Impact behavior and fractographic study of carbon nanotubes grafted carbon fiber-reinforced epoxy matrix multi-scale hybrid composites

Carbon nanotubes are the most promising reinforcement for high performance composites. Multiwall carbon nanotubes were directly grown onto the carbon fiber surface by catalytic thermal chemical vapor deposition technique. Multi-scale hybrid composites were fabricated using the carbon nanotubes grown fibers with epoxy matrix. Morphology of the grown carbon nanotubes was investigated using field emission scanning electron microscopy and transmission electron microscopy. The fabricated composites were subjected to impact tests which showed 48.7% and 42.2% higher energy absorption in Charpy and Izod impact tests respectively. Fractographic analysis of the impact tested specimens revealed the presence of carbon nanotubes both at the fiber surface and within the matrix which explained the reason for improved energy absorption capability of these composites. Carbon nanotubes presence at various cracks formed during loading provided a direct evidence of micro crack bridging. Thus the enhanced fracture strength of these composites is attributed to stronger fiber–matrix interfacial bonding and simultaneous matrix strengthening due to the grown carbon nanotubes.     

Fatigue in bamboo

This paper describes the results of an experimental programme to determine the fatigue behaviour of bamboo. Bamboo is subjected to cyclic loading, both in the plant itself and subsequently when the material is used in load-bearing applications in the construction industry. However, there is currently no data in the literature describing fatigue in this material. We found that sections of bamboo culm loaded parallel to the culm axis did not undergo fatigue failure: samples either failed on the first loading cycle, or not at all. By contrast, fatigue was readily apparent in samples loaded in compression across the diameter of the culm. The number of cycles to failure increased as the cyclic load range decreased in a manner similar to that found in many engineering materials: fatigue occurred at applied loads as small as 40% of the ultimate strength. Two different species of bamboo were tested and found to have different ultimate strengths but similar high-cycle fatigue strengths. Finite element analysis was used to help understand the progression of fatigue damage and the effect of stress concentration features. Some tentative design rules are proposed to define stress levels for the safe use of bamboo, taking fatigue into account.     

Bamboo biochar-catalytic degradation of lignin under microwave heating

Abstract

Lignin biochar-catalytic depolymerization using biochar Fe-600, Fe-800, Ni-600, Ni-800 catalysts under microwave-heating (180?°C for 30?min) was explored in an ethanol/formic acid (1:1) media. Non-catalyst depolymerization was also studied and compared with the biochar-catalysts results. Characteristics of the bio-char catalysts were analyze by BET, XRD, and FT-IR. GPC, FT-IR, and MALDI-TOF MS spectrometry were also used to characterize the depolymerization products. The experimental results showed that the S_BET, V_t, and V_mec and average pore diameter of the biochars are considerably dependent on the preparation temperature and type of cation (Ni²⁺ or Fe³⁺). The maximum yield of bio-oil product was obtained as 85?wt% with the addition of biochar Ni-600 and the total amount of oligomers or monomers with a molecular weight of 164 to 446 reaches 80.4%.     

纤维在沥青混合料中的应用研究

选用工程中常用的几种纤维,结合工程应用要求,试验分析了纤维的吸湿性、耐热性,并通过网篮析漏试验、动态剪切试验和沉锥试验,讨论了纤维对沥青的稳定和吸附作用,以及纤维对沥青混合料“加筋”效果和作用机理。研究表明有的纤维“吸附、稳定”性能好,而有的纤维“加筋、桥接”效果好,在应用纤维时,应根据纤维的主要特点以及沥青混合料的使用要求来选用。     

Improving Short-Circuit Current Capacity, Resistance, and Breaking Load of OPGW Constructions by Modifying Aluminium Alloy With AlB2

This article presents a method that can be applied to molten AA-6101 alloy to improve electrical properties of the aluminium part of the optical ground wire (OPGW) used in overhead transmission lines to protect phase conductors from lightning strike and to transmit signals and data. AA-6101 alloy in casting of the log as 6 m length and 178 mm diameter for extrusion has been inoculated by AlB₂ to decrease detrimental effects of Cr, Ti, V, and Zr on the conductivity of the material. After inoculation, improved billets were extruded as 9.5 mm diameter feedstock. Required wires drawn from the feedstock according to the construction types of OPGW to be tested were exposed to aging at 175°C, 6 h (T-8). Upon completion of the back-twist and performing-type stranding process, resistance, and short-circuit current capacity and breaking load of the OPGW 88/44 constructions with other metal combinations have been examined and tested to show improvement. Results are summarized in tables and graphically.     

色用缓变光纤中交叉相位调制不稳定性分析

从非线性薛定谔方程出发得到了色散缓变光纤（DDF）中交叉相位调制（XPM）不稳定增益谱。研究了增益谱随入纤功率及光纤纵向色散参量的变化关系。结果表明：反常色散区的增益谱宽比正常色散区宽，且峰值增益高：DDF中XPM不稳定增益谱宽比常规光纤的宽，二者的比值随传输距离和光纤色散参量的乘积成指数增长；DDF的反常色散区是产生调制不稳定的较好的色散介质。     

Experimental Investigation of FRP-Strengthened RC Beam-Column Joints

The results of a comprehensive experimental program, aimed at providing a fundamental understanding of the behavior of shear-critical exterior reinforced concrete (RC) joints strengthened with fiber reinforced polymers (FRP) under simulated seismic load, are presented in this study. The role of various parameters on the effectiveness of FRP is examined through 2/3-scale testing of 18 exterior RC joints. Conclusions are drawn on the basis of certain load versus imposed displacement response characteristics, comprising the strength (maximum lateral load), the stiffness, and the cumulative energy dissipation capacity. The results demonstrate the important role of mechanical anchorages in limiting premature debonding, and they provide important information on the role of various parameters, including: area fraction of FRP; distribution of FRP between the beam and the column; column axial load; internal joint (steel) reinforcement; initial damage; carbon versus glass fibers; sheets versus strips; and effect of transverse beams.     

Deflection Calculation of FRP Reinforced Concrete Beams Based on Modifications to the Existing Branson Equation

Fundamental concepts of tension stiffening are used to explain why Branson’s equation for the effective moment of inertia Ie does not predict deflection well for fiber reinforced polymer (FRP) reinforced concrete beams. The tension stiffening component in Branson’s equation is shown to depend on the ratio of gross-to-cracked moment of inertia (Ig/Icr), and gives too much tension stiffening for beams with an Ig/Icr ratio greater than 3. FRP beams typically have an Ig/Icr ratio greater than 5, leading to a much stiffer response and underprediction of computed deflections as observed by others in the past. One common approach to computing deflection of FRP reinforced concrete beams has been to use a modified form of the Branson equation. This paper presents a rational development of appropriate modification factors needed to reduce the tension stiffening component in Branson’s original expression to realistic levels. Computed deflections using this approach give reasonable results with the right modification factor, and compare well with a more general unified approach that incorporates a realistic tension stiffening model. Comparison is made with the existing and past correction factors recommended by ACI 440 for predicting deflection of FRP beams. The method presently used by ACI 440 gives reasonable estimates of deflection for glass and carbon FRP reinforced beams. However, this method underestimates deflection of aramid FRP reinforced beams and is restricted to rectangular sections. A proposal is made for adoption of a simple modification factor that works well for all types of FRP bar and beam cross-sectional shape.     

Proposed Design of a CFRP Flange-to-Flange Connection for Precast Prestressed Double Tee Systems

The current methods of connecting the flanges of precast double tee members, and their respective short comings in specific situations, are described. A new carbon fiber-reinforced polymer (CFRP) flange-to-flange connection is proposed to eliminate the problems associated with repair requirements for the current connections. Design expressions for the currently used mechanical anchorage and the proposed CFRP connection are presented. A comparative calculation for the two systems is given.