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Xizhuang Liang Peng Wang Fengxia Tong Xiaolei Liu Cong Wang Minrui Wang Qianqian Zhang Zeyan Wang Yuanyuan Liu Zhaoke Zheng Ying Dai Baibiao Huang 《Advanced functional materials》2021,31(8):2008656
p-type tetragonal zircon BiVO4 nanocrystal photocathodes (P-BVO) and n-type monoclinic scheelite BiVO4 nanoporous photoanodes (N-BVO) are prepared by a hydrothermal method and an electrochemical synthesis method, respectively. Pt nanoparticles and cobalt-phosphate (Co-Pi) as co-catalysts are loaded by an electrodeposition way to improve the photoelectrochemical (PEC) performance of BiVO4 (BVO) electrodes. After modification, a monochromatic incident photon-to-current conversion efficiency (IPCE) of P-BVO/Pt at 360 nm is improved by 2.2 times, and the highest IPCE of N-BVO/Co-Pi at 440 nm is increased by 1.7 times. The calculated electron-hole separation yield and the charge carrier injection yield of N-BVO/Co-Pi at 1.23 VRHE are further improved to 80% and 86%, respectively. The surface modification also results in the latest ≈0.2% half-cell solar-to-hydrogen energy conversion efficiency (HC-STH) for a P-BVO/Pt photocathode and a higher ≈1.16% half-cell applied bias photon-to-current conversion efficiency (ABPE) for an N-BVO/Co-Pi photoanode. Furthermore, the prepared photoelectrodes are proved to have excellent stability for water splitting. Above all, a tandem-type PEC cell containing the newly developed P-BVO/Pt photocathode and an N-BVO/Co-Pi photoanode is built for the first time, which evolves H2 and O2 at a stoichiometric ratio of 2:1 with a bias-free STH of 0.14%. 相似文献
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A solar water splitting cell composed of WO3, Polymer Electrolyte Membrane (PEM) and Pt was constructed for producing hydrogen from deionized water in sunlight. Spectral responsivity measurements under various temperatures and bias voltages were conducted for the cell using the Incident Photon to Current Efficiency (IPCE) method. For comparison, a known WO3 Photo Electro Chemical (PEC) cell containing H3PO4 electrolyte, WO3/H3PO4/Pt, was tested using the same test method. The WO3/PEM–H2O/Pt cell showed better Quantum Efficiency (QE) performance compared to that obtained from the cell with the chemical electrolyte. For the first time, spectral responsivity of photo water splitting process without bias power was unveiled in the new WO3 cell, demonstrating the self-sustained photo electrolysis capability. Bias voltage effect on Solar to Hydrogen (STH) conversion efficiency was dramatic in the range from 0.2 V to 1.2 V and suppressions of STH were observed when high bias voltages were applied. In addition, a strong temperature effect on the energy conversion efficiency at high bias voltage was observed in the cell containing PEM–H2O, revealing that the STH at 54 °C is nearly five times that at 14 °C. 相似文献
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