Influence of Se and Te substitutions at Tl-site of Tl(Ba,Sr)CaCu2O7 superconductor on the AC susceptibility and electrical properties

The Sr and Ba bearing Tl-1212 phase, Tl(Ba,Sr)CaCu₂O₇ is an interesting superconductor. The Sr only bearing TlSr₂CaCu₂O₇ is not easily prepared in the superconducting form. The Ba only bearing TlBa₂CaCu₂O₇ on the other hand does not show improvement in the transition temperature with elemental substitution. In this work the influence of multivalent Se (non-metal) and Te (metalloid) substitutions at the Tl-site of Tl_1-xM_x(Ba,Sr)CaCu₂O₇ (M = Se or Te) superconductors for x = 0–0.6 was studied. The samples were prepared via the conventional solid-state reaction method. XRD patterns showed a single Tl-1212 phase for x = 0 and 0.1 Se substituted samples. The critical current density at the peak temperature, T_p of the imaginary (χ”) part of the AC susceptibility (χ = χ’ +χ”), J_c-inter(T_p) for all samples was between 15 and 21 A cm⁻². The highest superconducting transition temperature was shown by the x = 0.3 Se-substituted sample (T_c-onset = 104 K, T_c-zero = 89 K, T_cχ’ = 104 K and T_p = 80 K). Te suppressed the superconductivity of Tl-1212 phase. The order of highest transition temperatures are as follows: Tl_1-xTe_x(Ba,Sr)CaCu₂O₇<Tl(Ba,Sr)CaCu₂O₇<Tl_1-xSe_x(Ba,Sr)CaCu₂O₇. This work showed that Se was better than Te in improving the transition temperature and flux pinning of the Tl-1212 phase. The roles of ionic radius of Se and Te on the superconductivity of Tl(Ba,Sr)CaCu₂O₇ are discussed in this paper.     

A mineralogical approach to evaluating laboratory scale acid rock drainage characterisation tests

Effective management of the risks associated with acid rock drainage (ARD) requires the ability to identify material with a potential to generate ARD reliably. With the increasing prevalence of quantitative mineralogy (Quantitative XRD, auto-SEM), opportunity exists to use mineralogy at all stages in ARD characterisation and prediction. This study uses a mineralogical approach across the head grade samples and the residues obtained under leach conditions of several common ARD characterisation tests (Acid Neutralising Capacity, Net Acid Generation), as well as the University of Cape Town (UCT) biokinetic test to evaluate the extent to which acid-neutralising minerals react. The results show the contribution of the carbonates to the acid neutralising capacity, as well as the partial dissolution of intermediate weathering silicate minerals such as chlorite and mica.     

储层泥浆侵入深度预测方法研究

泥浆侵入半径的确定尚缺乏严格的验证标准.以油水两相渗流理论和离子扩散方程为基础,结合储集层特点,研究了不同储层参数下泥浆滤液对地层的侵入特性.数值模拟侵入时间选取10 d和20 d.数值模拟结果表明,侵入半径在渗透率不变的情况下随孔隙度的增大而减小,在孔隙度不变的情况下随渗透率的增大而增大;当渗透率和孔隙度都发生变化时,泥浆侵入半径一般随孔隙度的增加呈幂函数增加.依据这种关系对测井资料约束处理,得到的泥浆侵入半径较客观地反映了地层的真实情况.     

对象族可镇定半径的计算

本文采用优化方法把计算对象族的可镇定半径问题转化成优化问题。2范数定义下的可镇定半径采用了Lagrange乘子法求解；无穷范数意义下的可镇定半径采用了最小范数解方法求解。本文方法对可镇定半径的定义形式和不确定参数结构没有要求，因此更具有一般性。     

普通稠油油藏启动压力梯度求解方法与应用

利用微观尺度管流模型,结合普通稠油流变特征,提出了在考虑稠油流变性条件下微观启动压力梯度计算方法.对渤海渤中18块不同渗透率岩心进行室内驱替实验,通过对实验数据的回归分析,得到不同粘度普通稠油油藏启动压力梯度与地层平均渗透率关系,并绘制了启动压力梯度的图版.将研究结果应用于普通稠油油藏,给出了利用启动压力梯度确定极限泄油半径及合理井距的理论计算方法.     

射孔枪+内置式压力计托筒+水力泵新三联作试油(测试)工艺技术在大港油田研制与应用

该工艺技术是在原三联作(TCP+MFE+JET)基础上,根据大港油田勘探试油(测试)的需要,研制开发出的又一新技术,与原三联作相比,一趟管柱不但完成求产、测压、泵排工作,而且还能进行酸化等措施,提高了资料品质,减少了作业成本。经过6井次现场应用,全部达到了设计要求,取得了工艺、资料、成本、速度的较大进步,具有较高推广应用价值。     

Collection Conduits Including Subsurface Drains

Numerous types of pipes and channels with spatially increasing flows in environmental engineering applications are identified by type and function and referred to as collection conduits. An overview of methods for designing and analyzing collection conduits is provided. Full conduits with nonuniform and uniform inflow are first considered. Dimensional analysis is then employed to demonstrate the relationship between variables for open channels; that leads to the identification of possibilities for generalized numerical solutions. Prior collection conduit applications are discussed within the framework of the dimensional analysis (which also pertains to some constant-flow applications). A previously unpublished generalized numerical solution for rectangular collection conduits is presented. Subsurface drains are addressed with particular emphasis, including the use of numerical methods to develop a new generalized chart and relation to other design methods. Among the important conclusions for subsurface drains is that the somewhat common practice of using Manning’s equation alone for such problems is not generally adequate. Examples and practical design suggestions are included, and the use of computer-based numerical methods is discussed more generally.     

吐丝圈径对大规格高碳盘条组织性能的影响

计算与分析了斯太尔摩冷线上盘条的吐丝圈径、搭接密度及"佳灵"装置横向布风曲线之间的关系,研究了吐丝圈径的大小对大规格82B盘条组织和性能的影响,确定了大规格82B盘条最小吐丝圈径应为980mm.     

Inhibition of acid rock drainage from uranium ore waste using a conventional neutralization and precipitation treatment

Glass columns (length 50 cm, i.d. 4 cm) containing 900 g of uranium ore waste were subjected to a three-step process: (1) acid drainage generation, (2) neutralization and precipitation treatment and, again, (3) acid drainage generation. In the first acid generation step, lasting about one year, different variables (pyrite addition, inoculation and irrigation solution) were tested by measuring effluent pH, redox potential, total iron and sulphate. Conditions of acid generation were satisfactorily reproduced, reaching stable pH values around 2.0 that were determined mainly by pyrite addition and the type of irrigation solution used (distilled water or ferrous sulphate). The neutralization and precipitation treatment consisted of alternating irrigations of a neutralizing solution (CaO saturated plus NaOH) and a precipitating solution (ferric sulphate saturated). This treatment caused accumulation of basic iron sulphate and iron oxide precipitates according to SEM studies. After this treatment, the barrier effect created by the reaction products was checked, using irrigation solutions similar to the first step. The effluents collected showed higher pH and lower redox potential, total iron and sulphate values than those observed before the treatment, evidencing inhibition of acid drainage generation.     

厦门市筼筜湖城市防汛排涝现状及其对策

本文通过分析筼筜湖的自然概况、防汛排涝系统设施及实际运行等资料,提出进一步提高筼筜湖防汛排涝能力的对策。