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1.
W. Sjoerd Kijlstra Joop C.M.L. Daamen Jolinde M. van de Graaf Bart van der Linden Eduard K. Poels Alfred Bliek 《Applied catalysis. B, Environmental》1996,7(3-4):337-357
The effect of water on the selective catalytic reduction (SCR) of nitric oxide with ammonia over alumina supported with 2–15 wt.-% manganese oxide was investigated in the temperature range 385–600 K, with the emphasis on the low side of this temperature window. Studies on the effect of 1–5 vol.-% water vapour on the SCR reaction rate and selectivity were combined with TPD experiments to reveal the influence of water on the adsorption of the single SCR reactants. It turned out that the activity decrease due to water addition can be divided into a reversible inhibition and an irreversible deactivation. Inhibition is caused by molecular adsorption of water. TPD studies showed that water can adsorb competitively with both ammonia and nitric oxide. Additional kinetic experiments revealed that adsorbed ammonia is present in excess on the catalyst surface, even in the presence of water. Reduced nitric oxide adsorption is responsible for the observed reversible decrease in the reaction rate; the fractional reaction order changes from 0.79 in the absence of water to 1.07 in its presence. Deactivation is probably due to the dissociative adsorption of water, resulting in the formation of additional surface hydroxyls. As the amount of surface hydroxyls formed is limited to a saturation level, the deactivating effect on the catalyst is limited too. The additional hydroxyls condense and desorb in the temperature range 525–775 K, resulting in a lower degree of deactivation at higher temperature. A high temperature treatment at 775 K results in a complete regeneration. The amount of surface hydroxyls formed per unit surface area decreases at increasing MnOx-loading. The selectivity to the production of nitrogen is enhanced significantly by the presence of gas phase water. 相似文献
2.
Substituted uracils were tested as corrosion inhibitors of copper in 3% NaCl medium using electrochemical polarisation, impedance measurements and non-electrochemical techniques (weight loss, IR and UV-visible). This study permitted to follow the evolution of the inhibitory effect of the uracil derivatives, according to their substituents, on copper in 3% NaCl medium. Comparison of results showed that dithiouracil (DTUr) was the best inhibitor. The maximum inhibition efficiency reached 98% at 10−3 M. DTUr adsorbs on the copper surface according to the Frumkin isotherm model. 相似文献
3.
Lamellar zinc pigment reacts in aqueous alkaline media (e.g., water-borne paints) with the evolution of hydrogen. This corrosion reaction can be inhibited by 2-nitrophenol (2-NP), 2,4-dinitrophenol (2,4-DNP), 2-hydroxy-3,5-dinitro-benzoic acid (HDNBA) and 2-hydroxy-3-nitro-benzoic acid (2-H-3-NBA) which all have a nitro-group ortho to a hydroxy-group; this structural part of the inhibitors can be considered as a potential chelating group which may explain the corrosion inhibiting effect. As a rule, with triethylamine (TEA) as neutralizing agent corrosion inhibition is slightly better when compared to dimethylethanolamine (DMEA). With TEA there is complete corrosion inhibition with addition of 2,4-DNP at pH 8 and 10; with 2-H-3-NBA there is complete inhibition at pH 10. 相似文献
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tific Experiment Center of Guangxi Medical University,Nanning 530021,China)Objective:To investigate the mutation pattern of adenomatous polyposis coli(APC),Kirsten-ras(K-ras) and p53 genes in sporadic colorectal cancer tissues.Meth 相似文献
6.
Anacardic acids, 6-pentadec(en)ylsalicylic acids isolated from the cashew Anacardium occidentale L. (Anacardiaceae) nut and apple, were found to possess preventive antioxidant activity while salicylic acid did not show this activity. These anacardic acids prevent generation of superoxide radicals by inhibiting xanthine oxidase (EC 1.1.3.22, Grade IV) without radical-scavenging activity. Notably, the inhibition kinetics of anacardic acids do not follow hyperbolic dependence of enzyme inhibition on inhibitor contents (Michaelis–Menten equation) but follow the Hill equation instead. Anacardic acid (C15:1) inhibited the soybean lipoxygenase-1 (EC 1.13.11.12, Type 1) catalyzed oxidation of linoleic acid with an IC50 of 6.8 μM. The inhibition is a slow and reversible reaction without residual enzyme activity. The inhibition kinetics indicate that anacardic acid (C15:1) is a competitive inhibitor and the inhibition constant, KI, was 2.8 μM. Anacardic acids act as antioxidants in a variety ways, including inhibition of various prooxidant enzymes involved in the production of the reactive oxygen species and chelate divalent metal ions such as Fe2+ or Cu2+, but do not quench reactive oxygen species. The C15-alkenyl side chain is largely associated with the activity. 相似文献
7.
The forming behaviour at high temperature of a modified 9%Cr‐1%Mo (P91) ferritic steel containing B and Ti for elevated temperature service was investigated. The microstructure of the as‐received material is mainly martensite at room temperature, but special etching revealed prior austenite grains of about 25 μm in size. Torsion tests were conducted at temperatures in the range 850 to 1250 °C to simulate the hot rolling process under comparable conditions of temperature, strain rate and strain. The deformation data obtained from these tests were correlated with the Garofalo equation with a stress exponent of 4.6 and an activation energy of 315 kJ/mol. This equation was used to predict the formability behaviour for the rolling process and also to determine the maximum forming efficiency and stability of the steel. A temperature of 1200 °C is recommended to conduct the forming process. 相似文献
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为分析新型低毒有机磷杀虫剂“1%双硫磷颗粒”投放对河道水质的影响,设置不同药剂投放浓度和不同反应时间的室内试验,以TP、NH3-N及S2-为目标因子,分析该药剂投放后水体污染物浓度。结果表明:不同试验组水样中S2-质量浓度均小于0.02 mg/L,NH3-N质量浓度处于0.029~0.036 mg/L之间,均达到地表水Ⅰ类标准;不同浓度药剂投放1 h后,水体TP质量浓度已达到稳定状态,且在60 h内均保持稳定,药剂投加量与水体TP质量浓度呈显著正相关(R2=0.85);不同处理组的药剂在水体中的TP释放量无明显差异,均在1.06~1.30 mg/g之间。“1%双硫磷颗粒”推荐适宜投放量不会使河道水质恶化到劣Ⅴ类,但增加药剂投放量会增加水体TP污染及富营养化风险。 相似文献
10.
A comparative study of high-temperature oxidation of Ni containing 1 at.% Cr and pure Ni was carried out. Instead of the conventional kinetics study using thermogravimetry, a microlithographic marker experiment was designed. Observation of the markers using cross-sectional TEM and SEM has revealed striking differences in the scale morphology, microstructures, and oxidation mechanisms between pure Ni and the Cr-doped Ni substrates. In particular, the results suggest that a small addition of Cr promotes significant inward transport of oxygen. Marker experiments revealed that NiO grown on pure Ni is wholly attributable to outward-cation diffusion. In contrast, NiO grown on Ni–1 at.% Cr exhibited formation of a substantial inner layer having a submicron grain size, established by the markers to have formed from oxygen ingress. For pure Ni, voids were observed to be distributed only within oxide grains. In contrast, for Ni containing 1 at.% Cr, elongated pores formed extensively along oxide-grain boundaries. Formation of new fine-grain oxide in these pores was observed to have sometimes completely resealed the void. It is, therefore, proposed that the transport of oxygen in the case of oxide scale grown on Ni–1 at.% Cr occurs via voids (pores) formed by vacancy coalescence at the grain boundaries. 相似文献