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1.
2.
Absorption spectra of several types of diesel fuel are studied experimentally. Index of refraction of these fuels is calculated using subtractive Kramers-Krönig analysis. The ageing process of fuels is simulated by prolonged boiling. Radiative properties of diesel fuel droplets are calculated using the Mie theory and a simplified approach, based on approximations of absorption and scattering efficiency factors. It is pointed out that the accuracy of the simplified approach is sufficient for practical applications in the visible and infrared ranges, for various types of diesel fuel, and for droplet radii in the range from 5 to 50 μm. The monodisperse approximation is shown to be applicable for the analysis of infrared radiative properties of realistic polydisperse diesel fuel sprays. 相似文献
3.
ImprovingWearResistanceoftheNibaseThermalSprayWeldingCoatingUsingRareEarthsZhaiGuangjie(翟光杰)(InstituteofPhysics,AcademicaSi... 相似文献
4.
The objective of this paper is to prove that the Clausius inequality must be re-stated to have general applicability for heat transfer involving radiative fluxes. The integrand (đQ/T) of the Clausius expression applies to heat conduction and convection, but does not hold for most radiative transfer scenarios, with the exception of reversible infinitesimal net blackbody radiation transfer. In other cases involving radiative transfer, the equality holds for a cycle even though irreversible heat addition by radiative transfer occurs. This is without the erroneous presumption of entropy destruction anywhere in the cycle. Thus, the Clausius inequality indicates reversibility for a cycle that includes an irreversible process. Further, in some radiative cases the quantity đQ/T, where T is the boundary temperature, is not the entropy transfer at the system boundary, and in fact, primarily represents entropy production within the system. It is also clear that in another case considered, the quantity đQ/T had no physical meaning whatsoever. Consequently, the Clausius expression has been re-stated so that it is applicable to cycles with processes involving any form of heat transfer. A new integrand (đQcc/T + đSNet,Rad) is presented, allowing the Clausius inequality to generally apply to all heat transfer scenarios. The work in this paper emphasizes the need to re-state other fundamental equations allowing applicability to all heat transfer processes, and draws attention to the unique character of radiative entropy calculations. 相似文献
5.
Dong Zhang 《Korean Journal of Chemical Engineering》2008,25(5):1205-1207
Ceria-zirconia solid particles have been recognized as a key material of the automotive exhaust catalysts since they can release
and uptake oxygen owing to the rapid reversible oxidation states of cerium between Ce3+ and Ce4+. Several methods have recently been described to prepare the CeO2-ZrO2 solid particles used in the catalysts. In this paper, a new coprecipitation method is used to prepare the CeO2-ZrO2 solid particles. The Ce-Zr alcogel is dried and calcined in flowing N2 not in flowing air under atmospheric pressure. The results show that the ceria-zirconia sample calcined at 650 °C has high
surface area over 90 m2g−1, which drops to 40 m2g−1 following treatment at 900°C. 相似文献
6.
M. Jayasankar 《Materials Letters》2007,61(3):790-793
Formation of aluminium titanate (AT) has been achieved at low temperature through sol-gel process using boehmite and titanium hydroxide as precursors by controlling the particle size at nanoscale followed by in-situ peptisation. The formations of AT phase, particle size distributions, sintering and thermal expansion characteristics, and microstructural features have been reported. DTA and XRD analysis have been performed to confirm the formation of AT. A 94% relative density was obtained for aluminium titanate sintered at 1550 °C with controlled grain size in the range of 2-3 μm. 相似文献
7.
Measurements of gel time of the epoxy system DGEBA(n=0)/m-XDA were carried out using rheometry and dielectric analysis with the objective of checking the validity of Mangion-Johari equation (DEA) and Harran-Laudouard criterium (rheometry) for gel time determination. In this work, gel times obtained by rheometry and dielectric analysis are compared and conversions at gel time calculated. From the experimental results obtained for gel times it was found a reasonable agreement between the two techniques that lead to gel conversion values very close to those obtained using Flory equation. 相似文献
8.
从冷却曲线上相变段倾角最小原则出发,研究了新型激冷剂的配比与热分析法检测铸铁成分精度的关系,实验结果表明,能使相变段倾角最小的成分配比,也能提高对铸铁成分的热分析和检测精度。 相似文献
9.
Preparation of polyimide-epoxy composites 总被引:2,自引:0,他引:2
Kevin Gaw Mitsutoshi Kikei Masa-aki Kakimoto Yoshio Imai 《Reactive and Functional Polymers》1996,30(1-3):85-91
The formation of a three dimensional network of crosslinked epoxy leads all unmodified epoxies to have inherent brittleness and relatively low degradation temperatures. Polyimides, on the other hand, are widely used for applications that require high degrees of flexibility and thermal resistance. Here, we have focused on the preparation of epoxy systems cured with polyamic acids instead of traditional amino-group-containing hardening agents. The cure behavior and potential reaction mechanisms of EPON 828 resin and polyamic acid mixtures were evaluated by DSC and TGA. Thermal analysis showed a complex reaction sequence taking place in the mixture and also determined the extent of reaction of the polyamic acid with itself and the competitive reaction of the polyamic acid with the epoxy. The compositions of the mixtures were varied to see the dependence of the cure behavior on component concentrations. Solutions of the two components did not phase separate and also phase separation was not apparent either optically or microscopically in the cured samples. This phase behavior was attributed to a unique in situ reaction. A novel solvent system for the polyamic acid precursor was also used. 相似文献
10.
隧道小孔中超薄SiO2的生长是EEPROM电路制造的关键工艺之一。采用SUPREM-Ⅲ工艺模拟程序对超薄SiO2的热生长进行了工艺模拟,经过大量的工艺实验及优化,确定了超薄SiO2的最佳生长条件,生长出的SiO2性能良好,完全可满足EEPROM研制的要求。 相似文献