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排序方式: 共有3354条查询结果,搜索用时 31 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(80):33919-33937
Development of efficient, low cost and multifunctional electrocatalysts for water splitting to harvest hydrogen fuels is a challenging task, but the combination of carbon materials with transition metal-based compounds is providing a unique and attractive strategy. Herein, composite systems based on cobalt ferrite oxide-reduced graphene oxide (Co2FeO4) @(rGO) using simultaneous hydrothermal and chemical reduction methods have been prepared. The proposed study eliminates one step associated with the conversion of GO into rGO as it uses direct GO during the synthesis of cobalt ferrite oxide, consequently rGO based hybrid system is achieved in-situ significantly, the optimized Co2FeO4@rGO composite has revealed an outstanding multifunctional applications related to both oxygen evolution reaction (OER) and hydrogen counterpart (HER). Various metal oxidation states and oxygen vacancies at the surface of Co2FeO4@rGO composites guided the multifunctional surface properties. The optimized Co2FeO4@rGO composite presents excellent multifunctional properties with onset potential of 0.60 V for ORR, an overpotential of 240 mV at a 20 mAcm?2 for OER and 320 mV at a 10 mAcm?2 for HER respectively. Results revealed that these multifunctional properties of the optimized Co2FeO4@ rGO composite are associated with high electrical conductivity, high density of active sites, crystal defects, oxygen vacancies, and favorable electronic structure arisinng from the substitution of Fe for Co atoms in binary spinel oxide phase. These surface features synergistically uplifted the electrocatalytic properties of Co2FeO4@rGO composites. The multifunctional properties of the Co2FeO4@ rGO composite could be of high interest for its use in a wide range of applications in sustainable and renewable energy fields. 相似文献
2.
Mohammad Afshari Amir-Reza Rouhani Isfahani Saeed Hasani Fatemeh Davar Khadijeh Jahanbani Ardakani 《International Journal of Applied Ceramic Technology》2019,16(4):1612-1621
In the present study, spinel structure CoFe2O4 nanoparticles were successfully synthesized by the sol-gel auto-combustion technique. The effect of apple cider vinegar (ACV) addition as an organic biocompatible agent on the size, morphology, and magnetic properties of CoFe2O4 nanoparticles was investigated in detail. The phase evolution, particle size, and lattice parameter changes of the synthesized phase have been estimated by using Rietveld structure refinement analysis of X-ray powder diffraction data. Also, Fourier transform infrared spectra (FT-IR) of the samples verified the presence of two expected bands correspond to tetrahedral and octahedral metal-oxygen complexes within the spinel structure. Furthermore, microstructural observations revealed that ultrafine particles have a semi-spherical morphology. It was shown that the particles size decreased from ~45 to ~17 nm with an increase in the amount of ACV. Magnetic properties were carried out by vibrating sample magnetometer (VSM) at room temperature. Both the saturation magnetization (Ms) and coercivity (Hc) were found to be significantly dependent on the crystallite size and the amount of ACV. 相似文献
3.
Carbon supported bimetallic Ru‐Co catalysts for H2 production through NaBH4 and NH3BH3 hydrolysis
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This work investigates the effect of the addition of small amounts of Ru (0.5‐1 wt%) to carbon supported Co (10 wt%) catalysts towards both NaBH4 and NH3BH3 hydrolysis for H2 production. In the sodium borohydride hydrolysis, the activity of Ru‐Co/carbon catalysts was sensibly higher than the sum of the activities of corresponding monometallic samples, whereas for the ammonia borane hydrolysis, the positive effect of Ru‐Co systems with regard to catalytic activity was less evident. The performances of Ru‐Co bimetallic catalysts correlated with the occurrence of an interaction between Ru and Co species resulting in the formation of smaller ruthenium and cobalt oxide particles with a more homogeneous dispersion on the carbon support. It was proposed that Ru°, formed during the reduction step of the Ru‐Co catalysts, favors the H2 activation, thus enhancing the reduction degree of the cobalt precursor and the number of Co nucleation centers. A subsequent reduction of cobalt and ruthenium species also occurs in the hydride reaction medium, and therefore the state of the catalyst before the catalytic experiment determines the state of the active phase formed in situ. The different relative reactivity of the Ru and Co active species towards the two investigated reactions accounted for the different behavior towards NaBH4 and NH3BH3 hydrolysis. 相似文献
4.
Amun Amri Ahmad Fadli Zhong-Tao Jiang Chun-Yang Yin M. Mahbubur Rahman Hantarto Widjaja Syamsu Herman Silvia Reni Yenti M. Miftahul Munir Gadang Priyotomo M. Iqbal Neni Frimayanti 《Ceramics International》2018,44(13):15274-15280
The copper and cobalt oxides composites coatings on aluminum substrates have been successfully synthesized via sol-gel method using nitrate-based sol precursors. The composites were characterized by X-ray Diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Field Emission Scanning Electron Microscopy (FESEM), Atomic Force Microscopy (AFM), and UV–Vis–NIR spectrophotometry. The sol-gel reactions were discussed and Molecular Dynamics (MD) simulation was integrated into the study to predict molecules assembly properties. The XRD analyses revealed that the CuO and the Co3O4 composites were formed after the annealing process with the average difference of the calculated lattice parameters compared to ICDDs was 1.17%. The surface electronic structure was mainly consisted of tetrahedral Cu(I), octahedral Cu(II), tetrahedral Co(II), octahedral Co(III) as well as surface, sub-surface and lattice oxygen O?. The XRD, XPS and MD simulation results showed that there was minimal (or possibly non-existing) indication of copper-cobalt mixed phase oxides formations. FESEM and AFM surveys revealed that the coating had a porous surface composed of interlinked nanoparticles in the range of ~?10 to ~?40?nm. UV–Vis–NIR reflectance spectra showed that the sol precursors concentration and the dip-drying cycle significantly influenced the absorptance value with optimum absorptance (α) of 88.7% exhibited by coating synthesized using sol concentration of 0.1?M and 10 dip-drying cycles. High absorptance value and simplicity in the synthesis process render the coatings to be very promising candidates for solar selective absorber (SSA) applications. 相似文献
5.
特大型桥梁工程地质勘察区域地壳稳定性研究 总被引:1,自引:0,他引:1
重大工程区域地壳稳定性研究,是工程前期工程地质勘察的重要内容之一,并越来越多地为工程建设所重视。大桥工程地质勘察以往对此涉及较少,也无明确的统一规定,以长江上所建特大桥为例,对此项工程作了些探索性的研究,重点研究的问题是:区域构造环境及构造变形,地壳结构和深部构造,新构造活动,断裂活动,地震活动等,为大桥建设宏观决策和抗震设计提供依据。 相似文献
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8.
采用化学共沉淀法作为钴蓝颜料的制备方法,探讨了主要工艺因素对制备钴蓝颜料性能的影响,对制备的样品进行了测试与表征。结果表明:Co2+和Al3+物质的量比为1∶2.5时,制备的钴蓝样品颜色饱和度与明度最高,沉淀剂为尿素时制得的样品的粒度最小,粒度分布比较均匀。前驱体的洗涤过程采取水洗加醇洗的方法可有效减少样品的硬团聚现象,且前驱体的最佳煅烧温度为950℃左右。 相似文献
9.
Kenzo Kitayama 《Journal of the American Ceramic Society》1992,75(6):1447-1451
Phase equilibria in the Ta-Co-O and Nb-Co-O systems have been studied at 1200°C at oxygen partial pressures from 10−0.68 to 10−13.50 atm for the former and from 10−0.68 to 10−13.30 atm for the latter. In both systems, M2 CoO6 and M2 Co4 O9 are stable ternary compounds under the experimental conditions, and a new phase, Nb5 Co2 O14 , has been identified. The Ta-Co-O system is simple, whereas the Nb-Co-O system is somewhat more complicated because of the extra phase. The lattice constants of the ternary compounds have been determined and compared with previous values. The standard Gibbs energies of reactions have been determined using oxygen partial pressures in equilibrium with three solid phases. 相似文献
10.
陕甘宁盆地中部奥陶系风化壳储层特征 总被引:5,自引:1,他引:4
陕甘宁盆地中部奥陶系风化壳碳酸盐岩储集层属于古岩溶型,主要储集空间是溶蚀孔洞。本文根据古岩溶成因及发育特征,利用毛细管压力曲线、铸体薄片、阴极发光及物性分析资料,综合研究了碳酸盐岩储层参数及其分布特征,探讨了孔、洞、缝组合关系并划分出4种储层类型,判别了储层的有效性,为天然气勘探及储量计算提供了地质基础资料。 相似文献