KingSCADA和工业实时数据库软件在垃圾渗滤液工程上的应用

本文介绍亚控KingSCADA软件和工业库KingHistorian搭建的系统实现了对垃圾渗滤液处理项目的工艺展示、数据实时监视、设备控制等功能,达到很好的应用效果。     

Microorganisms in landfill bioreactors for accelerated stabilization of solid wastes

Landfill bioreactors (LBRs) with management of leachate and biogas have presented numerous advantages such as accelerated stabilization of solid wastes, reduced amount of leachate, and in situ leachate treatment. Such advantages have minimized environmental risks, have allowed extension of the useful life of the landfill site, and have fostered cost reduction. LBRs of three types have been developed using both anaerobic and aerobic modes: anaerobic, aerobic, and hybrid. Microorganisms in landfills cause various reactions related with organic fractions and heavy metals. Such functions have been stimulated in LBRs by recirculation of leachate with or without aeration. To date, most studies of microorganisms in LBRs have analyzed bacteria and archaea based on 16S rRNA genes and have analyzed fungi based on 18S rRNA genes from a taxonomical viewpoint. Indicator genes for specific functions in LBRs such as nitrification, denitrification, and methane production have also been monitored. The population dynamics of microorganisms in LBRs have been partially clarified, but the obtained data remain limited because of highly heterogeneous features of solid wastes inside LBRs. Systematic monitoring of microorganisms should be established to improve LBR performance.     

Optimum Ozone Dosage of Preozonation and Characteristic Change of Refractory Organics in Landfill Leachate

Preozonation on landfill leachate was carried out. COD removal rate has an obvious inflection at ozone dosage 0.186 mg_O3/mg_COD in ozonation process. Seven sets of identical O₃-SBR combined process under different ozone dosages were studied. The results indicated that the best COD removal rate of synergetic effect is also at 0.186 mg_O3/mg_COD. New organic substances produced after ozonation was confirmed by an excitation-emission matrix (EEM). Carbon dioxide production increased from 36.3 mg to 75.7 mg after ozonation, confirming that biodegradability of refractory organics in landfill leachate was enhanced. All the arguments indicated that the inflection point of COD removal by ozonation has a great significance for preozonation.     

Removal of bisphenol A and 17α-ethinyl estradiol from landfill leachate using single-walled carbon nanotubes

In this study, the adsorption of bisphenol A (BPA) and 17α-ethinyl estradiol (EE2) from landfill leachate onto single-walled carbon nanotubes (SWCNTs) was investigated. Different leachate solutions were prepared by altering the pH, ionic strength, and dissolved organic carbon (DOC) in the solutions to mimic the varying water conditions that occur in leachate during the various stages of waste decomposition. The youngest and oldest leachate solutions contained varying DOC and background chemistry and were represented by leachate Type A (pH = 5.0; DOC = 2500 mg/L; conductivity = 12,500 μS/cm; [Ca²⁺] = 1200 mg/L; [Mg²⁺] = 470 mg/L) and Type E (pH = 7.5; DOC = 250 mg/L; conductivity = 3250 μS/cm; [Ca²⁺] = 60 mg/L; [Mg²⁺] = 180 mg/L). These solutions were subsequently combined in different ratios to produce intermediate solutions, labeled B-D, to replicate time-dependent changes in leachate composition. Overall, a larger fraction of EE2 was removed as compared to BPA, consistent with its higher log K_OW value. The total removal of BPA and EE2 decreased in older leachate solutions, with the adsorptive capacity of SWCNTs decreasing in the order of leachate Type A > Type B > Type C > Type D > Type E. An increase in the pH from 3.5 to 11 decreased the adsorption of BPA by 22% in young leachate and by 10% in old leachate. The changes in pH did not affect the adsorption of EE2 in the young leachate, but did reduce adsorption by 32% in the old leachate. Adjusting the ionic strength using Na⁺ did not significantly impact adsorption, while increasing the concentration of Ca²⁺ resulted in a 12% increase in the adsorption of BPA and a 19% increase in the adsorption of EE2. DOC was revealed to be the most influential parameter in this study. In the presence of hydrophilic DOC, represented by glucose in this study, adsorption of the endocrine disrupting compounds (EDCs) onto the SWCNTs was not affected. In the absence of SWCNTs, hydrophobic DOC (i.e., humic acid) adsorbed 15-20% of BPA and EE2. However, when the humic acid and SWCNTs were both present, the overall adsorptive capacity of the SWCNTs was reduced. Hydrophobic (π-π electron donor-acceptor) interactions between the EDCs and the constituents in the leachate, as well as interactions between the SWCNTs and the EDCs, are proposed as potential adsorption mechanisms for BPA and EE2 onto SWCNTs.     

垃圾渗滤液中氨氮的处理技术

阐述了氨氮对垃圾渗滤液处理效果的影响,介绍了垃圾渗滤液中氨氮的脱除方法、技术特点及工作原理,结合国内外的工程实例,对各种处理技术进行了分析比较。     

ABR反应器对垃圾渗滤液的处理试验研究

ABR工艺在处理垃圾渗滤液中具有其他厌氧生物反应器所达不到的优点。尤其是对B/C低、氨氮浓度高、COD浓度高的废水处理,通过调节回流比、HRT、碱度等参数后,可以取得很好的处理效果。在本次实验中,HRT控制在18h后明显提高的垃圾渗滤液的可生化性及C/N,使ABR出水CODcr去除率达到75%,C/N为6.72,对后续好氧反应起到了重要作用。在调控一定回流比后,为提供厌氧氨氧化所需的电子受体NO-3和NO-2实现脱氮。反应器在经过120d的培养驯化,氨氮进水为460mg/L,ABR对氨氮的去除率稳定在80%。不同格室的厌氧颗粒污泥都得到很好的驯化并在其合适的环境中发挥各自的功能。     

Treatment of Industrial Landfill Leachates By Chemical And Biological Methods: Ozonation,Ozonation + Hydrogen Peroxide,Hydrogen Peroxide And Biological Post-Treatment For Ozonated Water

The objective of this study was to determine a suitable treatment method for variable waters from a forest industry landfill site. The main target was to find out the impact of different chemical treatments on the composition and biodegradability of those waters. Earlier studies have shown that biological treatment alone is not a suitable treatment method for these waters. That is why ozonation, ozonation+hydrogen peroxide and hydrogen peroxide treatment were studied in a laboratory scale. The ozonated waters were also biologically post-treated.

All the methods studied were able to degrade a part of the organic compounds and convert them into a more biodegradable form. Also the BOD/COD -ratio increased significantly. The removal of organic compounds by ozonation was 30 - 50 %. Hydrogen peroxide addition did not improve the degradation. The combination of pre-ozonation and biological post-treatment gave a total TOC removal between 50 - 95 %.     

A fractal-like kinetics equation to calculate landfill methane production

Landfill appears as a convenient choice to get rid of municipal solid waste while providing energy, due to methane generated through anaerobic fermentation. However, without capture and treatment landfill gas is considered an important source of atmospheric methane. The control and use of this gas require knowledge of both, current yield and long-term accumulative production. These values are usually calculated with mathematical expressions that consider 100% of conversion, and homogeneous chemical reactivity inside the fill. Nevertheless, fermentation in landfills is erratic and spatially heterogeneous. This work introduces a fractal-like chemical kinetics equation to calculate methane generation rate from landfill, Q_CH4 (m³/year), in the way: where fermentable wastes are partitioned in readily, moderately and slowly biodegradable categories, L₀ is the potential of methane yield of refuse (m³/tonne under standard conditions), d_s is the solid-phase fracton dimension, k_i is the reaction kinetics constant of waste category i (year⁻¹), and t_j is the time from the year of burying j (year), C_ij⁰ (kg/tonne) and M_ij (kg) are the initial concentration and the mass of waste category i landfilled in year j, respectively. The idea behind this equation is that methane production kinetics is limited by the diffusion of hydrolyzed substrate into a heterogeneous solid-phase towards discrete areas, where methanogenesis occurs. A virtual study for a hypothetical case is developed. The predictions from this fractal approach are contrasted with those coming from two equations broadly used in the industrial work. The fractal-like kinetics equation represents better the heterogeneous nature of the fermentation in landfills.     

Geomembrane puncture and strains from stones in an underlying clay layer

Results from physical experiments are presented to assess the possible puncture of a 1.5-mm-thick HDPE geomembrane and, if not punctured, the maximum tensile strains in the deformed geomembrane from intentionally placed stone particles in an underlying compacted clay liner when subjected to applied vertical stresses. The influences of applied pressure, clay water content, stone size, stone burial depth and protection layer on the geomembrane tensile strains are reported. Except in one test conducted to a pressure of 2000 kPa, the geomembrane was not punctured in the short-term tests conducted; however, it was subjected to local indentations and tensile strains from the underlying gravel particles that may exceed proposed allowable long-term strain limits. Tensile strains for the specific 35 mm stones tested when initially flush with the clay surface were negligible, even up to pressures of 1000 kPa, provided the initial water content of clay was 12%. Increases in water content or stone size were found to increase the tensile strain. Placing the clay at the lower limit of acceptable water content was found to be beneficial in terms of reducing strains from buried stones; however, this was also found to make the geomembrane more susceptible to stone particles sitting on top of the clay surface and hence careful site inspection is required to remove all visible stones that sit on top of the clay surface.     

Size charge fractionation of metals in municipal solid waste landfill leachate

Municipal solid waste landfill leachates from 9 Norwegian sites were size charge fractionated in the field, to obtain three fractions: particulate and colloidal matter >0.45microm, free anions/non-labile complexes <0.45microm and free cations/labile complexes <0.45microm. The fractionation showed that Cd and Zn, and especially Cu and Pb, were present to a large degree (63-98%) as particulate and colloidal matter >0.45microm. Cr, Co and Ni were on the contrary present mostly as non-labile complexes (69-79%) <0.45microm. The major cations Ca, Mg, K, and Mn were present mainly as free cations/labile complexes <0.45microm, while As and Mo were present to a large degree (70-90%) as free anions/non-labile complexes <0.45microm. Aluminium was present mainly as particulate and colloidal matter >0.45microm. The particulate and colloidal matter >0.45microm was mainly inorganic; indicating that the metals present in this fraction were bound as inorganic compounds. The fractionation gives important information on the mobility and potential bioavailability of the metals investigated, in contrast to the total metal concentrations usually reported. To study possible changes in respective metal species in leachate in aerated sedimentation tanks, freshly sampled leachate was stored for 48h, and subsequently fractionated. This showed that the free heavy metals are partly immobilized during storage of leachate with oxygen available. The largest effects were found for Cd and Zn. The proportion of As and Cr present as particulate matter or colloids >0.45microm also increased.