The influence of biomass co-combustion on boiler fouling and efficiency

The paper presents an attempt to evaluate the influence of biomass co-combustion on the fouling of boiler convection surfaces. In order to show the influence of co-firing biomass with bituminous coal on boiler efficiency, the calculations of pulverized fuel (PF) OP 140 steam generator have been carried out. Typical Upper Silesian coal with medium fouling inclination has been chosen as a basic fuel. Three kinds of biomass have been taken into consideration: straw, wood and dried sewage sludge. The results confirm that the properties of additional fuels cause deterioration of the boiler efficiency as well as the changes in boilers operational parameters (amount of water injected in attemperators, ash stream, hot air temperature). The biomass during cofiring in fact replaces the coal, but always the additional fuel consumption is higher than that of the substituted coal. Therefore, the actual decrease of coal consumption is smaller than the thermal fraction of the biomass.     

Enhancing sulphur self-retention by building-in CaO in straw–bitumen pellets

Combined straw–bitumen pellets have been proposed as an alternative fuel. An interesting finding is the potentiality of straw ash constituents to retain sulphur as bitumen that has relatively high sulphur content. The aim of the present work is to enhance sulphur self-retention to directly meet the environmental regulations by building-in CaO in the pellet instead of feeding sorbent separately. CaO powder has been mixed with the pellet constituents during production processes.     

The effect of biomass co-combustion in a CFB boiler on solids accumulation on surfaces of P91 steel tube samples

The paper describes the results of industrial tests associated with the co-combustion of biomass and agromass with coal and focused on diagnostics and assessment of the effect of fuel type on the accumulation of solids on the surface of P91 steel tube samples placed in the vicinity of steam superheater in a commercial large-scale (over 400 MW) circulating fluidized bed boiler.Analysis of samples indicated the effect of fuel type, as well as the location of the area on the steel tube on the rate of solids accumulation. Alkali compounds were quite uniformly distributed at both front and rear sections of the steel tube samples, while calcium and sulfur components were mainly found in the front area. The average solids accumulation rates calculated for the rear areas of P91 steel tube samples were roughly two times higher than those for the front ones. The highest solids accumulation rate on the front area (1.04·10⁻⁹ ms⁻¹) was calculated for the case of agromass co-combustion with coal.     

A technical and environmental analysis of co-combustion of coal and biomass in fluidised bed technologies

The use of biomass, which is considered to produce no net CO₂ emissions in its life cycle, can reduce the effective CO₂ emissions of a coal-fired power generation system, when co-fired with the coal, but may also reduce system efficiency.The technical and environmental analysis of fluidised bed technologies, using the ECLIPSE suite of process simulation software, is the subject of this study. System efficiencies for generating electricity are evaluated and compared for the different technologies and system scales.Several technologies could be applied to the co-combustion of biomass or waste and coal. The assessment studies here examine the potential for co-combustion of (a) a 600 MWe pulverised fuel (PF) power plant (as a reference system), (i) co-firing coal with straw and sewage sludge and (ii) using straw derived fuel gas as return fuel; (b) a 350 MWe pressurised fluidised bed combustion (PFBC) system co-firing coal with sewage sludge; (c) 250 MWe and 125 MWe circulating fluidised bed combustion (CFBC) plants co-firing coal with straw and sewage sludge; (d) 25 MWe CFBC systems co-firing low and high sulphur content coal with straw, wood and woody matter pressed from olive stones (WPOS); (e) 12 MWe CFBC co-firing low and high sulphur content coal with straw or wood; and (f) 12 MWe bubbling fluidised bed combustion (BFBC), also co-firing low and high sulphur content coal with straw or wood.In the large systems the use of both straw and sewage sludge resulted in a small reduction in efficiency (compared with systems using only coal as fuel).In the small-scale systems the high moisture content of the wood chips chosen caused a significant efficiency reduction.Net CO₂ emissions are reduced when biomass is used, and these are compared for the different types and scales of fluidised bed technologies. NO_x emissions were affected by a number of factors, such as bed temperature, amount of sorbent used for SO₂ capture and HCl emitted.     

Measurements of dioxin emissions during co-firing in a fluidised bed

The emissions of dioxins could be considerable when fuels with high chlorine content are used, particularly in fluidised beds due to constraints to use temperatures in the range 800-900 °C for other considerations. However, mixing of fuels with different characteristics may lead to a reduction in dioxin emissions. Studies are currently being undertaken at the above-mentioned department in mixing fuels of varying chlorine and sulphur contents to monitor the emissions of dioxins both in the gas and solid phases. Furthermore, the influence of certain elements like Cu in the ash in the emissions of dioxins is also studied to verify the catalytic effect.The INETI pilot-scale test facility is used for the combustion work. Two different coals, namely Colombian and Polish, are used as the base fuel. The supplementary fuels for co-firing include MBM and straw pellets. The combustion temperature is maintained at about 800-830 °C range without any limestone addition. The residence time of over 2 s is respected.Results obtained by far suggest that the presence of sulphur in both fuels have a very strong effect on the eventual emissions of dioxins and the synergy regarding to reduce the dioxins below the levels permitted is possible by mixing fuels based on their characteristics. The paper reports the results obtained and evaluates the effect of fuel nature and operating conditions on the emissions of dioxins.     

Controlling the excess heat from oxy-combustion of coal by blending with biomass

Two different biomass species such as sunflower seed shell and hazelnut shell were blended with Soma-Denis lignite to determine the effects of co-combustion on the thermal reactivity and the burnout of the lignite sample. For this purpose, Thermogravimetric Analysis and Differential Scanning Calorimetry techniques were applied from ambient to 900 °C with a heating rate of 40 °C/min under dry air and pure oxygen conditions. It was found that the thermal reactivities of the biomass materials and the lignite are highly different from each other under each oxidizing medium. On the other hand, the presence of biomass in the burning medium led to important influences not only on the burnout levels but also on the heat flows. The heat flow from the burning of lignite increased fivefold when the oxidizing medium was altered from dry air to pure oxygen. But, in case of co-combustion under oxygen, the excess heat arising from combustion of lignite could be reduced and this may be helpful to control the temperature of the combustion chamber. Based on this, co-combustion of coal/biomass blends under oxygen may be suggested as an alternative method to the “Carbon Dioxide Recycle Method” encountered in the oxyfuel combustion systems.     

Effects of biomass co-firing with coal on ash properties. Part II: Leaching, toxicity and radiological behaviour

In this paper, the leaching, toxicity behaviour and the radioactivity content of solid residues coming from the co-combustion of biomass with coal were studied. A variety of samples collected from semi-industrial scale tests were analysed for their leaching and toxicity properties. Natural radioactivity and radon exhalation rate were also measured in samples collected from tests performed in a pilot facility in Germany (IVD, University of Stuttgart) and large-scale power plants. The high toxicity levels detected in the ash samples of olive kernel could be attributed to the relatively increased concentrations of Zn, Ni, Mn, Co, Cd. The effect of biomass co-combustion on the radioactivity content of fly ash was dependent on the fuel mixture used as well as the ash sampling location along the flue gas pathway. Activity concentrations of most nuclides of interest, namely ²³⁸U, ²²⁶Ra, ²¹⁰Pb and ²³²Th are comparable to those of fly ash produced when burning pure coal, while increased concentrations where observed for ⁴⁰K. In some cases the artificial radionuclide ¹³⁷Cs was also detected.     

Preventing chlorine deposition on heat transfer surfaces with aluminium-silicon rich biomass residue and additive

Biomass fuels often contain higher concentrations of easily vaporisable alkalis and chlorine than do coal and peat. The more vaporisable the alkalis or chlorine compounds the higher is the risk for ash-related problems. The presence of certain elements may reduce or remove these problems. This work shows how co-combusting of different biomass fuels in a fluidised bed boiler can result in useful interactions that decrease or totally inhibit Cl deposition and bed agglomeration. In a first set of experiments, fuel 1 contained easily vaporised chlorine that produces Cl-rich deposits on superheaters. Fuel 2 was enriched in aluminium silicate, but contained much ash, resulting in low heating value and high load of fly ash. In a second set of experiments, fuel 1 was enriched in Cl and alkalis, which lead to corrosive deposits, bed agglomeration and fouling. As a result of protecting reactions, the mixtures were free from the problems observed during their separate combustion.     

Hydrogen-diesel fuel co-combustion strategies in light duty and heavy duty CI engines

The co-combustion of diesel fuel with H₂ presents a promising route to reduce the adverse effects of diesel engine exhaust pollutants on the environment and human health. This paper presents the results of H₂-diesel co-combustion experiments carried out on two different research facilities, a light duty and a heavy duty diesel engine. For both engines, H₂ was supplied to the engine intake manifold and aspirated with the intake air. H₂ concentrations of up to 20% vol/vol and 8% vol/vol were tested in the light duty and heavy duty engines respectively. Exhaust gas circulation (EGR) was also utilised for some of the tests to control exhaust NO_x emissions.The results showed NO_x emissions increase with increasing H₂ in the case of the light duty engine, however, in contrast, for the heavy duty engine NO_x emissions were stable/reduced slightly with H₂, attributable to lower in-cylinder gas temperatures during diffusion-controlled combustion. CO and particulate emissions were observed to reduce as the intake H₂ was increased. For the light duty, H₂ was observed to auto-ignite intermittently before diesel fuel injection had started, when the intake H₂ concentration was 20% vol/vol. A similar effect was observed in the heavy duty engine at just over 8% H₂ concentration.     

Effect of co-combustion of chicken litter and coal on emissions in a laboratory-scale fluidized bed combustor

Co-combustion of chicken litter (CL) with coal was performed in a laboratory-scale fluidized bed combustor to investigate the effect of CL combustion on pollutant emissions. The emissions of major gaseous pollutants including CO, SO₂, H₂S and NO and temperature distribution along the combustor were measured during the tests. Effects of CL fraction and secondary air on combustion characteristics were studied. The experimental results show that CL introduction increases CO emissions and reduces the levels of SO₂. The ratio of H₂S/SO₂ increases with increasing fraction of CL. NO emissions either increase or decrease depending on the percentage of CL in the mixed fuels. The temperature in the freeboard region increases with increasing the fraction of CL while the reverse is true for the bed temperature.