全文获取类型
收费全文 | 1727篇 |
免费 | 22篇 |
国内免费 | 13篇 |
专业分类
电工技术 | 7篇 |
综合类 | 22篇 |
化学工业 | 551篇 |
金属工艺 | 13篇 |
机械仪表 | 16篇 |
建筑科学 | 92篇 |
矿业工程 | 30篇 |
能源动力 | 651篇 |
轻工业 | 46篇 |
水利工程 | 19篇 |
石油天然气 | 19篇 |
武器工业 | 2篇 |
无线电 | 27篇 |
一般工业技术 | 151篇 |
冶金工业 | 67篇 |
原子能技术 | 2篇 |
自动化技术 | 47篇 |
出版年
2024年 | 3篇 |
2023年 | 55篇 |
2022年 | 81篇 |
2021年 | 103篇 |
2020年 | 84篇 |
2019年 | 64篇 |
2018年 | 56篇 |
2017年 | 46篇 |
2016年 | 10篇 |
2015年 | 21篇 |
2014年 | 94篇 |
2013年 | 93篇 |
2012年 | 88篇 |
2011年 | 113篇 |
2010年 | 87篇 |
2009年 | 100篇 |
2008年 | 85篇 |
2007年 | 71篇 |
2006年 | 49篇 |
2005年 | 54篇 |
2004年 | 34篇 |
2003年 | 58篇 |
2002年 | 41篇 |
2001年 | 28篇 |
2000年 | 36篇 |
1999年 | 33篇 |
1998年 | 25篇 |
1997年 | 22篇 |
1996年 | 22篇 |
1995年 | 18篇 |
1994年 | 22篇 |
1993年 | 10篇 |
1992年 | 10篇 |
1991年 | 7篇 |
1990年 | 6篇 |
1989年 | 11篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有1762条查询结果,搜索用时 0 毫秒
1.
Valentina I. Simagina Pavel A. Storozhenko Olga V. Netskina Oksana V. Komova Galina V. Odegova Yury V. Larichev Arcady V. Ishchenko Anna M. Ozerova 《Catalysis Today》2008,138(3-4):253
Catalytic hydrolysis of NaBH4 and NH3BH3 has been studied. It was shown that the nature of the support and the active component of the catalyst affect the H2 generation rate. Despite similar sizes of rhodium particles formed on the surface of different supports (γ-Al2O3, TiO2, carbon), their reactivity is different. Rh/TiO2 with low rhodium concentration (1 wt.%) is the most active catalyst both in the hydrolysis of NaBH4 and NH3BH3. The obtained results show that the rhodium chloride interaction with titania determines the reactivity of rhodium particles formed under action of NaBH4 medium. TEM, DRS UV–vis and XPS were used to characterize the catalysts. 相似文献
2.
3.
A.K. PrasadP.I. Gouma D.J. Kubinski J.H. VisserR.E. Soltis P.J. Schmitz 《Thin solid films》2003,436(1):46-51
We report the gas-sensing properties of ion-beam sputter deposited MoO3 thin-films. The change in the DC conductivity was measured in dry N2 with 10% O2 in the presence of up to 490 ppm of NH3, NO, NO2, C3H6, CO and H2. At ∼440 °C the film was found to be very sensitive to NH3, with 490 ppm increasing the conductivity by approximately a factor of 70. This was approximately 17 times greater than the response to the other gases. The NH3 response was strongly affected by the accompanying levels of O2, NO2 and H2O. For example, changing the accompanying O2 levels from 1% to 20% decreased the NH3 response by approximately a factor of 20. Similarly, the presence of 100 ppm NO2 (in 10% O2) decreased the NH3 response by approximately a factor of three, and 1% water vapor decreased it by more than a factor of two. The NH3 response, however, was relatively unaffected by 100 ppm of accompanying NO, C3H6, CO or H2. XPS measurements show that the increased conductivity in the presence of NH3 was also accompanied by a partial reduction of the surface MoO3. We observed an increase in the resistance of the films after extended time at elevated temperatures. 相似文献
4.
5.
A model (MAST) to calculate the mass flow of NH3 through amodel dairy farm has been developed. Updated emission factors for UKagriculturewere used to examine different abatement strategies available for a typicaldairy farm. A range of annual NH3 emissions was calculated for bothslurry and FYM based dairy systems. Emission for the slurry based system ranged between 27 kg NH3-N ha–1 yr–1, achieved using a combination of abatementstrategies, and 107 kg NH3-N ha–1 yr–1, calculated for a worst casescenario. For FYM, this range was between 33 and 86 kg NH3-Nha–1 yr–1. The greatest reductionswereachieved by manipulating options linked to fertiliser usage and manureapplication. 相似文献
6.
7.
通过模拟计算对深冷净化系统做了深入的分析,研究了深冷净化系统脱除甲烷化气中过量氮、甲烷、惰气和回收弛放气中氢的能力,甲烷化气组成和压力对净化效果和操作稳定性的影响。 相似文献
8.
Pt-V2O5-WO3/TiO2 catalysts supported on SiC filter for NO reduction at low temperature 总被引:1,自引:0,他引:1
Joo-Hong Choi Jin-Hyun Kim Young-Cheoul Bak Rose Amal Jason Scott 《Korean Journal of Chemical Engineering》2005,22(6):844-851
The catalytic filter, V2O5-WO3-TiO2 supported on a ceramic filter, is known as a promising material for treating particulates and NO
x
simultaneously at optimum temperatures around 320°C. In order to improve its catalytic activity at low temperatures, the
effect of Pt addition on the catalytic filter has been investigated. Catalytic filters, Pt-V2O5-WO3-TiO2/SiC, were prepared by co-impregnation of Pt, V, and W precursors on TiO2 coated-SiC filter by vacuum aided-dip coating. The Pt-added catalytic filter shifted the optimum working temperature from
280–330°C (for the non Pt-impregnated filter) to 180–230°C, providing N
x
slip concentration less than 20 ppm for the treatment of 700 ppm NO at a face velocity of 2 cm/s with the same value over
the non Pt-added catalytic filters. The promotional effect following the addition of Pt is believed to result from electrical
modification of the catalyst maintaining a high electron transfer state. Ammonia oxidation was also observed to be dominant
above the optimal temperature for SCR. 相似文献
9.
二氧化碳激光熔铸技术在氨压缩机曲轴修复中的应用 总被引:3,自引:0,他引:3
用连续输出功率在千瓦级的二氧化碳激光器 ,激光功率密度达到 (10 4~ 10 5)W·cm-2 时 ,对铁基材料表面进行熔铸 ,讨论了激光熔铸修复工艺 ,论述了对修复件强度、表面硬度和抗磨性能、残余应力的影响。 相似文献
10.
A parametric investigation of NH4OH catalyzed solvent delignification of poplar was conducted to define pretreatment conditions which would yield an optimal separation of the biomass components and an enzymatic susceptible solid carbohydrate phase. Delignification parameters of interest included concentration of NH4OH, time and temperature of the reaction, and type of solvent. The addition of 0.82 M NH4OH to the delignification liquor increased lignin removal and decreased carbohydrate degradation, but increasing NH4OH concentration had no additional effect. At lower reaction temperatures, the extent of delignification increased with reaction time; at higher temperatures, a “relignification” of the pretreated wood was observed. The delignification and hemicellulose solubilization were modelled and rate constants reported. No major difference between three potential pulping solvents—ethanol, butanol, phenol—was observed. The enzymatic susceptibility of pretreated wood samples was approximately 6-fold greater than that of the untreated poplar. UV absorbance was used to qualitatively characterize the soiubilized lignins. 相似文献