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《International Journal of Hydrogen Energy》2022,47(44):19217-19236
In our previous work, phosphorylated chitosan was modified through polymer blending with poly(vinyl alcohol) (PVA) polymer to produce N-methylene phosphonic chitosan/poly(vinyl alcohol) (NMPC/PVA) composite membranes. The aim of this work is to further investigate the effects of a propylammonium nitrate (PAN) ionic liquid and/or silicon dioxide (SiO2) filler on the morphology and physical properties of NMPC/PVA composite membranes. The temperature-dependent ionic conductivity of the composite membranes with various ionic liquid and filler compositions was studied by varying the loading of PAN ionic liquid and SiO2-PAN filler in the range of 5–20 wt%. As the loading of PAN ionic liquid increased in the NMPC/PVA membrane matrix, the ionic conductivity value also increased with the highest value of 0.53 × 10?3 S cm?1 at 25 °C and increased to 1.54 × 10?3 S cm?1 at 100 °C with 20 wt% PAN. The NMPC/PVA-PAN (20 wt%) composite membrane also exhibited the highest water uptake and ion exchange capacity, with values of 60.5% and 0.60 mequiv g?1, respectively. In addition, in the single-cell performance test, the NMPC/PVA-PAN (20 wt%) composite membrane displayed a maximum power density, which was increased by approximately 14% compared to the NMPC/PVA composite membrane with 5 wt% SiO2-PAN. This work demonstrated that modified NMPC/PVA composite membranes with ionic liquid PAN and/or SiO2 filler showed enhanced performance compared with unmodified NMPC/PVA composite membranes for proton exchange membrane fuel cells. 相似文献
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Seyedeh Nooshin Banitaba Dariush Semnani Elahe Heydari‐Soureshjani Behzad Rezaei Ali A Ensafi Ahmadreza Taghipour‐Jahromi 《Polymer International》2020,69(8):675-687
In this study, solvent‐free nanofibrous electrolytes were fabricated through an electrospinning method. Polyethylene oxide (PEO), lithium perchlorate and ethylene carbonate were used as polymer matrix, salt and plasticizer respectively in the electrolyte structures. Keggin‐type hetero polyoxometalate (Cu‐POM@Ru‐rGO, Ni‐POM@Ru‐rGO and Co‐POM@Ru‐rGO (POM, polyoxometalate; rGO, reduced graphene oxide)) nanoparticles were synthesized and inserted into the PEO‐based nanofibrous electrolytes. TEM and SEM analyses were carried out for further evaluation of the synthesized filler structures and the electrospun nanofibre morphologies. The fractions of free ions and crystalline phases of the as‐spun electrolytes were estimated by obtaining Fourier transform infrared and XRD spectra, respectively. The results showed a significant improvement in the ionic conductivity of the nanofibrous electrolytes by increasing filler concentrations. The highest ionic conductivity of 0.28 mS cm?1 was obtained by the introduction of 0.49 wt% Co‐POM@Ru‐rGO into the electrospun electrolyte at ambient temperature. Compared with solution‐cast polymeric electrolytes, the electrospun electrolytes present superior ionic conductivity. Moreover, the cycle stability of the as‐spun electrolytes was clearly improved by the addition of fillers. Furthermore, the mechanical strength was enhanced with the insertion of 0.07 wt% fillers to the electrospun electrolytes. The results implied that the prepared nanofibres are good candidates as solvent‐free electrolytes for lithium ion batteries. © 2020 Society of Chemical Industry 相似文献
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琼东南盆地深水区经历了断陷、断拗和拗陷3大构造演化和沉积充填阶段,主要发育4种沉积体系,相应地形成了4类主要储层:1)陵三段扇三角洲或滨海相砂岩储层;2)三亚、梅山组滨浅海相砂岩储层;3)三亚—莺黄组低位体储层;4)梅山组台地边缘礁滩灰岩储层。平面上,储层发育具有明显的分带性,可划分为:北部浅水陆架滨岸砂岩、三角洲砂岩储层发育带;中央坳陷低位体储层发育带;南部永乐隆起区碳酸盐岩储层发育带。深水区主要位于后2个带,每个带储层发育的控制因素不同,可以进一步划分为多个储层发育区。每个储层发育区存在多套储盖组合,每套储盖组合在多个储层区中发育。其中台地灰岩储层可能成为南部隆起区具有重要意义的勘探层系。 相似文献
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对目前高炮火力控制系统目标滤波与预测进行了分析与研究.在此基础上结合工程实际设计了一种α-β滤波器.该滤波器的原理是把在连续系统中频率域的要求和在离散系统中Z域的要求转换成时域中在典型信号激励下的时间响应的特征值的要求.从而在时间域中以特征值的要求进行综合.再把综合的结果转换回Z域中.最终得到所确定的α-β滤波器.文中给出了α-β滤波器的Z传递函数.分析了α-β滤波器参数的确定.对α-β滤波器的静态误差进行了研究.对设计方案进行了计算机仿真和实际应用. 相似文献
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介绍了新型浅色补强填充剂LEE白滑粉的组成、物化性质、加工特性、硫化胶性能及应用前景。 相似文献
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The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002 相似文献
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