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1.
John Bensted 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(4):181-184
Characterisation of raw materials for Portland cement manufacture by use of the methylene blue adsorption method is discussed. The method is shown to be a simple, convenient ‘rule of thumb’ procedure. It provides a guide to the quantity and type of argillaceous minerals present in a given raw material sample. 相似文献
2.
Nanocomposites based on poly(butylene terephthalate) (PBT) and an organoclay (Cloisite 30B) were prepared by melt blending using a twin‐screw extruder. Two kinds of PBTs, ie PBT‐A and PBT‐B, with different inherent viscosities (ηinh), were used for this study (ηinh of PBT‐A and PBT‐B were 0.74 and 1.48, respectively). Dispersion of the clay layers in the PBT nanocomposites was characterized by using X‐ray diffraction (XRD) and transmission electron microscopy (TEM). Tensile and dynamic mechanical properties and non‐isothermal crystallization temperatures of the nanocomposites were also examined. Nanocomposites based on the higher‐viscosity PBT (PBT‐B) showed a higher degree of exfoliation of the clay and a higher reinforcing effect when compared to the composites based on the lower‐viscosity PBT (PBT‐A). The clay nanolayers dispersed in PBT matrices lead to increases in the non‐isothermal crystallization temperatures of the PBTs, with such increases being more significant for the PBT‐B nanocomposites than for the PBT‐A nanoocomposites. Copyright © 2004 Society of Chemical Industry 相似文献
3.
Ashok K. Vijh 《Drying Technology》1995,13(1):215-224
An attempt is made to elucidate the electrochemical aspects of the electroosmotic dewatering (EOD) of clays as reported in some recent work, especially that on interrupted DC power electroosmotic dewatering published by Rabie, Mujumdar and Weber (2). These authors showed that the dewatering by EOD stops after the DC power has been on for several minutes or hours; on interruption of their power and on short-circuiting of the electrodes, conditions can be created again for some further dewatering by DC power EOD. This discovery, of Rabie et al. is interpreted as a fuel cell effect and it is shown that it affords clues to several other electrochemical strategies for the possible enhancement of the efficiency of the EOD by DC power.
Further, the open circuit potentials observed by Rabie et al. (2) on the interruption of DC power are given an electrochemical interpretation which leads to quantitative estimates in agreement with the experimental values. 相似文献
Further, the open circuit potentials observed by Rabie et al. (2) on the interruption of DC power are given an electrochemical interpretation which leads to quantitative estimates in agreement with the experimental values. 相似文献
4.
RM Martín‐Aranda E Ortega‐Cantero ML Rojas‐Cervantes MA Vicente‐Rodríguez MA Baares‐Muoz 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(2):234-238
α,β‐Unsaturated nitriles have been synthesized by Knoevenagel condensation of a carbonylic compound with malononitrile, assisted by sonochemical irradiation. Two alkaline‐promoted clays (Li+‐ and Cs+‐exchanged saponites) have been employed as catalysts. The influence of the carbonylic compound (benzaldehyde or cyclohexanone) and the use of a solvent on the catalytic activity have been studied. Remarkable increase in the conversion values has been found when the reaction is activated by ultrasound, as compared with the thermal activation. In this green, solvent‐free procedure, α,β‐unsaturated nitriles have been produced in very high yields (97%) when the Cs+‐saponite is used as catalyst. Copyright © 2004 Society of Chemical Industry 相似文献
5.
Marina Fomina Geoffrey M Gadd 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2003,78(1):23-34
The sorption of toxic metals by fungal mycelia grown in clay‐containing medium is reported in this work. Biomass of melanin‐producing microfungi of the genus Cladosporium (C cladosporioides, C resinae and C herbarum) and Aureobasidium pullulans, clay minerals and fungal mycelia grown in clay‐containing medium were compared for their equilibrium Cu and Cd uptake from pH‐buffered solutions using experimental sorption isotherms. Bentonite (Cherkassy) in the natural form was shown to be the best Cu sorbent compared with the other clays and clay minerals tested. Cu sorption isotherms fitted the Langmuir sorption model for all cases. Comparison of Cu and Cd uptake for biomass and bentonite showed a lower biomass uptake capacity but a considerably higher affinity of the biosorbent for the solute. The presence of kaolinite and palygorskite in the medium generally reduced both Cu and Cd sorption capacity and the metal‐binding ability of the fungal–clay mixtures. In contrast, addition of bentonite into the medium did not appreciably alter the Cd sorption ability but increased the sorption of Cu by A pullulans and C cladosporioides grown in this medium. A common feature for all fungi grown in the presence of bentonite was an increase in the Cu sorption capacity (Qmax) of the biomineral sorbents and a reduction in their affinity (Langmuir parameter b) compared with control biomass. A difference between predicted and experimental data obtained for biomass grown on bentonite medium was also observed. The connection between the sorption capacity of biomass grown in clay‐containing medium, mycelial morphology and the structure of fungal pellets is discussed and a mechanism for the changed sorption capacity of the combined biomineral sorbents is proposed which involves blocking or modification of binding sites on biotic and abiotic components of the ‘biomineral’ association. © 2002 Society of Chemical Industry 相似文献
6.
Animesh Chakrabarti Man Mohan Sharma 《Journal of the American Oil Chemists' Society》1992,69(12):1251-1253
Anhydrous esterification of myristic acid with propylene was carried out in the temperature range of 110–145°C and pressure
from 190–195 psig in the presence of Amberlyst-15 (cation exchange resin) and Filtrol-24 (acid-treated clay) as catalysts.
The product ester, isopropyl myristate finds use in cosmetic and topical medicinal preparations where good absorption through
the skin is desired. Filtrol-24 is the catalyst of choice, and the recommended operating temperature is 130°C with a pressure
of 190 psig. 相似文献
7.
采用稀土氧化物和无机化合物的复合物(不简称RI-复合物)作为搪瓷釉浆悬浮剂,使之全部或大部分代替粘土,进行了一系列试验,已获得成功,突破了长期来搪瓷工业离不开粘土的传统工艺,并实现了工业化生产。 相似文献
8.
Intercalation of poly[oligo(oxyethylene) methacrylates] onto sodium montmorillonite (MMT) clay has been investigated. A polymer–clay hybrid has been synthesized through intercalation of the monomer followed by its solution free‐radical polymerization. Eight polymer–clay hybrids were prepared using different weight ratios of clay, different oligo(oxyethylene) lengths and different proportions of crosslinker. Evidence of the development of nanostructures is obtained from scanning electron microscopy, and wide‐angle X‐ray diffraction studies support these results which show disappearance of the peak characteristic to d001 spacing. In this hybrid MMT is dispersed homogeneously in the polymer matrix. © 2003 Society of Chemical Industry 相似文献
9.
为了继承和发扬错金工艺,从其定义出发,探讨了该工艺在中国古代及国外的发展与应用以及笔者对该工艺的实验研究。针对在错金工艺实践过程中出现的问题,在查阅了相关的资料后,对传统错金工艺的实现方法提出了质疑。 相似文献
10.
对Daleel油田作业5区三分支水平井DL-59井井下复杂情况分析,室内测定了引起复杂情况的Nahr Umr泥页岩地层的矿物组分和粘土矿物含量,优选了适应在该泥页岩地层215.9 mm造斜井段的钻井液配方中的各种处理剂,最后研制出钻井液配方,通过DL-73井应用后,取得了良好的防塌效果. 相似文献