Fenton试剂降低采油污水CODCr的研究与应用

针对辽河油区超稠油采油污水的特点，采用Fenton试剂催化氧化，对采油污水处理进行研究。实验研究及现场应用结果表明，此方法对污水的CODCr具有良好的去除效果。处理后污水经过简单生化，进一步降解污染物，能够实现稳定迭标排放，且具有能耗低、运行成本低和操作简单等特点。     

Synthesis and characterization of polyaniline films using Fenton reagent

The chemical oxidation of aniline to form polyaniline (PANI) films and powder samples was made using Fenton reagent as an oxidizing agent in aqueous sulfuric acid medium. The PANI films were monitored by using the quartz crystal microbalance and the electronic absorption techniques. The optimum concentration was determined and the results were justified by measuring the UV–vis absorption spectra for the in situ PANI films. The conductivity for the PANI films and powder samples, prepared in different conditions, was measured. Also, the IR spectra, X‐ray and the thermogravimetric analysis for the PANI powder formed in the bulk were measured and compared with the polymer prepared using ammonium peroxydisulfate. A preliminary investigation to the dielectric properties of the polymer powder was measured and discussed. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Fenton试剂处理苯酚和甲醛废水的研究

用H2O2同Fe^2 结合的Fenton试剂处理有机废水是一种经典的催化氧化法，这种方法适合于处理废水中高浓度、难降解的有机物质。主要研究了Fenton试剂处理含苯酚和甲醛有机废水样的反应机理和影响因素，试验结果表明：废水中苯酚和甲醛的去除率均可达到95％以上，COD去除率达到85％以上，表明用Fenton法处理含苯酚和甲醛的有机废水是一种非常有效的方法。     

D-HPG废水的预处理

D-对羟基苯甘氨酸制药废水 COD高 ,成分复杂。采用 Fe粉及 Fenton试剂预处理 ,COD总去除率高达98%以上。小试确定了 Fe粉加入量为 14 0 g/ L、曝气时间为 7h、Fenton法预处理 D- HPG废水的最佳反应条件 :H2 O2 质量浓度为 2 1.5 g/ L,Fe SO4 质量浓度为 3.8g/ L,氧化时间为 4 h,p H为 5     

Fenton氧化法处理废水的机理及应用

阐述了Fenton试剂的氧化机理 ,分析了各项因素对氧化效果的影响。介绍了光 -Fenton法、电 -Fenton法及Fenton -混凝法在废水处理中应用情况以及存在的问题 ,并展望了其发展趋势。     

乙醇和PVA的光助Fenton降解机理

Contrast degradation experiments between ethanol and polyvinyl alcohol (PVA) were conducted during H2O2, UV/H2O2, Fenton, and Photo-Fenton processes in this study. UV/VIS spectra showed: that complexes between Fe(Ⅲ) and organics were easily formed and degraded within reaction time. Compared with.the degradation of complex, hydroxyl radicals acted weakly in Fenton or Photo-Fenton process. Hydroxyl radicals involved in Photo-Fenton process were deemed to be generated from the split decomposition of H202, photolysis of Feaq^3 , and degradation of hydrated Fe(IV)-complex but not traditional Fenton reaction. Experimental evidence to support this point was presented in this paper.     

Manganese ferrite nanoparticles synthesized through a nanocasting route as a highly active Fenton catalyst

Spinel ferrite MnFe₂O₄ nanoparticles were synthesized by means of a nanocasting technique using a low-cost mesoporous silica gel as a hard template. The magnetic nanoparticles, of <10 nm diameter and with a surface area of around 100 m²/g, were tested as a heterogeneous Fenton catalyst for the decomposition of hydrogen peroxide under neutral and basic conditions. This catalyst shows a much higher activity than previous heterogeneous catalysts reported in the literature, which is mainly ascribed to its small particle size. Furthermore, the magnetic catalyst can be easily separated from the reaction medium by means of an external magnetic field. The effects of residual silica and the purity of the catalyst (hematite formation) on catalytic activity have been studied and correlated. The results obtained show this catalyst to be a suitable candidate for the removal of pollutants in wastewaters by means of the Fenton heterogeneous reaction.     

光催化-Fenton工艺处理废纸制浆废水

为有效处理废纸制浆废水,采用氙灯照射下的光催化-Fenton技术,研究不同反应器、曝气、草酸钾、H2O2投加方式和废水质量浓度对光-Fenton工艺去除废水中TOC或吸光度的影响.结果表明,提高光照强度可提高TOC去除率;添加适量的草酸钾可提高处理效果;H2O2分两次投加可取得较好的处理效果,大大减少对催化剂的需求;在处理过程中使废水暴露于空气可提高有机物的脱氯效果,但曝气对处理效果并无益处.对于TOC为185 mg/L左右的废纸制浆废水,在[H2O2]=1000 mg/L、[Fe(Ⅱ)]=100 mg/L、pH=3.0、温度为30℃的条件下,经过30 min处理,废水的TOC可去除63%以上.     

用Fenton试剂-矿化垃圾生物反应器联合处理离子交换树脂再生废水

研究了Fenton试剂-矿化垃圾生物反应器联合处理离子交换树脂再生废水.研究结果表明：当原水CODCr为413 mg/L和过氧化氢投加量为24 mL/L（废水）时,经Fenton试剂预处理后,再经矿化垃圾生物反应器后续生化处理（运行周期为4 h,1 h进水,3 h落干,进水流量为600 mL/h）,出水CODCr降至85 mg/L左右,达到国家排放标准.     

混凝-Fenton氧化联合工艺处理有机废水的试验研究

利用多种方法联合处理是废水处理技术的发展方向,通过单因素实验确定了Fenton氧化和混凝处理高浓度有机废水的最佳参数,并进行了联合工艺处理该废水的实验。结果表明:采用Fenton-混凝联合工艺处理高浓度有机废水优于混凝-Fenton法,处理后苯酚含量、CODCr和浊度分别为45.2mg/L、818.2 mg/L和0.1 NTU,去除率分别为95.5%、60.1%和99.9%。