高速钢W6Mo5Cr4V2的脱磷试验

在３０ｋｇ感应炉上用ＣａＯ－Ｎａ２ＣＯ３－ＣａＦ２－ＦｅｘＯ（ＭｏＯ３）渣、ＭｏＣｌ６粉剂和Ａｌ－Ｃａ合金作脱磷剂对高速钢Ｗ６Ｍｏ５Ｃｒ４Ｖ２进行脱磷试验。结果表明，ＣａＯ－Ｎａ２ＣＯ３－ＣａＦ２－ＦｅｘＯ渣的脱磷效果最好，一般脱磷率可达２６％￣５６％。     

超低碳奥氏体不锈钢00Cr18Ni10还原脱磷研究

在 2 5kg真空感应炉上用镁钙合金对超低碳奥氏体不锈钢 0 0Cr18Ni10进行了还原脱磷试验。通过充入工业纯氩使炉内压力为 6 6 .6 6kPa和精炼时的反应温度 14 5 0～ 15 0 0℃ ,加入镁钙合金 5 0kg t和助熔剂CaF2 11kg t,可使精炼后 0 0Cr18Ni10的磷含量进一步降低到 (5 0～ 6 0 )× 10 - 6 ,钢中氧、硫含量分别稳定降到(4～ 6 )× 10 - 6 和 15× 10 - 6 。     

Li2O对CaO基钢包渣系脱磷能力影响的热力学研究

渣金平衡实验表明Li2 O替代CaO基钢包渣系中等量CaO使渣系磷酸盐容量Cp提高。在此基础上进行钢液脱磷的工艺性实验 ,研究了Li2 O含量、渣系碱度及氧化性对渣系脱磷能力的影响 ,并给出了控制转炉钢液在钢包中回磷及钢包渣脱磷的渣系。     

应用转炉渣对铁水预脱硅脱磷的实验研究

转炉渣中添加CaF2助熔剂降低其熔化温度可用于铁水预处理。实验确定合适的CaF2添加量为15%~20%。在此基础上,应用转炉渣对铁水进行脱硅、脱磷预处理实验。结果表明,采用转炉渣(80%)-CaF2(20%)的转炉渣剂对铁水脱硅、脱磷预处理,相应的脱硅、脱磷率可分别达到70%和78%左右。在1350℃~1450℃的温度范围内,温度的升降明显影响铁水脱硅、脱磷率。     

模式识别方法研究影响转炉炼钢脱磷的因素

利用模式识别方法中的偏最小二乘法对转炉炼钢的磷分配比及主要影响因素进行了分析 ,用二维分类图给出了优化趋势 ,结果符合一般脱磷理论和实际 ,可以作为冶炼的参考。     

A novel control algorithm for dephosphorization in an LD converter

This paper proposes a new control algorithm for dephosphorization in the steelmaking process using a LD converter. The control algorithm is composed of two steps, which achieves a low phosphorous content in the hot metal after treatment. The first step creates target concentration for the iron oxide in the slag for the next heat, which is optimal to achieve effective dephosphorization. The target concentration is obtained after applying independent component analysis (ICA) to the concentration data of past heats. The second step decides the control inputs for the next heat, namely the oxygen blowing rate and the lance height by calculating a weighted summation of past control inputs. The weight is based on the difference between the target concentration and concentration of each past heat. The proposed algorithm was applied to an actual process, and the results showed high control performance at the end of this paper.     

60 t Consteel电弧炉-60 t LF(VD)冶炼60Si2CrVAT弹簧钢的工艺实践

西宁特钢采用60 t Consteel电弧炉-60 t LF(VD)-700 kg铸锭工艺生产60Si2CrVAT弹簧钢(%)0.56～0.64C,1.40～1.80Si,0.90～1.20Cr,0.10～0.19V,≤0.020P,≤0.020S.Consteel电弧炉偏心底出钢留渣作业,熔炼温度控制在1 560～1 590 ℃,冶炼全过程泡沫渣长弧操作,可使电弧炉出钢时钢水中磷含量≤0.015%,LF精炼时加铝脱氧,氩气搅拌,控制钢中全铝含量为0.025%～0.050%,并经VD处理使钢中氧含量达(9～12)×10-6,氢含量为(0.6～0.9)×10-6.检验结果表明,钢中A细类夹杂≤1.0级,B细类夹杂为0.5级,其余为0级.     

Prospect of Refractory for Hot Metal Pretreatment

The paper describes the recent developing situation and the latest research achievements of refractory for hot metal pretreatment. The relationship among desiliconization, dephosphorization and desulphurization techniques and the main corrosion reactions by various treating agents is analyzed. Some improving measures for several problems in practice are put forward while we anticipate the future developing direction of refractory for hot metal pretreatment.     

CaO—CaF_2—SiO_2熔剂脱磷脱硫特性的研究

在 P_(co)=1atm,1300℃条件下研完了 CaO-CaF_2-SiO_2三元渣用作中磷铁水预处理熔剂进行脱磷脱硫的特性。研究结果表明:CaO饱和的 CaO-CaF_2-SiO_2三元渣具有很强的同时脱磷脱硫能力,组成为48%CaO、22%SiO_2、30%CaF_2的渣的磷容量为10~(25),硫的分配系数10~3以上。     

高磷铁矿含碳球团还原熔分脱磷

通过对高磷铁矿中磷灰石还原机理的分析,发现配加碱性添加剂有利于抑制磷灰石还原,减少珠铁中磷含量。试验首先向含碳球团中配加CaCO3调节碱度,并在此基础上分别添加Na2CO3、CaF2,研究碱度和添加剂对球团还原熔分后珠铁和渣中磷含量的影响,得到磷的分配情况。试验结果表明:提高碱度,配加Na2CO3、CaF2均有利于抑制高磷铁矿中磷灰石的还原,降低珠铁中的磷含量。在1 400℃,碱度为1.4,Na2CO3、CaF2的质量分数均为4%,反应时间为12min时,珠铁中磷含量达到最低,脱磷率达到81.2%。