重金属(以铅计)含量测定方法的改进

探讨了用硫化钠-丙三醇溶液代替饱和硫化氢水溶液进行重金属(以铅计)测定的分析方法。此法简单、快速,并在实际应用中取得了满意的结果。     

对HIC试验中两种不同腐蚀介质酸碱度的探讨

HIC是腐蚀试验中常用的检测方法,用来测评材料在含硫化氢环境中对氢离子敏感性大小.其包含两种不同的腐蚀介质,不同的腐蚀介质中酸碱度是不一样的,腐蚀介质的酸碱度对试验结果有较大的影响,为此,运用电离平衡理论,计算并分析两种不同腐蚀介质电离平衡前后的氢离子浓度变化,得出动态反应平衡时氢离子浓度的关系式,从而获得介质中精确的氢离子浓度,并对腐蚀介质中相关离子进行了探讨,为进一步探究相关环境中的腐蚀机理提供了依据.     

Effect of nitrocarburizing on sulphide layer during nitrocarburizing-sulphurating treatment

Compared with the single sulphurating treatment, the duplex treatment of nitrocarburizing-sulphurating can more effectively improve the properties of steel such as friction-reducing, wear resistance and anti-scuffing. Under the same processing parameters, the sulphide layers were fabricated on the surface of CrMoCu alloy cast iron by single ion-sulphurating treatment and nitrocarburizing-sulphurating duplex treatment, respectively. Through the analysis of the sulphide, the effect of the nitrocarburizing on the fabrication of the sulphide layer was investigated. And the result shows that the fabrication of sulphide layer is promoted by the nitrocarburizing treatment.     

有机介质中合成二硫化钛

本文研究了硫化氢与四氯化钛在某些有机介质中的反应，并提出了一个合成二硫化钛的新方法。该法是将干燥的硫化氢通入沸腾的四氯化铁的α－氯代萘溶液中，使硫化氢和四氯化钛发生复分解反应而生成二硫化钛。方法简便易行。Ｘ－射线物相鉴定及化学分析结果表明，产物为单一物相的、符合化学计量的二硫化钛。     

ADSORPTION MECHANISMS OF HS-IONS ON SULPHIDE MINERAL SURFACES RELATED TO Na_2S-INDUCED FLOTATION

The adsorption mechanisms of HS~- ions existing in air-saturated alkaline solutions on sulphide minerals (including pyrite, arsenopyrite, chalcopyrite and galena) were investigated. The measurement of adsorption density, solvent extraction-chemical analysis of neutral sulphur at the surfaces, measurements of pulp potential and voltammogram, and flotation tests were done. Both the electrochemical and non-electrochemi cal adsorption models of HS~- ions were established. The former was observed and resulted in the formation of neutral sulphur (S°)when the pyrite and arsenopyrite were chosen, and hence renders the surfaces hy drophobic and induced the two minerals flotation. It is called Na_2S-induced flotation. On the other hand, the latter took place and did not produce S° when the chalcopyrite and galena were selected, and hence de presses the collectorless flotation of the two minerals. The adsorptions of HS~- ions were mainly influenced by potentials, pH and the electron structures of the mineral surfaces.     

34CrNiMo钢齿轮轴开裂原因分析

对34CrNiMo钢齿轮轴的化学成分、金相组织及断口分析表明，其淬火开裂的主要原因是由于锻造温度过高，导致过热缺陷所致。     

Catalytic oxidation of hydrogen sulphide on activated carbons

Activated carbon is a suitable adsorbent for removal of hydrogen sulphide from natural, synthesis or other product gases. The process depends predominantly on physical adsorption, though catalytic oxidation is also involved. During catalytic oxidation the H₂S is converted in the presence of oxygen to elemental sulphur, which is adsorbed onto the internal surface of the activated carbon, thus leading to a sulphur load of up to 120% by weight. The oxidation rate depends on the partial pressure of both reactants, H₂S and O₂ and is largely controlled by the characteristics of the activated carbon. The activity of the catalyst can be improved by impregnating the activated carbon with promoters such as iron and iodine. The regeneration of spent carbon is currently carried out using hot gas desorption methods at temperatures around 450 °C.     

硫铁矿沸腾炉掺烧含硫化氢酸性气体的研究

对合成氨装置排出的酸性气体掺入硫铁矿在沸腾炉内燃烧进行了试验研究，酸性气体φ（H2S）约31．8％，φ（CO2）约68％，掺烧试验结果表明，在正常的操作条件下，硫化氢燃烧生成二氧化硫的反应相当迅速和完全，通过调节投矿量沸腾炉可以适应硫化氢气体浓度和流量的变化，生产出符合硫酸生产的原料气，因此在硫铁矿中掺烧含硫化氢的酸性气体是可行的，建议在工业生产中，由沸腾炉的扩大层加入酸性气体，这样可防止泄漏，避免出气孔堵塞，并且可通过调节二次风量控制硫化氢气体的燃烧。     

Fluor SOx净化工艺——为俄罗斯绿色环境开发的将SOx转化为元素硫的经济技术

Fluor公司开发的Fluor SOx净化工艺具有广泛多样的工艺布局，可以通过经济的方式定制脱除烟气中的有害组成。该工艺几乎能去除全部SOx并减少CO排放。Fluor SOx净化工艺的主要步骤已在多套工业装置中得到成功的证实。除技术可行、经济合理之外，Fluor SOx净化工艺不会产生任何有害副产物，也不会遇到与SOx有关的腐蚀问题。此外，该工艺生产高纯度可市售的元素硫。论述了Fluor SOx净化工艺的特征、技术和成本优势、设计和操作的简易性以及实施的便利性。     

Fluor SOx净化工艺--为俄罗斯绿色环境开发的将SO2转化为元素硫的经济技术

Fluor公司开发的Fluor SO_2净化工艺具有广泛多样的工艺布局,可以通过经济的方式定制脱除烟气中的有害组成。该工艺几乎能去除全部SO_2并减少CO排放。Fluor SO_x净化工艺的主要步骤已在多套工业装置中得到成功的证实。除技术可行、经济合理之外,Fluor SO_x净化工艺不会产生任何有害副产物,也不会遇到与SO_3 有关的腐蚀问题。此外,该工艺生产高纯度可市售的元素硫。论述了Fluor SO_x净化工艺的特征、技术和成本优势、设计和操作的简易性以及实施的便利性。