Experimental study and model predictions on helium release in an enclosure with single or multiple vents

This paper presents experiments performed at Canadian Nuclear Laboratories (CNL) to examine the dispersion behaviour of helium in a polycarbonate enclosure that was representative of a residential parking garage. The purpose was to gain a better understanding of the effect of buoyancy- or wind-driven natural ventilation on hydrogen dispersion behaviour. Although hydrogen dispersion studies have been reported extensively in the literature, gaps still exist in predictive methods for hazard analysis. Helium, a simulant for hydrogen, was injected near the centre of the floor with a flow rate ranging from 5 to 75 standard litres per minute through an upward-facing nozzle, resulting in an injection Richardson number ranging between 10^?1 and 10². The location of the nozzle varied from the bottom of the enclosure to near the ceiling to examine the impact of the nozzle elevation on the development of a stratified layer in the upper region of the enclosure. When the injection nozzle was placed at a sufficiently low elevation, the vertical helium profile always consisted of a homogenous layer at the top overlaying a stratified layer at the bottom. To simulate outdoor environmental conditions, a fan was placed in front of each vent to examine the effect of opposing or assisting wind on the dispersion. The helium transients in the uniform layer predicted with analytical models were in good agreement with the measured transients for most tests. Model improvements are required for adequately predicting transients with primarily stratified profiles or strong opposing wind.     

Se doped nickel-molybdenum bimetal sulfide with enhanced electrochemical activity for hydrogen evolution reaction

In this work, we synthesized Se doped MoS₂@Ni₃S₂ with nanosheets coated nanorods structure supported on Ni foam (MoNiSeS). Firstly, MoS₂@Ni₃S₂ (MoNiS) nanorods was synthesized by hydrothermal method. After selenization treatment, MoSe₂ successfully formed on the edge of MoS₂ nanosheets and particle Ni₃S₂ transformed into NiSe, in which MoSe₂ and NiSe acted as new phase in MoNiSeS. The obtained MoNiSeS only needs a low overpotential of 68 mV to reach the current density of 10 mA cm^?2, and has a low Tafel plots of 72.77 mV dec^?1 and good electrochemical durability, whose electrochemical activity is much better than that of MoNiS and NiSeS, implying the introduction of Mo and Se is beneficial to improve the electrocatalytic performance of NiS for HER. In addition, the proper amount of Mo source, which has an effect on the morphology of product, has also been investigated. For MoNiSeS, the typical nanosheets coated nanarods expose more active sites and the synergic effects is good to the improvement of the catalytic activity. Meanwhile, WNiSeS has also been prepared using the same method and the corresponding results show that the electrochemical activity of WNiSeS is much better than that of NiSeS, proving the universality of this strategy.     

利用整合区域特性约束提高孔隙率模拟精度

本文将空间结构变化的要求与动态资料确定的储量共同作为约束,建立了包含两个约束条件的目标函数, 应用模拟退火算法对孔隙率的空间分布进行预测。在实现过程中,通过初始控制参数的给定及目标函数修改提高了运算效率。由于目标函数有效地整合了静、动态信息,从而降低了模拟结果的不确定性．提高了模拟的精度。合成数据及实际数据的模拟试验表明,整合区域特性约束不仅提高了孔隙率模拟精度,而且算法收敛快、稳定性高。     

陆东凹陷油气藏烃类组成非均质性及其意义

陆东凹陷原油和油砂抽提物中烃类的宏观组成存在着明显的非均质性。在高孔隙度(>15%)储层单元中,饱和烃的含量高,占总组成的含量均大于40%,而极性化合物则相对较低,一般不足40%;相反,在低孔隙度(<15%)储层单元中,饱和烃的含量明显降低,而极性化合物则显著增加。此外,陆东凹陷原油和油砂抽提物中烃类成熟度亦存在着非均质性:在高孔隙度储层中,原油和油砂烃类的成熟度参数高,而在低孔隙度储层中原油和油砂烃类的成熟度参数低。根据原油和油砂抽提物中烃类的宏观组成特征和成熟度参数的变化规律,提出了陆东凹陷油气聚集模式。     

义东油田大81-4块咸化湖泊生物礁储集层特征

义东油田位于济阳坳陷沾化凹陷义东断裂带，该油田大81—4块沙四段成化湖泊生物礁复合体自下而上可分为5个小型礁体(2个藻礁，3个藻礁丘体)。根据岩心观察、镜下鉴定和钻井等资料，主要有3种岩石类型：白云岩类是下部藻礁的主体，灰岩类是礁丘相的主体，其它岩类(主要为碎屑岩类和盐岩)分布局限；储集空间主要有7种类型(粒间孔隙、粒内孔隙、铸模孔隙、生长骨架孔隙、角砾间孔隙、晶间孔隙和构造裂缝）。该生物礁复合体位于凸起边缘的断阶带平台，发育于有陆源碎屑供给的半清水水域，紧邻深水区。礁体形成后经历了深埋藏成岩期，对储集空间演化影响最大的成岩作用是白云石化作用、溶解作用、新生变形作用和胶结作用。预测大81—221井区及附近的2个枝管藻白云岩礁体为最有利的勘探目标，义东22井附近生物礁也有良好的勘探前景。     

专用汉字库在仿真系统中的应用

本文介绍了一种专用汉字库的建立与管理方法，由该方法建立的汉字库具有使用灵活、维护方便、占用内存少、显示速度快等特点。它不仅用于计算机仿真系统，也可用于其它计算机应用系统。     

既有钢筋混凝土框架结构抗震加固若干问题探讨

针对钢筋混凝土框架结构抗震加固问题的复杂性 ,本文深入分析了抗震加固结构的受力特征 ,探讨了卸荷对加固构件承载力的影响 ,并针对抗震加固后的“隐含危险转移”问题提出了相应的对策。最后 ,提出了抗震加固的基本原则 ,可供结构抗震加固时参考     

酯酶活性与柞蚕部分经济性状的关系

幼虫消化液酯酶活性与中肠酯酶活性表现出一定的负相关关系，消化液酯酶活性与全茧量、蛹重存在显正相关关系，中肠酯酶活性和茧层率性状呈显正相关关系，卵的酯酶活性与茧质性状呈高度正相关。酯酶活性与茧质性状的杂种优势率的强弱表现也一致。因此可以认为Fl代消化液酯酶和中肠酯酶活性的提高是茧质性状杂种优势形成的原因之一。酯酸活性可用来预测F1代的茧质性状的优劣。     

秦岭金矿9~#脉主要矿物特征及矿物学标志

小秦岭地区金矿床严格受构造控制，各成矿阶段及矿物学特征明显，通过对矿物学特征的研究找出矿物学标志，认为今后找矿要注意各阶段石英的颜色、黄铁矿中金的含量以及矿石中银的含量，这些与金有密切关系.     

核素^147Pm在细胞内滞留的电镜放射自显影研究

木文用电镜放射自显影术研究了重核裂片~(147)Pm在体内亚细胞水平滞留动态。发现~(147)Pm的内污染沉积早期在血细胞和血管内皮细胞中,尤以在红细胞的沉积为多。~(147)Pm呈选择性滞留于肝细胞亚微结构中,可较多的掺入枯否细胞、肝细胞核和核仁内,在胞质中的糙面内质网、线粒体、微体和糖元中亦有滞留,且主要沉积于糙面内质网和线粒体,在高尔基复合体与糙面内质网所芽生的转移小泡融合处,亦有~(147)Pm滞留的放射自显影象。而在肾小体足细胞的线粒体和溶酶体中,有浓集的放射自显影径迹呈现。在肾近端小管曲部上皮细胞核中和胞质的线粒体和微体中,亦有较多的~(147)Pm滞留。 随着观察时间的延续,~(147)Pm在骨有机质亚微结构中呈现选择性、持续性的沉积增多。可浓集于破骨细胞和成骨细胞核中。此外在骨组织细胞间质中的胶原纤维部位,亦有较多的~(147)Pm沉积,难以排除。