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排序方式: 共有157条查询结果,搜索用时 15 毫秒
1.
研究了杂多酸催化无水乙醇和环氧乙烷(EO)制备乙醇乙醚的醚化反应,考察了不同种类的杂多酸以及醚化反应工艺条件对反应活性和选择性的影响.结果表明,PW_(12)催化剂的反应活性高、反应温度低、选择性好,当用PW_(12)作催化剂,乙醇与环氧化乙烷之比为3.0(mol),反应温度45℃,反应时间1h时,转化率和选择性均超过97%. 相似文献
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分析了环氧乙烷,乙二醇装置工艺系统中有机酸生成的原因.指出在银催化剂作用下,乙烯氧化过程有机酸生成主要成分是甲酸和乙酸,银催化剂不是影响氧化反应器出口醛含量的主要因素;杂质、温度等对反应器出口气中的醛含量有重要影响,也直接影响到装置前系统的有机酸含量;乙二醇后系统中有机酸的增加仅取决于两级吸收及解析工艺的稳定操作。 相似文献
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A series of ethylene oxide(EO)-propylene oxide (PO) random co-polymers (EOPO) were used to form aqueous two-phase systems (ATPS) with ammonium sulfate.Effects of EOPO′s properties on the phase separation behaviors and on the partition of cephalexin and 7-aminodesacetoxicephalosporanic acid(7-ADCA) in ATPS were investigated.Both the molar mass and molar ratio of EO to PO of EOPO could greatly influence partition behaviors of cephalexin and 7-ADCA as well as the binodal curve of ATPS. With the increase of molar mass of co-polymer or the decrease of molar ratio of EO to PO,the critical point of ATPS decreased,the binodal curve became more asymmetry,and both cephalexin and 7-ADCA followed the same tendency to partition into the polymer-poor bottom phase.The experimental results shows that it is feasible to partition cephalexin and 7-ADCA in either the polymer-rich top phase or the polymer-poor bottom phase by choosing a specific phase-forming EOPO. 相似文献
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A type of graft macroinitiator, synthesized by reversible addition–fragmentation chain transfer (RAFT) and atom transfer radical polymerization, was employed to prepare polymer‐dispersed liquid crystals (PDLCs) with graft copolymer matrix; meanwhile, a linear macroinitiator was also synthesized via RAFT polymerization. The effect of linear and graft macroinitiators on the electro‐optical (EO) properties of the PDLCs was investigated. The results showed that the graft macroinitiator could make a large difference to the EO properties of the PDLCs. The memory effect was reduced remarkably, but the driving voltage increased and transmittance decreased. A possible mechanism is presented. © 2014 Society of Chemical Industry 相似文献
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以Aspen Open Solver接口集中的非线性代数方程组(NLA)部分作为研究对象,在对接口集进行系统地分析之后,利用AspenTech提供的接口代码将分别基于梯度和非基于梯度的四种求解算法嵌入生成solver组件,并实现用Aspen Plus调用该solver组件观察各种算法嵌入的结果. 相似文献
9.
The study explores the chemical profile, antimicrobial and antioxidant activity of Boswellia carterii essential oil (EO). The EO significantly inhibited growth and aflatoxin production by the food borne toxigenic strain of Aspergillus flavus at 1.75 μl/ml and 1.25 μl/ml respectively. It exhibited broad fungitoxic spectrum against 12 food borne moulds and also showed strong antioxidant activity, IC50 value and % inhibition of linoleic acid peroxidation being 0.64 μl/ml and 51.68% respectively. The antifungal action of EO was observed in terms of reduction in ergosterol content of plasma membrane of A. flavus. As fumigant in food system in storage containers, the EO provided 65.38% protection against fungal deterioration of Piper nigrum. GC–MS results revealed 31 components of EO. The chemically characterized B. carterii EO may thus be recommended as plant based preservative in view of its antifungal, antiaflatoxigenic, antioxidant activity and efficacy in food system. 相似文献
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本文在前文基础上,从强碱催化非等速率离子反应机理的产物分布公式出发,推导出反应过程中环氧乙烷耗量及加成速率随时间变化的关系方程,并通过实验数据加以讨论,结果表明,本文推导出的关系方程从动力学角度能够较好地反映乙氧基化反应的真实规律。 相似文献