新型无毒无味卡尔.费休试剂的研制

对原卡尔．费休试剂进行了改进。以无毒无味的咪唑代替了原试剂中的吡啶，并以乙醇代替了试剂中的甲醇，制成了无毒无味的卡氏试剂。对由卡尔．费休试剂组成的电解液进行了改进，用碘化物代替碘，解决了长期储存和问题。     

无吡啶,无甲醇卡尔费休试剂的应用

对传统卡尔费休试剂的不足进行了分析 ,提出了一种用有机胺代替吡啶 ,用多元醇衍生物代替甲醇的无吡啶、无甲醇、高效低毒、性能稳定、应用范围广泛、克服了传统卡尔费休试剂无法测定含羰基化合物样品中微量水弊端的新型卡尔费休试剂。经与英国BDH公司、北京石油科学研究院和山东淄博无线电一厂生产的市售卡尔费休试剂的对比分析和工厂现场试验证明本试剂可完全替代传统和进口卡尔费休试剂对石油产品、化工产品及含有羰基化合物样品中的微量水分分析。分析误差符合GB6 0 6 77规定的范围     

生物柴油及其原料中水分含量的测定

通过比较卡尔费休法和烘箱法认为卡尔费休法和烘箱法都适合于植物油中水分含量的测定,而卡尔费休法适合于生物柴油中水分含量的测定。     

Novel inorganic precursors [Co4.32Zn1.68(HCO2)18(C2H8N)6]/SiO2 and Co4.32Zn1.68(HCO2)18(C2H8N)6]/Al2O3 for Fischer–Tropsch synthesis

The silica- and alumina-supported Co–Zn catalysts were synthesized by thermal decomposition of new inorganic precursors [Co_4.32Zn_1.68(HCO₂)₁₈(C₂H₈N)₆]/SiO₂ or Al₂O₃. A novel coordination polymer formulated as [Co_4.32Zn_1.68(HCO₂)₁₈(C₂H₈N)₆] (1) was prepared using the solvothermal technique and characterized by elemental analysis, FT-infrared spectroscopy. Thermal stability of the complex 1 was investigated by thermogravimetric analysis and differential scanning calorimetry, and its structure was determined by single-crystal X-ray diffraction. Characterization of catalysts was carried out using powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and BET specific surface area. The catalysts were evaluated for Fischer–Tropsch synthesis (FTS) in the temperature range 200–300 °C. The results revealed that the synthesized catalysts have higher selectivity to the desired products at 260 °C. The performance of the catalysts was compared to those of catalysts constructed via impregnation method and the fabricated catalysts show higher activity and selectivity than the reference catalysts.     

Higher Hydrocarbon Production through Oxidative Coupling of Methane Combined with Hydrogenation of Carbon Oxides

In the production of higher hydrocarbons, combining oxidative coupling of methane (OCM) with hydrogenation of the formed carbon oxides in a separate reactor provides an alternative to the currently applied methane conversion to syngas followed by Fischer‐Tropsch synthesis. The effects of CH₄:O₂ feed ratio in the OCM reactor and partial pressures of H₂ or/and H₂O in the hydrogenation reactor were analyzed to maximize production of C₂₊ hydrocarbons and reduce CO_x formation. The highest C₂₊ yield was achieved with low CH₄:O₂ feed ratio for OCM and removal of the formed water before entering the hydrogenation reactor.     

卡尔费休法测定液态氯乙烯中水含量的研究

采用卡尔费休法测定了液态氯乙烯单体中的水含量。试验确定了采样工具、样品的预处理方式及选用溶剂的最优方案,并进行了精密度与准确度的验证。结果表明卡尔费休法测定液态氯乙烯单体中的水含量准确、快速,可以用来准确、及时地指导生产。     

氯化氢中水分测定方法的探讨

采用重量法和卡尔菲休水分测定法对氯化氢气体中的水分进行测定。结果表明,2种分析方法测试数据准确度较高,都可以作为中控脱水的分析方法,但重量法操作简单,所需分析仪器价廉易得,在环保方面优于卡尔菲休水分测定法。     

卡尔-费休滴定法测定奥柳氮锌中的水分

以甲醇-氨溶液为溶剂,采用卡尔-费休滴定法快速测定新药奥柳氮锌中的水分,水分平均含量为10．89%,RSD=0．30%。该法适用于类似有机金属药物和精细石油化工产品中水分的测定。