Biodegradation of monoaromatic hydrocarbons in aquifer columns amended with hydrogen peroxide and nitrate

The ability of indigenous microorganisms to degrade benzene, toluene, ethylbenzene and xylenes (BTEX) in laboratory scale flow-through aquifer columns was tested separately with hydrogen peroxide (110 mg/l) and nitrate (330 mg/l as NO₃⁻) amendments to air-saturated influent nutrient solution. The continuous removal of individual components from all columns relative to the sterile controls provided evidence for biodegradation. In the presence of hydrogen peroxide, the indigeneous microorganisms degraded benzene and toluene (> 95%), meta- plus para-xylene (80%) and ortho-xylene (70%). Nitrate addition resulted in 90% removal of toluene and 25% removal of ortho-xylene. However, benzene, ethylbenzene, meta- and para-xylene concentrations were not significantly reduced after 42 days of operation. Following this experiment, low dissolved oxygen (< 1 mg/l) conditions were initiated with the nitrate-amended column influent in order to mimic contaminated groundwater conditions distal from a nutrient injection well. Toluene continued to be effectively degraded (> 90%), and more than 25% of the benzene, 40% of the ethylbenzene, 50% of the meta- plus para-xylenes and 60% of the ortho-xylene were removed after several months of operation.     

用土壤含水层处理系统去除水库微污染有机物的试验研究

本文针对当前中国饮用水源污染以微污染为主的特点，以北京三家店水库原水和永定河河道砂为研究对象，设计了用于表征土壤含水层处理系统的一维土柱，进行污水净化效果的试验研究。结果表明，土壤含水层处理系统对三家店水库微污染水中的有机物有一定的去除效果，在0．12m／d的水力负荷条件下，对CODMo去除率虽然仅为15％，但是出水达到了地表水Ⅱ类水质标准；对BOD5的去除率达到了55％，可以被有效地去除。渗透速率相同时，水力负荷周期对去除效果的影响不明显，但在保证一定水力负荷的情况下，可适当延长落干期，恢复土壤的渗透能力，达到较好的处理效果。同时，土壤含水层处理系统的净化能力主要发生在土层50cm以内。     

Investigations of water inrushes from aquifers under coal seams

In many coal mines, limestone-confined aquifers underlie coal seams. During coal extraction from these mines, water inrushes occur frequently with disastrous consequences. This paper introduces the hydrogeological conditions of the coal mines and the potential water inrush disasters from aquifers under coal seams. It then presents the water inrush mechanism. The main factors which control water inrushes include strata pressure, mining size, geologic structures and the water pressure in the underlying aquifer. Analysis shows that reduction of confinement due to mining is the major cause of the water-conducting failure in the floor strata. The depth of the failure zone is strongly dependent on the mining width. This paper also presents field observation results of the water-conducting failure in the floor strata, and applies the finite element method coupled with stress-dependent permeability to analyze hydraulic conductivity enhancement due to coal extraction. Finally, theoretical and empirical methods to predict water inrushes are given, and technical measures for improving mine design and safety for coal extraction over aquifers are presented. These measures include fault and fracture grouting and mining method modification such as changing long-wall to short-wall mining.     

Theory of Seepage into an Auger Hole in a Confined Aquifer Overlying a Gravel Substratum

An analytical solution is presented to the problem of steady groundwater flow seeping into a pumped cylindrical hole partially penetrating a homogeneous and anisotropic confined aquifer overlying a gravel substratum. Solutions are obtained for two general cases of the problem: (1) when the level of the pumped hole is below the confining layer; (2) when it is above it. The validity of the proposed theory is tested by comparing analytical predictions obtained for a few flow situations with corresponding results obtained by numerical means. The theory presented here can be utilized to convert the rate of rise of water in a pumped auger hole into directional conductivities of soil, in areas where water is found to be in a confined state overlying a gravel substratum. The study shows that the conductivity values calculated by neglecting the confining pressure of an artesian aquifer with a gravel base [i.e., by applying the existing (Boast and Kirkham in 1971), auger hole seepage theory for a phreatic aquifer with a gravel base to confined situations] may result in serious error; hence, the artesian head of an aquifer must be accounted for while computing the conductivity values. Further, it is observed that the area contributing flow to a pumped auger hole/well with a gravel base is mostly restricted to a short radial distance from the center of the hole, particularly for situations where the gravel substratum is located close to the bottom of the hole. This is in contrast to auger hole flow situations overlying an impervious substratum, where the domain contributing flow is mostly spread out to a considerable distance from the center of the hole.     

江苏复杂断块高含水单元改善水驱效果的技术对策

在分析高含水开发单元特点的基础上,针对该阶段剩余油的品位、分布和油水关系极为复杂、挖潜难度大的技术难点,提出了适合江苏复杂断块油田高含水开发单元改善水驱开发效果的思路和工作程序、技术对策,并在真武油田高含水开发单元进行了实际应用,取得了良好的效果.     

Water table fluctuation with a random initial condition

The nonlinear Boussinesq equation is used to understand water table fluctuations in various ditch drainage problems. An approximate solution of this equation with a random initial condition and deterministic boundary conditions, recharge rate and aquifer parameters has been developed to predict a transient water table in a ditch-drainage system. The effects of uncertainty in the initial condition on the water table are illustrated with the help of a synthetic example. These results would find applications in ditch-drainage design.Notation A / tanh t - a lower value of the random variable representing the initial water table height at the mid point - a+b Upper value of the random variable representing the initial water table height at the midpoint - B tanh t - C 4/ - h variable water table height - h mean of the variable water table height - h _m variable water table height at the mid point - h _m mean of the variable water table height at the mid point - K hydraulic conductivity - L half spacing between the ditches - m ₀ initial water table height at the mid point - N Uniform rate of recharge - S specific yield - t time of observation - x distance measured from the ditch boundary - (4/SL)(NK)^1/2 - (L/4)(N/K)^1/2 - dummy integral variable     

Streamflow alteration and habitat ramifications for a threatened fish species in the Central United States

In the Central United States, the Arkansas darter (Etheostoma cragini) is listed as a threatened fish species by the State of Kansas. Survival of the darter is threatened by loss of habitat caused by changing streamflow conditions, in particular flow depletion. Future management of darter populations and habitats requires an understanding of streamflow conditions and how those conditions may have changed over time in response to natural and anthropogenic factors. In Kansas, streamflow alteration was assessed at 9 U.S. Geological Survey streamgages in 6 priority basins with no pronounced long‐term trends in precipitation. The assessment was based on a comparison of observed (O) and predicted expected (E) reference conditions for 29 flow metrics. The O/E results indicated a likely or possible diminished flow condition in 2 basins; the primary cause of which is groundwater‐level declines resulting from groundwater pumping for irrigated agriculture. In these 2 basins, habitat characteristics adversely affected by flow depletion may include stream connectivity, pools, and water temperature. The other 4 basins were minimally affected, or unaffected, by flow depletion and therefore may provide the best opportunity for preservation of darter habitat. Through the O/E analysis, anthropogenic streamflow alteration was quantified and the results will enable better‐informed decisions pertaining to the future management of darters in Kansas.     

深部互层咸水层二氧化碳分布特征探究

通过构造砂页岩互层结构,并根据渗透率对砂岩层岩性进行分类,建立了多岩相非均质模型,利用多组分多相流数值模拟软件TOUGH2/ECO2N探究二氧化碳注入深部互层咸水层后的分布特征,结果显示二氧化碳聚集在低渗透性的页岩层底部,呈分层结构,砂岩层中优先在渗透率较高的岩相中运移并呈分散分布;超临界二氧化碳不断溶于地层水,含饱和二氧化碳的咸水密度增加并缓慢下沉,无明显分层现象。     

承压含水层地下水稳定流的有限层分析

有限层法是一种对空间某一方向进行数值离散,而在其余两方向采用连续函数的半数值半解析方法.该方法能有效地将三维问题简化为一维问题求解,从根本上解决了常用数值分析方法在模拟三维地下水运动时存在的计算工作量大、占用内存多、耗时大等缺点.文中基于有限层法的优点,推导了以伽辽金法结合贝塞耳函数为基础的层状非均质各向异性承压含水层的稳定流有限层方程,并编制了相应的计算程序.通过对2个经典算例的数值解与解析解对比分析,验证了该方法的正确性.     

Characteristics of water inflow and chemical grouting treatment of a Liu Yuanzi Coal Mine shaft in the Ordos Basin

During shaft constructing, a borehole water inflow of 30 m3/h was encountered in Liu Yuanzi Coal Mine in the southwestern Ordos Basin, whose aquifer is mainly cretaceous. On the basis of regional hydrogeological conditions, a mercury intrusion method and scanning electron microscope were used in this study. We conclude that the loose, porous and easily collapsible clay particles of the cretaceous aquifer rock mass were the major geological cause for water hazards during the construction of the shaft. We propose an approach of chemical grouting from the working surface and in the end succeeded in blocking the water.