氯气氧化硫化钴渣浸取钴镍

本文介绍用氯气氧化硫化钴渣浸取钴镍的工艺及试生产情况、一次浸出率可达88％以上,是从硫化钴渣回收钴、镍的有效途径。     

硫脲法从低品位含金硫化矿及其焙砂酸浸渣中回收金

本工作采用硫脲法从钴铜硫化矿及其经硫酸化焙烧,酸浸钴铜后的渣中对低品位金进行了浸取研究.直接浸取硫化矿,金的溶出率低,操作参数如电位、pH值等不稳定,试剂耗量大;而从酸浸渣中浸取金的溶出率高,可达91.0%以上,数据重现性好,试剂消耗大大降低,操作稳定.优化了浸取条件,从而降低了硫脲消耗,耗量是1.78kg/t矿.最后,用还原铁粉和活性炭从硫脲浸取富液中回收金进行了探索,效果良好.试验结果表明,硫脲法具有潜在的工业性应用推广价值.     

常压酸浸铁闪锌矿制取硫酸锌工艺研究

运用正交设计优化试验法，研究了常压浓硫酸浸取铁闪锌矿制取硫酸锌的工艺条件，发现温度为１５０－１８０℃，硫酸浓度为４０－６０％，浸取时间为２小时，锌浸取率达９０％以上。     

细磨活化对白钨矿浸取行为的影响SCIEI

本文研究了细磨活化对白钨矿浸取行为的影响.实验结果表明,细磨活化后白钨矿在HCl-Na_3PO_4介质中的浸出速率显著加快,钨的浸出率由原来的约8％提高到99％以上.红外光谱和X射线分析结果表明,细磨除了使白钨矿比表面积显著增大外,还在固体的表面和内部产生缺陷结构,增加了矿物表面的反应活性,改善了白钨矿的分解,使得白钨矿的浸出能在较低的温度顺利进行。     

硫酸根存在下硫代硫酸铵溶液浸出硫化金精矿中金的动力学研究

含铜的氨性硫代硫酸铵溶液浸取合铜硫化金精矿中金的反应过程分为前期反应、后期反应两个阶段。前期为界面反应控制,后期为反应剂通过固体反应产物层的扩散过程控制。整个浸取过程都受载金矿物腐蚀反应所控制。体系中硫酸铵可能有两种作用:①NH_4~ 与NH_3组成缓冲液;②SO_4~(2-)抑制S_2O_3~(3-)氧化分解。体系中Cu~(2 )作为氧化剂,氧气使Cu~(2 )再生。     

Study on bioleaching of primary chalcopyrite ore with thermoacidophilic archae

A high temperature-tolerating thermoacidophilic archae （TA） was isolated from water samples collected from a hot sulfur-containing spring in the Yunnan Province, China, and was used in bioleaching experiments of a low-grade chalcopyrite ore. The TA grow at temperatures ranging from 40 to 80℃, with 65℃ being the optimum temperature, and at pH values of l.5 to 4.0, with an optimum pH value of 2.0. The bioleaching experiments of the chalcvpyrite ore were conducted in both laboratory batch bioreactors and leaching columns. The results obtained from the bioreactor experiments showed that the TA bioleaching rate of copper reached 97% for a 12-day leaching period, while the bioleaching rate was 32.43% for thiobacillus ferrooxidans （Tf） leaching for the same leaching time. In the case of column leaching, tests of a two-phase leaching （196 days）, that is, a two-month （56 days） Tf leaching in the first phase, followed by a 140-day TA leaching in the second phase were performed. The average leaching rate of copper achieved for the 140-day TA leaching was 195mg/（L.d）, while for the control experiments, it was as low as 78mg/（L .d） for the Tf leaching, indicating that the TA possesses a more powerful oxidizing ability to the chalcopyrite than Tf Therefore, it is suggested that the two-phase leaching process be applied to .for the heap leaching operations, whereas, the TA can be used in the second phase when the temperature inside the heap has increased, and the primary copper sulfide minerals have already been partially oxidized with Tf beforehand in the first phase.     

天青石矿石中碳酸锶的测定

经实验研究，选用氯化铵-氯化锶为浸取液，有效浸取天青石矿石中的碳酸锶（SrCO3），20mL浸取液可浸取SrCO3达500mg，而SrSO4溶解度降低到最低限度（0．1％），石膏的干扰先用水浸取除去。经过条件实验、标准回收、样品测定，收到了令人满意的结果。方法的重现性和准确度较好。适用于天青石中少量碳酸锶的测定，也适用于菱锶矿中碳酸锶的测定。