莺歌海地区低电阻率气层测井响应特征与判别方法

文中概述了莺歌海地区低电阻率气层的主要测井响应特征,详细分析了低电阻率气层的成因,并提出了测井判别方法.特别强调指出局部发育的菱铁矿对该区地层电阻率无明显影响.     

Two-step flotation recovery of iron concentrate from Donganshan carbonaceous iron ore

The flotation of pure and natural carbonaceous iron ore samples in the oleate flotation system was investigated. Starch can depress hematite effectively in a wide pH range, but cannot depress siderite efficiently in neutral conditions. The flotation recovery of pure hematite, siderite, and quartz in the oleate-starch-CaCl₂ system is significantly different when the slurry pH varies from 4 to 12. A novel two-step flotation process was developed for the separation of iron concentrate from Donganshan carbonaceous iron ore through which the siderite concentrate is first recovered and the high quality hematite concentrates with relative high iron recovery can be obtained in the second step flotation. The siderite concentrate may be utilized directly or undergo further concentration steps to increase iron grade.     

Microstructure Characteristic and Phase Evolution of Refractory Siderite Ore during Sodium-carbonate-added Catalyzing Carbothermic Reduction

Thermodynamic analysis of refractory siderite ore during carbothermic reduction was conducted.Microstructure characteristics and phase transformation of siderite ore during sodium-carbonate-added catalyzing carbothermic reduction were investigated.X-ray diffraction(XRD),scanning electron microscopy and energy-dispersive analysis of X-rays were used to characterize the reduced samples.Results indicate that the solid reaction between FeO and SiO_2 is inevitable during carbothermic reduction and the formation of fayalite is the main hindrance to the rapid reduction of siderite.The phase transformation of present siderite ore can be described as:siderite-magnetite-metallic iron,complying with the formation of abundant fayalite.Improving the reduction temperature(≤1 050 ℃)and duration is helpful for the formation and aggregation of metallic iron.The iron particle size in the reduced ore was below 20μm,and fayalite was abundant in the absence of sodium carbonate.With 5% Na_2CO_3 addition,the iron particle size in the reduced ore was generally above 50 μm,and the diffraction intensity associated with metallic iron in the XRD pattern increased.The Na_2O formed from the dissociation of Na_2CO_3 can catalyze the carbothermic reduction of the siderite.This catalytic activity may be mainly caused by an increase in the reducing reaction activity of FeO.     

菱铁矿对砷的吸附解析特性试验研究

砷污染是地下水污染中的严重威胁之一。菱铁矿是砷吸附材料的一种,碳酸亚铁是菱铁矿中的主要成分之一。文章将菱铁矿与Fe2O3作对照,分别进行了静态试验和动态试验,初步探究了时间、温度、pH对砷在菱铁矿中的吸附解析行为的影响。结果表明,Fe2O3的吸附明显比菱铁矿好;pH在2到11范围内变化时,菱铁矿对砷的吸附曲线成M形;温度在20℃到40℃范围内变化时,菱铁矿对砷的吸附没有明显的变化;随着时间的变化,在前8个小时内,菱铁矿对砷的吸附速度较快,8小时之后,吸附曲线趋于平缓,说明最佳吸附时间是8小时。在解析实验中,在0.01 mol/L到0.5 mol/L范围内,随着NaOH浓度的增大,砷的解析率逐渐增大,其中在0.5 mol/L的时候达到最大,为50%。     

菱铁矿直接还原-低阶煤提质一体化扩大试验

摘要：菱铁矿作为中国重要的铁矿资源,因具有“贫、细、杂”的特点,常规选矿工艺无法对其进行有效分选;此外,中国低阶煤通常被用作低级燃料直接燃烧使用,导致大气污染严重。因此,开发复杂难选铁矿石及低阶煤资源高效清洁利用新技术,将具有重要现实意义。以难选的低品位菱铁矿和难利用低阶煤为对象,开展菱铁矿直接还原与低阶煤提质一体化扩大试验研究。以神府烟煤为还原剂,在直接还原温度为1050℃,时间为120min,C/Fe质量比为250,脱硫剂配比为6%,干式磁选磁场强度为015 T,一段磨矿细度小于0074mm占50%左右,湿式磁选磁场强度为008 T,二段磨矿细度小于0074mm占90%左右,磁选磁场强度为0043 T的条件下,可获得直接还原铁（DRI）粉铁品位9103%、铁总回收率8133%的良好指标;同时每吨DRI固定碳质量分数为7611%的半焦产品产出率为1340kg,其质量达到工业及民用燃料兰炭Ⅰ级品标准。在煤基直接还原工艺中一步成功实现低阶煤半焦化提质和铁矿直接还原,不仅可制备电炉炼钢原料,还可以生产新型的清洁燃料半焦。     

云南某低品位菱铁矿选矿试验研究

云南怒江地区某低品位菱铁矿含TFe 25.67%,金属矿物主要为菱铁矿,还有少量黄铁矿、黄铜矿等,脉石矿物主要为石英,绢云母等,为有效开发利用该矿石资源,对有代表性的矿石进行了详细的试验研究,最终采用强磁选—焙烧的选矿工艺流程,获得了铁品位57.95%、回收率为80.13%的铁精矿,为同类型矿石的开发利用提供了借鉴。     

降低90m2烧结机返矿率的探索与实践

博宏小河公司烧结返矿率一直居高不下,造成烧结生产成本增加。为此,分析了影响其90m2烧结机返矿率的因素,从优化配料、强化制粒和造球、合理调整七辊布料器的角度、合理提高料层厚度、适当提高点火温度、对烧结机本体设备进行堵漏风等方面着手,通过两年的生产实践,使烧结返矿率从2011年的20．08％降到了2013年的13％。     

石灰石对难选菱铁矿煤基熔融还原的影响

基于新型预还原-熔融还原一步炼铁工艺,以石灰石作为造渣剂,对新疆难选菱铁矿进行煤基熔融还原试验研究.探讨了石灰石在菱铁矿熔融还原过程中的作用机理及其掺量对铁收得率、渣铁分离效果、渣活性的影响规律.结果表明:石灰石对快速熔渣和熔融还原反应有促进作用,在一定范围内增加石灰石掺量有助于渣铁分离后铁收得率和渣活性的提高,随着石灰石掺量增大渣铁分离难度增大.     

添加剂对膨润土-地下水体系化学性能影响研究

本文以菱铁矿和碳酸钠为添加剂,在常温低氧条件下开展试验研究,考察了不同添加量下,菱铁矿和碳酸钠对膨润土-北山地下水体系的pH值、氧化还原电位(Eh值)、液相关键阳离子成分、固相矿物成分和可交换阳离子的影响。研究结果表明:添加碳酸钠后不仅保证体系维持在碱性范围,而且有效地阻止了钠基膨润土向钙基膨润土的转化;菱铁矿的加入使得体系维持在还原状态,Eh值稳定-158mV;菱铁矿和碳酸钠的加入并未改变膨润土本身的矿物成分。通过试验,最终获得了试验条件下增强膨润土化学缓冲性能的菱铁矿和碳酸钠的最佳添加量。