全文获取类型
收费全文 | 310篇 |
免费 | 3篇 |
国内免费 | 4篇 |
专业分类
电工技术 | 8篇 |
综合类 | 9篇 |
化学工业 | 182篇 |
金属工艺 | 5篇 |
机械仪表 | 6篇 |
建筑科学 | 5篇 |
能源动力 | 63篇 |
轻工业 | 6篇 |
石油天然气 | 3篇 |
无线电 | 1篇 |
一般工业技术 | 26篇 |
冶金工业 | 1篇 |
原子能技术 | 2篇 |
出版年
2023年 | 3篇 |
2022年 | 8篇 |
2021年 | 9篇 |
2020年 | 4篇 |
2019年 | 9篇 |
2018年 | 5篇 |
2017年 | 9篇 |
2016年 | 5篇 |
2015年 | 5篇 |
2014年 | 16篇 |
2013年 | 24篇 |
2012年 | 15篇 |
2011年 | 18篇 |
2010年 | 14篇 |
2009年 | 11篇 |
2008年 | 22篇 |
2007年 | 11篇 |
2006年 | 19篇 |
2005年 | 18篇 |
2004年 | 17篇 |
2003年 | 20篇 |
2002年 | 14篇 |
2001年 | 7篇 |
2000年 | 8篇 |
1999年 | 9篇 |
1998年 | 3篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1991年 | 2篇 |
排序方式: 共有317条查询结果,搜索用时 15 毫秒
1.
Corncob liquefaction in supercritical ethanol–water was performed with and without the addition of an alkali catalyst by direct addition or biomass impregnation in a 250-cm3 batch reactor. The effects of temperature, solvent and alkali addition on the biomass conversion level and oil yield were investigated to find the optimum condition. For non-catalytic liquefaction using a 1:1 (v/v) ethanol: water ratio, a maximum oil yield and conversion level of 49.0% and 93.4%, respectively, were obtained at 340 °C. For alkali catalytic liquefaction, the oil yield with KOH addition (57.5%) was higher than that from KOH-impregnated corncob liquefaction (43.3%). The oil from liquefaction with KOH addition had higher heating value (26.7–35.3 MJ kg−1) than the corncob (19.1 MJ kg−1). The dominant components of the obtained oil were found by GC/MS analysis to be aldehyde, ester, phenol derivatives and aromatic compounds. 相似文献
2.
3.
4.
The interactions of NO with carbon and carbon-supported catalysts have been investigated by means Fourier transform infrared spectroscopy. Nitric oxide direct decomposition over carbon-supported catalysts (Cu, Pt) was studied in a temperature ranging from 473 to 623 K. NO conversion increased with increasing reaction temperature in the whole temperature range. The carbon-supported Pt catalyst has a very high activity for the decomposition of NO in the absence of oxygen. As a result of NO chemisorption isocyanate (-NCO) species on the surface of carbon containing Cu were observed. When the reaction temperature was increased, the -NCO band at 2229 cm−1 became more intense. 相似文献
5.
A novel method was developed for the fabrication of activated carbon fiber (ACF) with wet spinning polyvinyl alcohol (PVA) fibers as the precursors. Through a combination of preoxidation, dehydration, carbonization and activation under a certain tension, PVA-based ACFs (PVA-ACFs) with high yields and good mechanical properties were obtained. The surface and cross-section morphologies, pore structures, surface geometries, surface functional groups and crystal structures of the PVA-ACFs were characterized using field emission scanning electron microscopy, low temperature nitrogen adsorption, Fourier transformed infrared spectrophotometry, X-ray photoelectron spectroscopy and X-ray power diffraction. All the PVA-ACF samples prepared had lotus root-like axially meso- and macroporous structures with the domination of micropores. Fractal geometries of PVA-ACFs deduced from nitrogen adsorption isotherms indicates that capillary force dominated in the interactions between nitrogen and the PVA-ACFs. The surface functional groups of the PVA-ACFs depend on the activating agents. Graphitoidal crystal structures were observed for the PVA-ACFs. The small crystal size and short range ordering between the crystallites ensured a high specific surface area of the PVA-ACFs. 相似文献
6.
In this study, waste biological sludge is converted to an adsorbent by chemical activation with sulphuric acid. The adsorbent obtained is then applied to the aerated vessel of an activated sludge process treating glucose and phenol to improve the quality of the treated effluent. The sludge-based carbonaceous adsorbent was found to be mesoporous in nature, with a good adsorption capacity for large molecular weight compounds and limited removal efficiency for smaller molecules such as phenol. The addition of carbon, either sludge-based or commercial, enhanced phenol removal from 58% to 98.7% and from 87% to 93% the organic matter removal as measured by the chemical oxygen demand (COD) when operated with feed concentrations of 100 mg phenol/l and 2500 mg COD/l. No differences were found between the activated sludge-activated carbon bench scale continuous reactors operating with either commercial or sludge-based adsorbents in spite of the higher adsorption capacity of the former. It is suggested that powdered adsorbent bioregeneration in the combined AS-PAC system may be impaired by the obstruction of pores due to bacterial growth, the effect being more important for the commercial activated carbon with a narrower pore size distribution. 相似文献
7.
S.P AppleyardB Rand 《Carbon》2002,40(6):817-834
This paper reports the systematic characterisation of changes in the structure and properties of a series of unidirectional carbon-carbon composites at key stages of processing. The composites were fabricated from PAN-based carbon fibres (surface treated and untreated) and two carbon matrix systems (graphitising and non-graphitising). The effects of matrix shrinkage, together with thermal expansion mismatch and interfacial bonding, established the composite structure and hence the composite properties. The morphology and interconnectivity of the shrinkage cracks, the strength and nature of the fibre-matrix interfacial interaction and the development of matrix texture were identified as key structural features. These features were characterised and their effect on subsequent processing stages (densification) and composite properties was determined. 相似文献
8.
As previously reported, high surface area microporous carbons with long-range order can be synthesized by using zeolite Y as a template. In this work, an attempt is made to synthesize porous carbon using several other types of zeolites (zeolite β, ZSM-5, mordenite and zeolite L). Special attention is paid to whether the structural regularity of each zeolite can be transferred to the carbon structure as well as with the case of zeolite Y. The carbon filling method was then examined to see which gives the highest regularity to the carbon structure. It has been found that the optimum carbon filling method for zeolite Y is not an optimum one for the other zeolites and the degree of the regularity of long-range ordering in the carbons strongly depends on zeolite type. The order of the regularity in the resultant carbons is zeolite β>>zeolite L>mordenite>ZSM-5. The effect of zeolite type on the regularity is discussed in relation to the size and the shape of the zeolite channels. 相似文献
9.
10.
《材料科学技术学报》2019,35(7):1255-1260
At high temperature, the oxide redox reactions of ceria can split H2O and CO2 to produce H2 and CO, so porous ceria with high temperature resistance and high specific surface area has an important foreground in clean energy applications. In this work, a reticulated porous ceria ceramic material with interconnected porous structure was prepared by the impregnation technique using organic polyurethane sponges as template. The influences of pretreated sponge, dipping time length, pore size and sintering temperature on the porosity and strength of the porous ceria ceramics were systematically studied. With the increasing sintering temperature, the glass phase occurred and led to an increase in strength, but an decrease in porosity. Eventually, we analyzed the relationships between porosity and strength of these porous materials, aiming to provide theoretical and practical references for its application in clean-energy field. 相似文献