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Effect of ph on the extraction characteristics of succinic acid and the stability of colloidal liquid aphrons 总被引:1,自引:0,他引:1
Predispersed solvent extraction (PDSE) by colloidal liquid aphrons (CLAs) was used for the extraction of succinic acid from
aqueous solution. The loading values for succinic acid in PDSE by CLAs increased with increasing pH values in aqueous phase.
This was due to increasing of the concentration of the undissociated succinic acid. The extractability of PDSE was higher
than that of conventional contacting type extraction because of the interaction between factant and acid molecule. The stability
of CLAs increased with increasing of the pH values in aqueous phase and decreasing of trioctylamine (TOA) concentration in
organic phase. However, the structure of CLAs was stable at all the pH range except very low pH condition.
This paper is dedicated to Professor Wha Young Lee on the occasion of his retirement from Seoul National University. 相似文献
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Colloidal liquid aphrons (CLAs) provide very large interfacial area and thus could enhance interphase mass transfer in multiphase processes. This work characterized the mass transfer behavior of CLAs during mass transfer of benzoic acid from cyclohexane in CLAs to water in a small stirred vessel. From experimental data the overall mass transfer coefficient KL of the surfactant-stabilized CLAs was determined. The influence of stirring speed and concentration of surfactant used for formulating CLAs on KL was investigated. The experimental results show that surfactant adsorbed on the interface of CLAs influences greatly the value of KL, and when the surfactant concentration is below its CMC, the overall CLAs mass transfer coefficient KL (mainly varying with the interfacial mass transfer resistance) could be fitted to the following expression:
KL=H1+H2ln[C+H3]. 相似文献
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