全文获取类型
收费全文 | 17958篇 |
免费 | 2430篇 |
国内免费 | 1776篇 |
专业分类
电工技术 | 1964篇 |
综合类 | 1856篇 |
化学工业 | 1312篇 |
金属工艺 | 486篇 |
机械仪表 | 2019篇 |
建筑科学 | 643篇 |
矿业工程 | 510篇 |
能源动力 | 620篇 |
轻工业 | 353篇 |
水利工程 | 263篇 |
石油天然气 | 323篇 |
武器工业 | 786篇 |
无线电 | 3094篇 |
一般工业技术 | 2747篇 |
冶金工业 | 550篇 |
原子能技术 | 339篇 |
自动化技术 | 4299篇 |
出版年
2024年 | 83篇 |
2023年 | 372篇 |
2022年 | 532篇 |
2021年 | 569篇 |
2020年 | 674篇 |
2019年 | 607篇 |
2018年 | 565篇 |
2017年 | 687篇 |
2016年 | 788篇 |
2015年 | 853篇 |
2014年 | 1129篇 |
2013年 | 1067篇 |
2012年 | 1391篇 |
2011年 | 1424篇 |
2010年 | 1051篇 |
2009年 | 1054篇 |
2008年 | 1080篇 |
2007年 | 1242篇 |
2006年 | 1095篇 |
2005年 | 918篇 |
2004年 | 782篇 |
2003年 | 681篇 |
2002年 | 559篇 |
2001年 | 524篇 |
2000年 | 459篇 |
1999年 | 349篇 |
1998年 | 286篇 |
1997年 | 264篇 |
1996年 | 190篇 |
1995年 | 144篇 |
1994年 | 180篇 |
1993年 | 112篇 |
1992年 | 94篇 |
1991年 | 69篇 |
1990年 | 52篇 |
1989年 | 48篇 |
1988年 | 38篇 |
1987年 | 23篇 |
1986年 | 21篇 |
1985年 | 31篇 |
1984年 | 18篇 |
1983年 | 10篇 |
1982年 | 12篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1975年 | 3篇 |
1959年 | 5篇 |
1956年 | 2篇 |
1955年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(80):33955-33965
We report the study of conductive polyaniline (PANI) chain embedded Ti-MOF functionalized with CoS as a cocatalyst for hydrogen evolution reaction (HER) application. The post synthetically modified hybrid photocatalyst PANI/Ti-MOF/CoS greatly influences the redox and e? ? h+ separation process and exhibits an impressive rate of HER (~1322 μmol h?1g?1), suppressing the pristine Ti-MOF (~62 μmol h?1g?1) with apparent quantum yield (AQY) of ~3.2 and transient current response of ~46.4 μA cm?2. In this system, Ti-MOF provides the circulation of Ti3+ and Ti4+ to the reaction of photocatalytic H2 generation, where the additional PANI and CoS amended the performance of H2 production through electron enrichment and thereby improving the stability and integrity of Ti-MOF. The Electrochemical studies demonstrated increased photocurrent by interweaving Ti-MOF crystal with PANI through cation-π interaction thereby enhancing interface connection and then promoting electron transfers. The charge dynamics revealed the initial charge transfer from photoexcited PANI to encapsulated MOF framework to boost the photocatalytic performance of the system. Further, the electron movement at the Ti-MOF/CoS interface is investigated through work function and electrochemical potential of electrons (Fermi level). DFT results demonstrate the importance of CoS in improving the photocatalytic performance of hybrid Ti-MOF catalyst, which leads to superior catalytic behaviour. These results establish that the encapsulation of catalytic active sites inside MOFs with desirable energy band gaps would be an ideal choice for the production of solar fuels. 相似文献
2.
Electric nanogenerators that directly convert the energy of moving drops into electrical signals require hydrophobic substrates with a high density of static electric charge that is stable in “harsh environments” created by continued exposure to potentially saline water. The recently proposed charge-trapping electric generators (CTEGs) that rely on stacked inorganic oxide–fluoropolymer (FP) composite electrets charged by homogeneous electrowetting-assisted charge injection (h-EWCI) seem to solve both problems, yet the reasons for this success have remained elusive. Here, systematic measurements at variable oxide and FP thickness, charging voltage, and charging time and thermal annealing up to 230 °C are reported, leading to a consistent model of the charging process. It is found to be controlled by an energy barrier at the water-FP interface, followed by trapping at the FP-oxide interface. Protection by the FP layer prevents charge densities up to −1.7 mC m−2 from degrading and the dielectric strength of SiO2 enables charge decay times up to 48 h at 230 °C, suggesting lifetimes against thermally activated discharging of thousands of years at room temperature. Combining high dielectric strength oxides and weaker FP top coatings with electrically controlled charging provides a new paradigm for developing ultrastable electrets for applications in energy harvesting and beyond. 相似文献
3.
This article proposes an active balancer, which features bidirectional charge shuttling and adaptive equalization current control, to fast counterbalance the state of charge (SOC) of cells in a lithium-ion battery (LIB) string. The power circuit consists of certain bidirectional buck-boost converters to transfer energy among the different cells back and forth. Owing to the characterization of the open-circuit voltage (OCV) vs SOC in LIB being relatively smooth near the SOC middle range, the SOC-inspected balance strategy can achieve more precise and efficient equilibrium than the voltage-based control. Accordingly, a compensated OCV-based SOC estimation is put forward to take into account the discrepancy of SOC estimation. Besides, the varied-duty-cycle (VDC) and curve-fitting modulation (CFM) methods are devised herein to tackle the problems of slow equalization rate and low balance efficacy, which arise from the diminution in balancing current as the SOC difference between the cells decreases in the later duration of equalization especially. The proposed strategies have taken the battery nonlinear characteristic and circuit parameter nonideality into account and can adaptively modulate the duty cycle with the SOC difference to keep balancing current constant throughout the balancing cycle. Simulated and experimental results are given to demonstrate the feasibility and effectiveness of the same prototype constructed. Compared with the fixed duty cycle and the VDC methods, the proposed CFM has the best balancing efficiency of 81.4%, and the balance time is shortened by 27.1% and 18.6%, respectively. 相似文献
4.
Spinel LiSr0·1Cr0·1Mn1·8O4 was synthesised by high temperature solid state method in order to enhance the electrochemical performance. The LiSr0·1Cr0·1Mn1·8O4 (LSCMO) materials were characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical tests. The XRD and SEM studies confirm that LSCMO had spinel crystal structure with a space group of Fd3m, and the particle of LSCMO shows irregular shape. The cyclic voltammetry data illustrated that the heavy current charge–discharge performance of LMO was improved by Sr2+ and Cr3+ doping. The galvanostatic charge–discharge of LSCMO cathode materials was measured at 1, 5, 10 and 20 C. The results indicated that LSCMO improved the capacity retention. 相似文献
5.
为了研究径向不耦合条件下爆破效果的影响因素,利用AUTODYN-2D对比不耦合系数、不耦合介质、炸药种类对爆破效果的影响规律。结果表明,与耦合装药相比,径向不耦合装药条件下炮孔压力明显降低。对比水介质和空气介质下的爆破效果可知,水介质不耦合条件下,炸药爆炸能量的传递效率更高。炮孔压力与炸药种类密切相关,TNT产生的炮孔压力最大,但作用时间较短,而ANFO和乳化炸药的作用时间较长。 相似文献
6.
针对基于容积脉搏波(PPG)提取运动心率时,传统心率提取算法由于运动噪声干扰使测量结果误差大、实时性不好的问题,提出一种抗运动干扰的实时心率提取方法。该方法通过实时小波去噪,同时结合三轴加速度信号(ACC)对运动进行分类训练,计算各运动状态心率增益,对实时心率值进行补偿。实验结果表明,通过与同时采集的ECG信号计算出的实时心率进行对比,绝对误差率仅为1.2%左右。相比传统心率提取算法,该算法具有抗干扰性强,实时准确的特点。 相似文献
7.
Highly accurate real‐time localization is of fundamental importance for the safety and efficiency of planetary rovers exploring the surface of Mars. Mars rover operations rely on vision‐based systems to avoid hazards as well as plan safe routes. However, vision‐based systems operate on the assumption that sufficient visual texture is visible in the scene. This poses a challenge for vision‐based navigation on Mars where regions lacking visual texture are prevalent. To overcome this, we make use of the ability of the rover to actively steer the visual sensor to improve fault tolerance and maximize the perception performance. This paper answers the question of where and when to look by presenting a method for predicting the sensor trajectory that maximizes the localization performance of the rover. This is accomplished by an online assessment of possible trajectories using synthetic, future camera views created from previous observations of the scene. The proposed trajectories are quantified and chosen based on the expected localization performance. In this study, we validate the proposed method in field experiments at the Jet Propulsion Laboratory (JPL) Mars Yard. Furthermore, multiple performance metrics are identified and evaluated for reducing the overall runtime of the algorithm. We show how actively steering the perception system increases the localization accuracy compared with traditional fixed‐sensor configurations. 相似文献
8.
9.
This paper proposes a novel optimization algorithm inspired by the ions motion in nature. In fact, the proposed algorithm mimics the attraction and repulsion of anions and cations to perform optimization. The proposed algorithm is designed in such a way to have the least tuning parameters, low computational complexity, fast convergence, and high local optima avoidance. The performance of this algorithm is benchmarked on 10 standard test functions and compared to four well-known algorithms in the literature. The results demonstrate that the proposed algorithm is able to show very competitive results and has merits in solving challenging optimization problems. 相似文献
10.
Electrical Breakdown Properties and Space Charge Formation in High Temperature Region in Ultraviolet Ray Irradiated PVC 下载免费PDF全文
Polyvinyl chloride (PVC) is the most popular insulating material for electric wiring instruments. However, an exothermic reaction above 150 °C may cause deterioration of the insulating properties of PVC. Therefore, it is important to clarify the heat degradation in PVC, not only to investigate the ignition of electrical wiring products but also to use electrical products safely. It is known that ultraviolet (UV) irradiation causes chemical deterioration of PVC and an increase in its conductivity. Generally, it has been thought that the electrical breakdown properties, electrical conduction, and insulating performance are affected by space charge accumulation in an insulating material. A high temperature pulsed electroacoustic (PEA) system usable up to 250 °C has been developed, and the PEA system can measure the space charge distribution and conduction current in the high temperature range simultaneously. In this investigation, the space charge distribution and conduction current were measured up to electrical breakdown in a non‐UV irradiated sample (normal PVC) and in 353 nm and 253 nm UV‐irradiated PVC samples in the range from room temperature to 200 °C in a DC electric field. In the short wavelength UV irradiated PVC sample (253 nm, 300 h), a deterioration of breakdown strength at 90 °C to 150 °C and negative packet‐like charges were observed at 60 °C and 100 °C, a positive charge accumulated in front of both the anode and cathode above 90 °C, and a higher electric field near the cathode side because the positive charge of the cathode side was greater. 相似文献