A simulation study of reduction kinetics for sponge iron production in a rotary hearth furnace

ABSTRACT

A mathematical model has been developed by coupling genetic algorithm (GA) with heat and material balance equations to estimate rate parameters and solid-phase evolution related to the reduction of iron ore-coal composite pellets in a multi-layer bed Rotary hearth Furnace (RHF). The present process involves treating iron ore-coal composite pellets in a crucible over the hearth in RHF. The various solid phases evolved at the end of the process are estimated experimentally, and are used in conjunction with the model to estimate rate parameters. The predicted apparent activation energy for the wustite reduction step is found to be lower than those of the reduction of higher oxides. The thermal efficiency is found to decrease significantly with an increase in the carbon content of the pellet. Thermal efficiency was also found to increase mildly up to three layers. Multilayer bed remains as a potential design parameter to increase thermal efficiency.     

预分解窑燃无烟煤生产水泥熟料技术及其应用

无烟煤着火温度高、燃烧速度低、燃烬时间长,故一直难以用作回转窑燃料.20世纪90年代,南京院率先进行了回转窑燃无烟煤生产的研究开发.经10多年的努力,解决了所有的技术问题,开发了配套的专有装备,已在福建三德水泥厂、福建南平水泥公司、龙岩春池集团、广西鱼峰水泥公司等厂的多条生产线上应用并获巨大成功.     

金属管式换热器在气烧石灰竖窑上的应用

气烧石灰竖窑针对窑型产能较低、能耗较高的弊端,韶钢在新建气烧石灰竖窑上采用的双预热技术,使窑的产量提高47.5％,活性度提高每10min在20ml以上,能耗降低35.62％,经济效益明显.     

Studies on the microstructure of the black-glazed bowl sherds excavated from the Jian kiln site of ancient China

The Jian kiln, located in present-day Jianyang county of Fujian province, mainly produced black-glazed tea bowls. Jian tea bowl was used as a utensil for tea tasting and was greatly appreciated by emperor Huizong of the Northern Song dynasty. The black glaze of Jian bowl was sometimes marked with streaks or spots, usually called “hare's fur” or “oil spot”, which are the crystalline markings of iron oxide precipitated during firing in the dragon kiln. In this study, black-glazed Jian bowl sherds excavated from the late Northern Song strata of Luhuaping and Daluhoumen Jian kiln sites were adopted as test samples. Based on the physico-chemical foundation for the formation of glaze microstructure, the correlation among composition, microstructure, and visual appearance has been investigated by means of energy-dispersive X-ray fluorescence, X-ray diffraction, and field emission electron microscopy. For the first time, the study provides realizing proofs for two kinds of microstructural forming mechanics.     

富氧燃烧技术在梭式窑中的应用

研究了富氧燃烧技术对梭式窑烧成的影响.研究结果表明,随着氧浓度从21%-30%的逐渐增加,CO总浓度和NO总浓度都先明显下降,后缓慢上升;节能效果在初始段较为明显,而后效果不明显;而实际烟气量与氧浓度成反比,与过剩空气系数成正比.     

钛精矿回转窑直接还原过程结圈可能性的探讨

通过煤种，入窑球冷态强度和还原过程强度，以及钛精矿与煤灰混合物的软化温度等分析探讨了钛精矿预热球团回转窑直接还原产生结圈的可能性，获得了可以避免结圈的结论。     

New rotary valves for pulse-tube refrigerators

In most used rotary valves in GM-type pulse-tube refrigerators the rotor makes heavy mechanical contact with the stator, so the valve is liable to wear, and large torques are needed. In this paper we will describe two types of valves, which have balanced forces on the rotor. In the first valve the rotor and the stator make no mechanical contact. The second type is a contact valve, like the classical valves, but the forces on the rotor are balanced in a different way. Therefore, these valves are less liable to wear, and the torques needed to rotate the valves are small.     

机械化竖窑技术和节能特性简介

鞍钢耐火公司新建两座430m^3机械化石灰竖窑，与普通窑炉相比具有热耗低、石灰活性高、燃料适应性强、结构简单的特点。     

回转窑窑体变形的一种实时监测与报警系统

针对回转窑在运行过程中窑体变形的情况开发了一种监测与报警系统。完成了系统的前向通道设计、单片机与PC机的串行通讯设计和报警显示。     

高温对冶金窑窑体的影响

针对冶金回转窑窑体在高温下产生的失效进行数值分析，并在此基础上对冶金窑窑体的设计方法进行修正。