挠性胶管的阻尼减振机理初探

建立了挠性胶管阻尼耗能的简化模型。以此为基础分析了挠性胶管的阻尼耗能的一般规律,并得出了一些新的结论。     

Measuring and modeling the rheological data of diglycidylether of bisphenol‐A during polymerization for finite element analyses

Finite element analyses (FEA) of thermosets are often performed on the basis of rheological data for fully cured resin. For the FEA of thermosets during curing, a material model is established and a technique is demonstrated, which allows the rheological data of the linear viscoelastic material to be derived. As the moduli are sensitive to conversion, all measured properties are related to temperature and conversion. Therefore the basis for the rheological data has to be a suitable reaction kinetic. Based on the kinetics shear and compression properties are measured independently and modeled mathematically with the focus to gain a formulation, which is suitable for FEA. The considered time constants are in the range between one second and one month as these times are relevant for the investigated relaxation times. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1868–1872, 2003     

Thermally induced microstructural changes in cotton fibers: A free‐volume study

I measured positron lifetime in natural polymer–cotton fibers as a function of isochronal annealing temperature in the range 27–290°C. The variations in the positron results indicated structural changes occurring in the cotton fibers and determined the glass‐transition temperature as 80°C. Activation energies were measured separately for the crystalline and amorphous regions, indicating the versatility of the technique. These values were close to the O? H bond dissociation energy, suggesting O? H bond dissociation, the most probable process occurring under thermal treatment. As an extension of the positron results, the molecular weight of the cotton fibers was determined to be 1,200,000 based on free volume, which was within the range suggested for cotton. There seemed to be an indication that crosslinking changed the spiral structure of cotton fibers to the network type. However, this needs to be validated by other measurements. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3336–3345, 2002     

Entanglement network and relaxation temperature dependence of single‐site catalyzed ethylene/1‐hexene copolymers

In this work, we investigate the linear viscoelastic response of high molecular weight ethylene/1‐hexene copolymers, characterized by a narrow molecular weight distribution and comonomer content in the range from 0 to 10 mol %. A variation in the entanglement plateau modulus has been found in agreement with the recently developed packing length model. The packing model applied to viscoelastic data suggests decreased values of the characteristic ratio, accordingly with recent computer simulation results. The flow activation energy increases as the side chain content increases. This feature is thought to be related to the mobility of the molecules. The presence of side branches due to the comonomer hinders the mobility of the molecules, and increases the thermal barrier for the segmental motion. Then in the comonomer content range studied, the increase of the flow activation energy goes parallel with a decrease in the characteristic ratio. This result suggests that more parameters than only the stiffness of the chain modulate the thermal dependence of viscoelastic properties. A more refined study is necessary combining experiments with computer simulations in order to elucidate these aspects. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Viscoelastic properties of polyarylene ether nitriles/thermotropic liquid crystalline polymer blend

Polyarylene ether nitriles (PEN)/thermotropic liquid crystalline polymer (TLCP) blend was prepared via melt mixing. The immiscible phase morphologies, linear and nonlinear, as well as transient viscoelastic properties of the blend were studied using SEM, rheometer, and DMA. The linear dynamic viscoelastic behavior of the blend shows temperature dependence due to further evolution of the immiscible morphology and, as a result, the principle of time‐temperature superposition (TTS) is invalid. In the steady shear flow, the discrete TLCP phase is difficult to be broken up because of the high viscosity ratio of the blend systems, while is easy to be coarsened and followed by elongation, and finally, to form fibrous morphology at high TLCP content and high shear level. During this morphological evolution process, the transient stress response presents step increase and nonzero residual relaxation behavior, leading to increase of the dynamic viscoelastic responses after steady preshear. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Potential applications of poly(vinyl alcohol)‐congo red aqueous solutions and hydrogels as liquids for hydraulic fracturing

The authors report on the viscoelastic characterization of guar hydrogels obtained through complexation reactions with borax ions. These gels are compared with hydrogels obtained from poly(vinyl alcohol) of different degree of hydrolysis through complexation reactions with congo red. The effect of the degree of hydrolysis and both, the concentration of PVA and the concentration of congo red, on the viscoelastic properties of the hydrogels is analyzed. The potential use of the PVA‐based hydrogels as hydraulic fracturing liquids is discussed in relation to the commonly used fracturing liquid based on the guar–borax system. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

改造加热炉系统 提高加热炉热效率

分析了重整装置加热炉热效率低的原因，介绍了提高加热炉热效率采取的几项措施。     

火炮磁流变后坐系统仿真

将磁流变技术应用于火炮反后坐装置是目前正在发展的一种降低火炮后坐力的新技术,优化火炮反后坐装置控制,达到实时调节阻力。针对某型号火炮,在建立动力学模型和电磁模型的基础上设计了磁流变反后坐系统。为实现理想的后坐控制规律,提出了PID和模糊控制算法。利用ADAMS和MATLAB进行联合仿真,仿真结果表明,在后坐行程范围内,最大后坐阻力分别为3.71×105N,3.53×105N,相比传统火炮减小了13%和17%,并且模糊控制的后坐阻力曲线具有良好的"平台效应",实现了控制目标,表明磁流变阻尼器良好的可控性和应用于火炮后坐系统中的可行性。     

磁流变阻尼器内部流体动能的能量采集

为了构建自供能式磁流变阻尼器内部实时状态监测传感系统,本文介绍了一种针对磁流变阻尼器内部流体能的能量采集装置。该装置被安装于磁流变阻尼器活塞顶端并为检测阻尼器内部工作参数的无线传感模块1供电。根据能量守恒定律,推导出磁流变阻尼器中磁流变液流动能的理论模型。通过实验测试分析了在不同的外界激励下能量采集装置的工作情况,证明了采集的电能随着活塞的运动频率增加而增加,而与磁流变阻尼器的磁流变特性没有明显的关系。测试表明利用此装置能较好的采集到来自于磁流变阻尼器内部流体流动产生的能量,为无线传感模块供电。