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1.
《International Journal of Hydrogen Energy》2022,47(100):41994-42000
Hydrogen technology is widely considered a novel clean energy source, and electrolysis is an effective method for hydrogen evolution. Therefore, efficient hydrogen evolution reaction (HER) catalysts are urgently needed to replace precious metal catalysts and meet ecological and environmental protection standards. Herein, Ni–Mn–P electrocatalysts are synthesized using facile electrodeposition technology. The influence of the Mn addition on the catalytic behavior is studied by the comprehensive analysis of catalytic performance and morphology of the catalysts. Among them, the Ni–Mn–P0.01 catalyst exhibits small coral-like structures, greatly improving the adsorption and desorption of hydrogen ions and reducing the overpotential hydrogen evolution. Consequently, overpotential at 10 mA cm?2 electric current density is 113 mV, and the value of the Tafel slope achieves 74 mV/dec. Furthermore, the Ni–Mn–P catalyst shows long-time (20 h) stability at current densities of 10 and 60 mA/cm2. The results confirm that the synergistic effect of Ni, Mn, and P accelerates the electrochemical reaction. Meanwhile, the addition of manganese element can change the micromorphology of the catalyst, thereby exposing more active sites to participate in the reaction, enhancing water ionization, improving the catalytic performance. This study opens a new way toward improving the activity of the catalyst by adjusting Mn concentration during the electrodeposition process. 相似文献
2.
Yuanyuan Zhang Haiyan Lu Bing Wang Zhuo Zhang Xiaorong Lin Zhongzheng Chen Bin Li 《International Journal of Food Science & Technology》2015,50(6):1397-1404
Removal of imidacloprid and acetamiprid in tea infusions by microfiltration membrane using dead‐end model was investigated in the present study. The results showed that microfiltration significantly promoted the removal of both pesticides (P < 0.05) in tea infusions. Furthermore, the extent of removal was strongly influenced by the pore size of membrane, operational pressure and the concentrations of tea infusions. The initial concentration of imidacloprid and acetamiprid showed no significant effect on their removal rates. The maximum removal rates were 79.7% for imidacloprid and 81.9% acetamiprid. The changes in major chemical components of tea infusions after microfiltration were evaluated. The results indicated that microfiltration caused no considerable changes in total polyphenols and total free amino acids, and small but statistically significant losses (6.3–18.0%) of eight catechins and three methylxanthines when filtration volume reached to 200 mL. The present study validated the application of microfiltration as a potentially feasible and promising method for the removal of imidacloprid and acetamiprid residues from tea infusions. 相似文献
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新汶矿业集团经过探索和实践,研究运用了差异互补式全掩护支护技术、掩护支架自牵引联动装置工艺、矿车运输、滑移运输多用轨道、自动找正装车平台、液控调整装置等新技术、新工艺,做到了液压支架综合流程快速回撤,实现了高效化、连贯化安全回撤,取得了良好的经济效益。 相似文献
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Syafikah Huda Paiman Mukhlis A Rahman Khairul Hamimah Abas Azian Abd Aziz Ahmad Fauzi Ismail Mohd Hafiz Dzarfan Othman Juhana Jaafar Mohammad Noorul Anam Mohd Norddin 《化学工程与技术》2019,42(6):1321-1329
Removal by absorptive ceramic membranes can simultaneously absorb and separate metal ions from water. Alumina/yttria‐stabilized zirconia (Al2O3/YSZ) hollow‐fiber membranes, fabricated using phase inversion and sintering process, were deposited with iron oxide by an in‐situ hydrothermal process. The results showed that α‐Fe2O3 was produced and incorporated across the membranes. A reduction in flux was recorded with the deposition of α‐Fe2O3. However, it improved the adsorption capacity for heavy metal adsorption. The adsorption‐separation test demonstrated that the optimized membrane is able to completely remove Pb(II) ions after two hours. 相似文献
7.
考察了双河油田双河联、江河联注入水堵塞地层的因素;膨胀性黏土,悬浮固体颗粒。细菌及悬浮污油。含膨胀性黏土的双河南、双河北及不含膨胀性黏土的双江岩心粉,在注入水中相对于地层水中的体积膨胀度分别为14.5%、11.1%及0.02%;注入100PV不含悬浮颗粒的等体积比地层水、注入水混合水使双河、双江岩心渗透率分别下降7%和4%、9%和7%。注入水中悬浮颗粒引起岩心渗透率下降,粒径越大、颗粒浓度越大、注入量越大,则渗透率越低。在粒径2.1μm或颗粒浓度3mg/L前后下降幅度变化较大。注入水中硫酸盐还原菌引起岩心渗透率下降,含菌量越大则渗透率开始下降时的注水量越小,注入含菌50个/L的水100PV使岩心渗透率下降7%。岩心对注水合油量敏感,注入含油量20mg/L的水50PV使岩心渗透率下降20%。在岩心注水实验中渗透率下降最严重的是双河南岩心,其次是双河北岩心.江河岩心较轻,注入精细过滤水的双河北岩心渗透率下降大大减少.说明悬浮固体是造成注水堵塞的主要因素。为了解除双河油田注水井的堵塞,研制了含黏土稳定剂、缓蚀剂、铁离子稳定剂、互溶剂的土酸液,与南阳油田使用的低伤害酸液一起,用于1口注水井的解堵,效果良好。图7表4参5。 相似文献
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Use of the Retarded Solution-Reprecipitation Process to Attain a Higher Initial Permeability in MnZn Ferrites 总被引:1,自引:0,他引:1
Miha Drofenik rej nidari Darko Makovec 《Journal of the American Ceramic Society》2003,86(9):1601-1604
We investigated the effect of various amounts of liquid phase on microstructure development during sintering and the resulting magnetic permeability of MnZn ferrite (MZF) samples. Our results revealed that the microstructure and the final magnetic permeability depend on the thickness of the liquid-phase film during sintering. The solution-reprecipitation (S-R) process, which is associated with an intensive microstructure development in MZF, starts when a continuous liquid-phase film of critical thickness δo , which wets the MZF grains, is formed. The solid-state sintering that takes place before the formation of the continuous liquid-phase film is essential for the final microstructure of MZF. 相似文献