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1.
B. A. Trofimov G. F. Myachina I. V. Rodionova A. G. Mal'kina I. A. Dorofeev T. I. Vakul'skaya L. M. Sinegovskaya T. A. Skotheim 《应用聚合物科学杂志》2008,107(2):784-787
Ethynedithiol‐based polyeneoligosulfides have been synthesized in 96% yield by the reaction of sodium acetylides (HC?CNa, NaC?CSNa) and elemental sulfur through the Na? Csp bond in liquid ammonia with the following spontaneous polymerization of ethynedithiols (HSC?CSH) formed by the hydrolysis. The polyeneoligosulfides synthesized are brown powders (up to 77% sulfur content, mp 128–184°C), partially soluble in organic solvents. They are high‐resistance semiconductors (10?13 to 10?14 S cm?1), possess paramagnetic (1017 to 1018 spin g?1) and redox properties. The oligosulfides obtained, being redox systems capable of reversible redox processes, provide high values of discharge capacity (345–720 mA h g?1) of rechargeable lithium‐sulfur batteries. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
2.
A novel current source inverter system interconnected to the single‐phase grid is proposed. It has the same construction as the conventional three‐phase current source inverter that is interconnected to the single‐phase three‐wire distribution system. Though the proposed circuit has no output transformer, it can be equivalently performed as the single‐phase double cascade inverter by diverting the pole transformer in the utility system. By controlling the appropriate scheme, the output currents can be obtained as the five‐level waveforms and their distortions can be decreased sufficiently. It is applied to the interactive electric energy storage system with batteries and the basic discharging characteristics are discussed experimentally. © 2004 Wiley Periodicals, Inc. Electr Eng Jpn, 150(2): 50–61, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10380 相似文献
3.
Possible use of methylbenzenes as electrolyte additives for improving the overcharge tolerances of Li-ion batteries 总被引:1,自引:0,他引:1
Based on the voltammetric behaviour of a series of methyl-substituted benzenes in 1M LiPF6/EC-DMC electrolyte, xylene was selected and tested as an electrolyte additive for overcharge protection of Li-ion batteries. From the overcharge curves, CV behaviour and SEM observations of the cells in the presence of xylene, it was found that the additive can polymerize at the overcharged voltage to form a dense layer of isolating polymer film at the cathode surface, which blocks off further oxidation of the electroactive material and electrolyte and, therefore, improves the overcharge tolerance of the Li-ion battery. In addition, the xylene additive has shown only a slight influence on the cycling behaviour. 相似文献
4.
A novel sol–gel method based on V2O5·nH2O hydro-gel was developed to synthesize nanocrystalline Li3V2(PO4)3/carbon composite material. In this route, V2O5·nH2O hydro-gel, NH4H2PO4, Li2CO3 and high-surface-area carbon were used as starting materials to prepare precursor, and the Li3V2(PO4)3/carbon was obtained by sintering precursor at 750 °C for 4 h in flowing argon. The sol–gel synthesis ensures homogeneity of the precursors and improved reactivity. The sample was characterized by XRD, SEM and TEM. X-ray diffraction results show Li3V2(PO4)3 sample is monoclinic structure with the space group of P21/n. The TEM image indicates that the Li3V2(PO4)3 particles modified by conductive carbon are about 70 nm in diameter. The Li3V2(PO4)3/carbon system showed that the discharge capacities in the first and 50th cycle are about 155.3 and 143.6 mAh/g, respectively, in the range of 3.0–4.8 V. The sol–gel method is fit for the preparation of Li3V2(PO4)3/carbon composite material which may offer some favorable properties for commercial application. 相似文献
5.
Yong Min Lee 《Electrochimica acta》2006,52(4):1582-1587
Highly ion-conductive solid polymer electrolyte (SPE) based on polyethylene (PE) non-woven matrix is prepared by filling poly(ethylene glycol) (PEG)-based crosslinked electrolyte inside the pores of the non-woven matrix. The PE non-woven matrix not only shows good mechanical strength for SPE to be a free-standing film, but also has very porous structure for high ion conductivity. The ion conductivity of SPE based on PE non-woven matrix can be enhanced by adding sufficient non-volatile plasticizer such as poly(ethylene glycol) dimethyl ether (PEGDME) into ion conduction phase without sacrificing mechanical strength. SPE with 20 wt.% crosslinking agent and 80 wt.% non-volatile plasticizer shows 3.1 × 10−4 S cm−1 at room temperature (20 °C), to our knowledge, which is the highest level for SPEs. It is also electrochemically stable up to 5.2 V and has high transference number about 0.52 due to the introduction of anion receptor as an additive. The interfacial resistance between Li electrode and SPE is low enough to perform charge/discharge test of unit cell consisting of LiCoO2/SPE/Li at room temperature. The discharge capacity of the unit cell shows 87% of theoretical value with 86% Coulombic efficiency. 相似文献
6.
Electrochemical properties of some cobalt antimonides as anode materi-als for lithium- ion batteries
ZHAO Xinbing CAO Gaoshao ZHANG Lijuan and XIE JianDepartment of Materials Science Engineering Zhejiang University Hangzhou China 《稀有金属(英文版)》2003,22(4)
Some cobalt antimonides have been prepared and studied as the candidate anode materials for lithium ion batter-ies. Reversible capacities of 424,423 and 546 mA·h·g-1 were measured at the first cycle for as-solidified CoSb2, CoSb3 and annealed CoSb3 respectively. A low lithium ions diffusion coefficient in the order of 10-16 m2·s-1 was estimated from the coulometric titration measurements in the annealed CoSb3 electrode. It was found that the electrochemical properties of fine powders are significantly better than coarse powders. However the SEM picture shows that the nano-sized CoSb3 powders gathered to larger granules, which worsens somewhat the capacity retention of the nano-sized materials, although the volume capacities of the annealed and ball milled CoSb3 remain near twice of that of graphite after 50 cycles. 相似文献
7.
Effect of surface modification of metal hydride electrode on performance of MH/Ni batteries 总被引:1,自引:0,他引:1
A novel method was applied to the surface modification of the metal hydride(MH)electrode of MH/Ni batteries.Both sides of the electrode were plated with a thin silver film about 0.1μm thick using vacuum evaporation plating technology,and the effect of the electrode on the performance of MH/Ni batteries was examined.It is found that the surface modification can enhance the electrode conductivity and decrease the battery ohimic resistance.After surface modification,the discharge capacity at 5C(7.5A)is increased by 212 mA.h and the discharge voltage is increased by 0.11 V,the resistance of the batteries is also decreased by 32%.The batteries with modified electrode exhibit satisfactory durability.The remaining capacity of the modified batteries is 89%of the initial capacity even after 500 cycles.The inner pressure of the batteries during overcharging is lowered and the charging efficiency of the batteries is improved. 相似文献
8.
Jiacheng Yin Na Li Ming Liu Zhigang Li Xuemin Wang Mingren Cheng Ming Zhong Wei Li Yunhua Xu Xian-He Bu 《Advanced functional materials》2023,33(21):2211950
Organic redox-active materials are promising electrode candidates for lithium-ion batteries by virtue of their designable structure and cost-effectiveness. However, their poor electrical conductivity and high solubility in organic electrolytes limit the device's performance and practical applications. Herein, the π-conjugated nitrogen-containing heteroaromatic molecule hexaazatriphenylene (HATN) is strategically embedded with redox-active centers in the skeleton of a Cu-based 2D conductive metal–organic framework (2D c-MOF) to optimize the lithium (Li) storage performance of organic electrodes, which delivers improved specific capacity (763 mAh g−1 at 300 mA g−1), long-term cycling stability (≈90% capacity retention after 600 cycles at 300 mA g−1), and excellent rate performance. The correlation of experimental and computational results confirms that this high Li storage performance derives from the maximum number of active sites (CN sites in the HATN unit and CO sites in the CuO4 unit), favorable electrical conductivity, and efficient mass transfer channels. This strategy of integrating multiple redox-active moieties into the 2D c-MOF opens up a new avenue for the design of high-performance electrode materials. 相似文献
9.
Zhongzhe Li Yufang Chen Xiaoru Yun Peng Gao Chunman Zheng Peitao Xiao 《Advanced functional materials》2023,33(32):2300502
Lithium metal batteries (LMBs), due to their ultra-high energy density, are attracting tremendous attentions. However, their commercial application is severely impeded by poor safety and unsatisfactory cycling stability, which are induced by lithium dendrites, side reactions, and inferior anodic stability. Electrolytes, as the indispensable and necessary components in lithium metal batteries, play a crucial role in regulating the electrochemical performance of LMBs. Recently, the fluorinated electrolytes are widely investigated in high-performance LMBs. Thus, the design strategies of fluorinated electrolytes are thoroughly summarized, including fluorinated salts, fluorinated solvents, and fluorinated additives in LMBs, and insights of the fluorinated components in suppressing lithium dendrites, improving anodic stability and cycling stability. Finally, an outlook with several design strategies and challenges will be proposed for novel fluorinated electrolytes. 相似文献
10.
Changmin Lee Youngjae Hong Dongho Kim Younghwan Lim Jang Wook Choi Sung-Yoon Chung 《Advanced functional materials》2023,33(44):2303763
Protons in aqueous electrolytes can perform as an additional type of charge carrier for insertion/extraction in addition to the primary carrier cations in aqueous rechargeable batteries. Despite many diverse claims regarding the effect of protons, mutually conflicting experimental results and their interpretations without direct evidence have been reported over the last decade. Systematic examinations and analyses are thus imperative to clarify the conditions of proton insertion in aqueous rechargeable batteries. Utilizing V2O5 as a model cathode and beaker-type cells with a sufficient amount of ZnSO4 aqueous electrolytes in this work, it is demonstrated that protons are inserted into the cathode prior to Zn-ions in low-pH conditions (pH ≤ 3.0). In stark contrast, the influence of protons on the discharge voltage and capacity is insignificant, when either the pH becomes higher (pH ≥ 4.0) or the electrolyte volume is considerably low in coin-type cells. Similar behavior of pH-dependent proton insertion is also verified in Na–, Mg–, and Al-ion electrolytes. Providing a resolution to the controversy regarding proton insertion, the present study emphasizes that the influence of protons substantially varies depending on the pH and relative volume of electrolytes in aqueous batteries. 相似文献