应用在地下工程施工中的新技术（Ⅱ）

为有效保护地面上的生态环境，开发利用地下空间资源并营建新世纪的地下水城，在新的21世纪里将会建造更多的地下工程以满足人们生产生活的各种需要。文中介绍了地下工程施工中采用的逆作法、盾构法、新奥法、沉管隧道、顶管工程和大型沉井施工新技术，供同行们参考应用。     

贝氏体铁素体片条的超微亚结构研究

首次采用扫描隧道显微镜(STM)在大气环境下直接观察了Fe-1.0C-2.0Si-4.0Cr钢中下贝氏体铁素体片条的组织结构,在下贝氏体亚单元内部首次观察到以前从未发现的,尺寸更小、形状规则、排列整齐的结构单元——超亚单元,并初步提出下贝氏体铁素体由以下四个结构层次组成:即下贝氏体铁素体片条由亚片条组成,亚片条由亚单元组成,亚单元由超亚单元组成。     

Excavation of Inlet Tunnels at Geheyan Power Station

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Electronic Theory of Thermodynamic Adhesion inMetal/Ceramic Systems

ＥｌｅｃｔｒｏｎｉｃＴｈｅｏｒｙｏｆＴｈｅｒｍｏｄｙｎａｍｉｃＡｄｈｅｓｉｏｎｉｎＭｅｔａｌ／ＣｅｒａｍｉｃＳｙｓｔｅｍｓＬｉＪｉａｎ＇ｇｕｏ（李建国）（ＩｎｓｔｉｔｕｔｆｕｒＮｉｃｈｔｍｅｔａｌｌｉｓｃｈｅＷｅｒｋｓｔｏｆｆｅ，ＴｃｈｎｉｓｃｈｅＵ...     

Self-assembled monolayers of a disulphide-derivatised cobalt-porphyrin on gold

A self-assembled monolayer (SAM) of a novel cobalt(II)porphyrin disulphide derivative was prepared on flat gold(1 1 1) electrode. Evidence for surface modification was provided by electrochemical reductive desorption of the monolayer and ellipsometry, consistent with a coverage of 2.5 × 10⁻¹⁰ mol cm⁻² and a thickness of 13 Å, respectively. Both results support the presence of SAMs where the molecules share an intermediate position between perpendicular and flat orientation. Scanning tunnelling microscopy have also proven the formation of CoPSS SAMs, however high-resolution images could only be obtained when the CoPSS molecules were diluted in an hexanethiol SAM. The electrocatalytic activity of the surface confined Co-porphyrin was evaluated for the oxygen reduction. Voltammetric data indicate that reaction involves two electrons consistent with the formation of hydrogen peroxide. Under similar experimental conditions the data obtained for an iron-porphyrin analogue points for a full reduction of dioxygen to water.     

软弱破碎围岩隧道二衬施作的合理时机判别研究

为了合理判别软弱破碎围岩隧道的二衬施作时机,结合工程实践,通过洞室拱顶沉降和边墙变形收敛的现场监控量测,提出了利用围岩-初支系统变形实测数据判别软弱破碎围岩隧道二衬施作合理时机的考虑支护是否保守的五级速率比值法并研发了相应的软件,并通过工程实例进行了成功验证。研究表明：1研制的软件操作具有界面简洁、友好,以及操作简单易用的特点,具有测点围岩-初支系统位移和收敛的现场监测数据的录入、储存、修改和管理等功能,能方便地进行软弱破碎围岩隧道的二衬合理时机判别;2通过工程实例验证分析表明,提出的方法是可行的,与现行的二衬时机选择的方法本质上是相同的,但更加具有可操作性,研究成果可以为同类型隧道的二衬时机选择提供可资借鉴的方法。     

Relaxation time and conductivity of comb‐like gel polymer electrolytes

Using the copolymer of acrylonitrile (AN), methyl methacrylate (MMA), and poly(ethylene glycol) methyl ether methacrylate as a backbone and poly(ethylene glycol) methyl ether (PEGME) with 1100 molecular weight as side chains, comb‐like gel polymers and their Li salt complexes were synthesized. The dynamic mechanical properties and conductivities were investigated. Results showed that the gel copolymer electrolytes possess two glass transitions: α‐transition and β‐transition. Based on the time–temperature equivalence principle, a master curve was constructed by selecting T_α as reference temperature. By reference to T₀ = 50°C, the relation between log τ_c and c was found to be linear. The master curves are displaced progressively to higher frequencies as the content of plasticizer is increased. The relation between log τ_p and the content of plasticizer is also linear. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 576–584, 2007     

基于内置接头参数数组的整环衬砌模型结构分析

为在整环衬砌结构分析中正确体现管片接头参数的复杂特性,通过表格型数组将管片接头参数内置于整环衬结构分析的程序中。经迭代计算,实现了管片接头三维非线性参数在整环衬砌分析中的全面应用。研究表明：这种将接头参数和整环衬砌整合在同一程序的算法,不但结果可靠而且运算速度更快;管片接头的抗弯刚度、接缝张开量、混凝土最大压应变、螺栓拉应力都将随着拼装方式、接头位置、外部荷载而改变,不适合单一取值;该模型不仅能分析整环受力和变形,而且能评价各管片接头的安全状态。     

ＴＢＭ隧道下穿市政桥梁施工变形规律研究

针对ＴＢＭ不同角度下穿既有结构,对既有结构产生的扰动问题,依托青岛地铁１号线海泊桥站到小村庄站区间ＴＢＭ隧道下穿市政桥梁工程,利用ＦＬＡＣ３Ｄ数值模拟分析软件与现场施工监测相结合的方法,建立相应的三维地质力学模型,研究双线ＴＢＭ隧道施工对既有桥梁结构的受力特征与变形规律,揭示ＴＢＭ隧道下穿市政桥梁施工变形规律。计算结果表明:ＴＢＭ下穿会导致既有桥面板向上隆起,左线隧道开挖引起的桥面板隆起值要远远大于右线开挖;当左线隧道开挖到桥梁跨中时,桥头与桥尾隆起量最大,最大值约４．６３ｍｍ;新建隧道下穿既有结构尽量采用小角度下穿,避免既有结构发生大变形。