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排序方式: 共有417条查询结果,搜索用时 15 毫秒
1.
《Ceramics International》2021,47(22):31319-31328
Manufacturing lightweight aggregate (LWA) at high temperature is an effective way to immobilize heavy metals in solid waste. This work investigated the performance and solidification mechanism of LWA prepared from copper contaminated soil. The volume expansion of LWA could reach a maximum of 28%, and its lowest density accounted of 1.5 g/cm3, which met the standard requirements. Optical microscope and micro-CT test illustrated that the addition of Cu leaded to obvious phase separation in LWA. The Cu leaching result of LWA first increased and then dropped with the temperature. The XRD test found that the main formation phase of Cu in LWA were t-CuFe2O4 and amorphous phase that they had different acid resistance ability. XPS revealed that the main cause of the agglomeration of liquid phase in LWA was the chain broken reaction between Cu and Si–O tetrahedron. SEM-EDS results showed that the distribution of Cu and Si had a strong correlation, which meant that Cu mostly formed amorphous phase. This work showed the uniqueness of Cu in the high temperature immobilization and pointed out the best immobilization target phase. 相似文献
2.
Junyang Xu Yanjun Jiang Liya Zhou Li Ma Zhihong Huang Jiafu Shi Jing Gao Ying He 《中国化学工程学报》2021,38(10):237-246
Immobilization is an effective method to promote the application of enzyme industry for improving the stability and realizing recovery of enzyme.To some extent,the performance of immobilized enzyme depends on the choice of carrier material.Therefore,the development of new carrier materials has been one of the key issues concerned by enzyme immobilization researchers.In this work,a novel organic-inorganic hybrid material,nickel-carnosine complex (NiCar),was synthesized for the first time by solvothermal method.The obtained NiCar exhibits spherical morphology,hierarchical porosity and abun-dant unsaturated coordination nickel ions,which provide excellent anchoring sites for the immobiliza-tion of proteins.His-tagged organophosphate-degrading enzyme (OpdA) and ω-transaminase (ω-TA)were used as model enzymes to evaluate the performance of NiCar as a carrier.By a simple adsorption process,the enzyme molecules can be fixed on the particles of NiCar,and the stability and reusability are significantly improved.The analysis of protein adsorption on NiCar verified that the affinity adsorp-tion between the imidazole functional group on the protein and the unsaturated coordination nickel ions on NiCar was the main force in the immobilization process,which provided an idea way for the develop-ment of new enzyme immobilization carriers. 相似文献
3.
转盘反应器固定米根霉的L-乳酸发酵 总被引:4,自引:0,他引:4
研究了米根霉的固定化方法,研制了用吸附法固定米根霉的生物转盘反应器,考察了在该反应器中培养基组成及其它操作条件对L-乳酸发酵的影响。实验结果表明,应用吸附法固定化的米根霉及生物转盘反应器进行L-乳酸发酵具有发酵速率快,L-乳酸得率高及既能用于连续发酵又能用于间歇发酵等优点 相似文献
4.
5.
Nikolaos Dimitratos Jose Antonio Lopez-Sanchez David Morgan Albert Carley Laura Prati Graham J. Hutchings 《Catalysis Today》2007,122(3-4):317-324
Solvent free oxidation of benzyl alcohol was investigated in the absence of a base using Au catalysts prepared by sol immobilization on titania and carbon supports. Comparison between the Au supported catalysts revealed that activity and distribution of products was dependent on the nature of support and heat treatment. Specifically, heat pre-treatment of the Au catalysts has a beneficial effect in terms of activity, but is detrimental in terms of selectivity to the benzaldehyde. We conclude that sol immobilization is a suitable technique for preparing gold catalysts with small particle size and narrow particle size distributions and very high activity and selectivity for benzyl alcohol oxidation. 相似文献
6.
Lian-Ying?ZhengEmail author Yu-Liang?Xiao 《Korean Journal of Chemical Engineering》2004,21(1):201-205
Chitosanase obtained fromPenicillium sp.ZD-Z1 was immobilized on DEAE cellulose with glutaraldehyde by cross-linking reaction. The optimal conditions of immobilization
were as follows: 0.1 g DEAE cellulose was treated with 5 ml 5% glutaraldehyde solution; then 2.3 mg chitosanase was immobilized
on the carrier. The optimal temperature and pH was 60 °C and 4.0, and the K
m
value was 18.87 g/L. Under optimal conditions, the activity of immobilized enzyme is 1.5 U/g, and the recovery of enzyme
activity is 81.3%. After immobilization, the optimal temperature and K
m
value increased (from 50 °C to 60 °C, from 2.49 g/L to 18.87 g/L), whereas the optimal pH was reduced (from 5.0 to 4.0).
The enzyme activity loss was less than 20% after 10 times batch reaction; the immobilized enzyme showed good operation stability. 相似文献
7.
A shear horizontal surface acoustic wave sensor for the detection of antigen–antibody reactions for medical diagnosis 总被引:1,自引:1,他引:0
In this paper we describe the development of a shear horizontal surface acoustic wave immunosensor for medical diagnostics. There exists a strong interest in the rapid detection of antigen–antibody reactions at small concentrations in the g/ml region in plasma, serum, or whole blood. Sensors whose operating principle is based on shear horizontal acoustic surface waves are well suited for this. We have used a spin-on glass film for the guidance of the surface wave as well as for the protection of the aluminum structures of the surface wave transducers from aggressive analyte liquids. This film has proven to considerably enhance the sensitivity of the device, and to simultaneously provide a durable protection of the transducers. Furthermore, polymers based on polyvinylamines have been used for the first time for immobilization of the capture protein. This technique effectively prevents the undesired binding of foreign substances like cells, non-specific antibodies, or other proteins at the sensor surface. 相似文献
8.
Results of a series of experimental tests performed to determine the influence of matrix characteristics on the leaching mechanism
of copper aluminum oxychloride immobilized into cement matrices are presented. The objective of this work was to investigate
the leaching mechanism of copper as a constituent of copper aluminum oxychloride (‘CAOX’). Transport phenomena involved in
the leaching of a waste material from a composite matrix into surrounding water were investigated using three methods based
on theoretical equations: (i) diffusion equation derived for a plane source model, (ii) rate equation for diffusion coupled
with a first-order reaction and (iii) the leaching data were also analysed by an empirical method employing a polynomial equation.
These three methods are compared with respect to their applicability to the leaching data. 相似文献
9.
冷冻聚丙烯酰胺法固定化黑曲霉生产柠檬酸的研究 总被引:1,自引:0,他引:1
本文建立了冷冻聚丙烯酰胺包埋固定化微生物的方法,并用于固定化黑曲霉生产柠檬酸,与常规方法进行了比较。优化了固定化细胞生产柠檬酸的条件:蔗糖浓度100~140g/L,NH4Cl3.0~4.0g/L初始pH3.0,培养温度30℃。固定化细胞在半连续发酵中重复使用5批次,在连续发酵中使用300h,其余酸活性没有明显下降。 相似文献
10.
The crude cell-free medium from a culture of Kluyveromyces marxianus var. bulgaricus was immobilized in a gelatin-water support, with an immobilization yield of 82.60% for inulinase activity. The optimum pH for both free and immobilized inulinase was the same (3.5) and the optimum temperatures were 55 °C for the free and 60 °C for the immobilized enzyme. The Arrhenius plots were linear and activation energies were 56.20 (free enzyme) and 20.27 kJ/mol K (immobilized enzyme). The kinetic parameters were calculated by Lineweaver–Burk plots and the Vmax and Km were 37.60 IU/mg protein and 61.83 mM for the free inulinase and 31.45 IU/mg protein and 149.28 mM for the immobilized enzyme, respectively. The operational stability of the immobilized inulinase was studied in a continuous fixed-bed column reactor for 33 days, at the end of which the sucrose conversion was 58.12%. 相似文献