Pyridinium molten salts as co-adsorbents in dye-sensitized solar cells

The influence of using pyridinium molten salts as co-adsorbents to modify the monolayer of a TiO₂ semiconductor on the performance of a dye-sensitized solar cell is studied. The current-voltage characteristics are measured under AM 1.5 (100 mW cm⁻²). The pyridinium molten salts significantly enhance the open-circuit photovoltage (V_oc), the short circuit photocurrent density (J_sc) as well as the solar energy conversion efficiency (η). 1-Ethyl-3-carboxypyridinium iodide ([ECP][I]) is applied successfully to prepare an insulating molecular layer with N719, and achieve high energy conversion efficiency as high as 4.49% at 100 mW cm⁻² and AM 1.5. The resulting efficiency is 20% higher than that of a non-additive device. This enhancement of conversion efficiency is attributed to the negative shift of the conduction band (CB) edge and the abundant concentration of I⁻ on the surface of the electrode when using [ECP][I] as the co-adsorbent.     

Dye-sensitized solar cells with a micro-porous TiO2 electrode and gel polymer electrolytes prepared by in situ cross-link reaction

The ionic conductivities and performances of dye-sensitized solar cells (DSSCs) of gel polymer electrolytes (GPEs) prepared by in situ cross-link reaction with different cross-linkers were investigated. The poly(imidazole-co-butylmethacrylate)-based GPE containing the 1,2,4,5-tetrakis(bromomethyl)benzene (B4Br) cross-linker showed a higher ionic conductivity than that containing cross-linkers with a linear structure, due to the formation of micro-phase separation that resulted in an increase in ion transport paths in the GPE. Moreover, the co-adsorbent ((4-pyridylthio) acetic acid, PAA) co-adsorbed with N3 dye on the TiO₂ electrode not only reduced dye aggregation, but also reacted with the cross-linkers in the GPE at the TiO₂/GPE interface. A decrease in the charge transport resistance at the TiO₂/GPE interface was noted after forming the gel; thus the value of J_SC significantly increased from 7.72 to 10.00 mA cm⁻². In addition, in order to reduce the ionic diffusion resistance within the TiO₂ electrode, incorporation of monodispersed PMMA in the TiO₂ paste was considered. With the optimal weight ratio of PMMA/TiO₂ (w/w=3.75), the TiO₂ electrode exhibited larger pores (ca. 350 nm) uniformly distributed after sintering at 500 °C, and the ionic diffusion resistance within the TiO₂ film could significantly be reduced. The cell conversion efficiency increased from 3.61% to 5.81% under illumination of 100 mW cm⁻², an improvement of ca. 55%.