obtaining the optimal generation construction process. The effectiveness and feasibility of the developed technique are demonstrated on a practical power system model which has five types of generation technologies including a hydropower generation technology.     

一种改进的共同进化遗传算法及其应用

将共同进化遗传算法应用于临床营养决策优化中,虽然取得了一定成果,但算法中仍存在早熟现象、局部搜索能量弱等问题,为此提出一种改进的共同进化模型。算法使用新的子群体划分方法和交叉算子,引入精英保留策略、信息交换原则和小生境技术。通过对糖尿病营养治疗的仿真表明,改进后的算法在保证群体多样性和避免早熟现象的前提下,提高了算法的局部和全局寻优能力,且膳食配方中营养素达标率符合要求,满足专家建议的糖尿病饮食需求。     

我国建筑涂料技术进步简评

从以下诸方面简述我国建筑涂料的技术进步:⑴新品种涂料的研制开发;⑵加强对配套材料及施工技术的研究;⑶超细填料在涂料中的应用;⑷计算机自动配色技术;⑸产品标准的修订;⑹建筑涂料的实用范围扩大。     

锌钾硼对甜菜产质量效应及最佳施肥措施的研究

本文利用最优回归设计“310”方案,研究了黑土地甜菜 Zn、K_2O、B的效果及合理施用问题。得出甜菜块根产量、含糖、产糖量、灰分 K 和有害 N 与 ZnK_2O、B 肥回归关系显著的回归模型,分析了 Zn、K_2O、B 对上述五个指标的效应,明确了 Zn 是影响各项指标的主要因子,并采用频率筛选法,提出了兼顾上述五项指标的优质高产施肥措施。     

SIMATIC S5—115U可编程控制器

本文通过对SIMATIC S5—115U可编程控制器性能的简介,简述国外PC技术的现状和发展,并提出对PC国产化的看法.     

Cationic ring-opening polymerization of hexamethylcyclodisilazane: General aspects and tentative mechanisms

The ring-opening polymerization of hexamethylcyclodisilazane (D_2NMe), initiated by methyl triflate in 1,2-dichloroethane, forms in the first, fast kinetic step both linear polymer and cyclic dimer (D_4NMe). Subsequently a slow depolymerization process occurs leading to exclusively cyclotrisilazane (D_3NMe). On the basis of kinetic measurements carried out using an adiabatic calorimetric technique and complementary experiments, mechanisms of both propagation, cyclization and back-biting reactions are proposed. The influence of the reaction temperature was also studied; it is demonstrated that, at low temperature, polymerization does not lead to cyclic oligomer formation. In such conditions, the polymerization presents a ‘living’ character.     

A comparison of lightness contrast effects in CRT and surface colours

The simultaneous contrast effect is investigated in this article. A total of 174 and 154 test/induction combinations were studied for CRT and surface colours respectively. Each combination was assessed by nine observers using a matching technique. The test and induction colours used for CRT colours were similar to surface colours using fabric samples. The results indicated a strong lightness contrast effect for both CRT and surface media; that is, the lightness of a test colour surrounded by a lighter induction colour was reduced for both CRT and surface colours. However, the effect in CRT medium was more pronounced than in the surface medium. © 2004 Wiley Periodicals, Inc. Col Res Appl, 30, 13–20, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20074