Synthesis and characterization of superoleophobic fumed alumina nanocomposite coated via the sol-gel process onto ceramic-based hollow fibre membrane for oil-water separation

Oily wastewater treatment is a global challenge due to the substantial amount of effluent resulted from many industrial and domestic activities. To overcome the challenge of using existing treatment approach and fouling, superoleophobic coatings were fabricated. In this study, a superoleophobic membrane surface was obtained using the sol-gel technique with perfluorooctanoate (PFO), poly (diallyl dimethylammonium chloride) (PDADMAC), and nanoparticles as complex-polymer nanocomposites. The effects of coating cycles on the surface structure, chemical properties, surface chemistry, and oleophobicity of the surface were examined using field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and oil contact angle measurement. The results showed that the coated layer successfully adhered to the substrate surface. However, the chemical stability with respect to oil contact angle (OCA) revealed a decline at pH 7 and pH 9 and maintained stability at pH 3. Besides, oil flux at 63.0 L/m². h was achieved for PDADMAC-Al₂O₃/44 wt% PFO and the highest separation efficiency of 98% was obtained. Furthermore, the oil rejection decreases as the oil concentration increases from 1 to 3 g/L. OCA of 155° was obtained after 5 coating cycles. Apart from mitigating substrate fouling, the superoleophobic and superhydrophilic coating can be applied to a ceramic-based hollow fibre membrane and efficiently used for the separation of oil from oily wastewater.     

Preparation and antifouling performance of thin inorganic ultrafiltration membrane via assisted sol-gel method with different composition of dual additives

A novel TiO₂ thin film was prepared on the ceramic hollow fiber by the sol-gel method using poly(vinylpyrrolidone) (PVP) and polyvinyl alcohol (PVA) as additives. SEM images verified the formation of TiO₂ layer with various thickness using different composition of titania sols. The effect of the PVP and PVA contents on the TiO₂ sol properties, the separation and the antifouling performance of the ultrafiltration membranes were investigated thoroughly. When the contents of PVP and PVA were 1.0 wt% and 0.8 wt%, respectively, the resultant membrane showed a thickness of 0.55 μm with a pure water flux of 255 L m^?2 h^?1. In addition, the adherent foulant bovine serum albumin was applied to evaluate the antifouling performance. During the three fouling-recovery cycles, the flux recovery ratio and the flux decay ratio maintained about 99% and 30%. The BSA flux and rejection were still 169 L m^?2 h^?1 and 96.9% after the cycles, indicating a superior antifouling property.     

用于远程激光测距机的板条激光器

研制了用于远程激光脉冲测距机的板条激光器。使用半导体泵浦的MOPA激光结构实现了大于250 mJ的脉冲激光输出,输出脉冲宽度为12.83 ns,最终输出激光光束束散角为0.18 mrad。该激光测照器可应用于远程激光测距。对激光测距机的测距与照射能力进行了理论计算与分析。理论分析表明,应用于机载平台时,该激光测照器能够实现50 km距离的激光测距。该型激光测距机具有测距距离远,重量轻,结构紧凑等特点,具有广泛的应用前景。     

一种可替代漂珠的低密度材料

漂珠低密度水泥浆由于密度低、强度高、体系稳定而在油田低压易漏层及低压油气层长封固段固井作业中获得了广泛的应用。但近年来,由于漂珠的产量越来越少,油田低成本要求急需开发代替漂珠的新型减轻材料,以满足配制低密度水泥浆的需求。开发了BCL-10S低密度混合减轻材料,其物化性能与漂珠相当,用它作减轻剂配制的低密度水泥浆性能与用漂珠作减轻剂配制的低密度水泥浆性能相媲美,并已经在长庆油田获得了应用。     

寒冷地区高温干燥条件下混凝土面板裂缝控制

希尼尔水库位于新疆巴音郭楞蒙古族自治州境内，气候特点为高温、干燥、冬季寒冷。根据混凝土面板产生裂缝的原因，并结合工程区的气候特点，认为控制面板的塑性收缩、干缩与冷缩裂缝是防止裂缝产生的重点。通过采用高性能混凝土，合理的养护措施(微喷灌洒水技术)，有效地防止了裂缝的产生，保证了工程质量。     

气动贯通式潜孔锤反循环连续取心取样钻进新技术在河南钼矿中应用

三道庄钼矿勘探生产中钻遇的地层非常复杂，采用其他方法均无法实现钻进，经过分析比较，决定采用贯通式潜孔锤反循环连续取心（样）钻进新技术来解决该地层钻进难、成孔难、取样难等三大问题。文章从钻进技术特点、工作原理等方面对该技术进行详细分析，得出其具有钻进效率高、岩心（样）采取率高、成孔质量好等突出优点。并介绍了钻进主要设备机具的配套、施工工序、操作要点、遇到问题的解决方法等。在河南钼矿露天采石场应用该项技术，有效避免了塌孔和卡钻事故，工程进展顺利、质量好、岩心（样）采取率在98％以上，取得了良好的效果。针对在生产试验中遇到的某些问题，作者提出了一些改进建议。     

浇筑式沥青混凝土心墙型式改进的建议

本文根据浇筑式沥青混凝土主、副心墙材料的性能，分折了沥青混凝土心墙施工或运行中破坏的原因，建议用编织一无纺复合布取代预制块，以避免主、副心墙材料变形性能相差悬残对心墙运行的不利影响，从而发挥浇筑式沥青混凝土心墙的优越性。     

织金县HFC双向网络设计方案

织金电视台通过对有线电视网络进行双向改造，为Internet宽带接入、数字电视、VOD等多媒体应用提供了运行平台，介绍织金县城区HFC双向网络设计方案。