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排序方式: 共有657条查询结果,搜索用时 15 毫秒
1.
Zirconium(IV) tungstoiodophosphate has been synthesized under a variety of conditions. The most chemically and thermally stable
sample is prepared by adding a mixture of aqueous solutions of 0·5 mol L−1 sodium tungstate, potassium iodate and 1 mol L−1 orthophosphoric acid to aqueous solution of 0·1 mol L−1 zirconium(IV) oxychloride. Its ion exchange capacity for Na+ and K+ was found to be 2·20 and 2·35 meq g−1 dry exchanger, respectively. The material has been characterized on the basis of chemical composition, pH titration, Fourier
transform infrared spectroscopy (FTIR) and thermogravimetric analysis. The effect on the exchange capacity of drying the exchanger
at different temperatures has been studied. The analytical importance of the material has been established by quantitative
separation of Pb2+ from other metal ions. 相似文献
2.
The purpose of this study is to clarify damage process of “Type IV cracking” in weldment of a 2.25Cr-1Mo steel and to propose a micro damage prediction method. From continuous observation under a creep-fatigue test, it was found that spherical shape voids initiated and grew on grain boundaries in fine grain region and these voids grow continuously by changing their shape to crack-like. Both spherical and crack-like void growth rate equations were derived from the proposed void growth model. It was indicated that measured void growth rate under the creep-fatigue loading was well predicted by the growth rate equations. 相似文献
3.
Bastnasiteisamainsourceofrareearthproducts inwhichCeO2/REOisabout50%.Atpresent,a cidity leachingcombinedwithalkali conversion method[1]iscommonlyusedinthebastnasitetreat ment.Thismethodisunfriendlytotheenvironment becausetheradioactiveelementofthoriuman… 相似文献
4.
U(Ⅳ)-U(Ⅵ)同位素交换反应动力学研究 Ⅰ.Fe~(2+)对U(Ⅳ)-U(Ⅵ)同位素交换反应的催化作用 总被引:1,自引:0,他引:1
一、前言由于U(IV)-U(VI)同位素交换体系具有相当大的同位素效应和很好的稳定性,并且容易实现两相回流,这对于分离U同位素的工业应用都是十分有利的。但是,U(IV)-U(VI)同位素交换反应速度非常慢,常温下H~+浓度为1.0—4.0 mol/l时,速度常数为1.0×10~(-4)l~2/mol·s。因此要用U(IV)-U(VI)交换体系浓缩铀同位素,必须研究U(IV)-U(VI)交换反应动力学,找到加快交换反应的方法。 相似文献
5.
Daniel Westln 《Progress in Nuclear Energy》2007,49(8):597-605
Stockpiles of spent nuclear fuel and weapons material are growing worldwide. So far, the only long-term strategy seriously considered is geological repository for several hundred thousand years. Transmutation is an option significantly reducing the time during which repositories have to be sealed, simplifying the task of protecting future generations from the radioactive remnants of our civilisation. This paper gives an overview of motives and priorities, and describes the main technique suggested for transmutation of nuclear waste. 相似文献
6.
Chun Lin Ma Qing Feng Wang Rufen Zhang Jikun Li 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(2):229-235
Six triorganotin(IV) complexes of the type {(R3Sn)2[C3S3(COO)2]}n (R = C6H5 1; n-Bu 2; PhCH2 4; p-F-PhCH2 5; o-F-PhCH2 6) and {(R3Sn)2[C3S3(COO)2]}n·[EtOH] (R = Me 3) have been synthesized by the reaction of bis(carboxymethyl)trithiocarbonate with triorganotin(IV) chloride
in the presence of sodium ethoxide. All complexes were characterized by elemental analysis IR, 1H, 13C and 119Sn NMR spectroscopy. Except for 4–6, all complexes were also characterized by X-ray crystallography. The X-ray date revealed
that complexes 1–3 show two-dimensional network polymeric structure in which the geometries of tin atoms are trigonal bipyramid
with the axial positions occupied by carboxylic oxygen atoms. 相似文献
7.
This paper discusses the potential role of Generation IV nuclear energy systems in managing plutonium. It briefly reviews the Generation IV goals and their relevance to plutonium management. Each of the six selected Generation IV systems [very high temperature reactor (VHTR), gas-cooled fast reactor (GFR), sodium-cooled fast reactor (SFR), super-critical-water-cooled reactor (SCWR), lead-cooled fast reactor (LFR), molten salt reactor (MSR)] is briefly discussed. The main characteristics of each system are summarised and the capability for plutonium management indicated. The potential for the management of plutonium using Generation IV systems is briefly reviewed from a complete fuel cycle perspective to illustrate the issues in the context of a fleet of reactor and fuel cycle facilities. 相似文献
8.
混合溶剂对Ru(Ⅳ)萃取的研究 总被引:2,自引:0,他引:2
一、前言 在一定浓度盐酸介质中,Ru(Ⅳ)以RuCl_6~(2-)络阴离子状态存在,可被C类溶剂TOA(三辛胺)以离子缔合机制定量地萃入有机相。由实验得到在相同条件下,TOA对Ru(Ⅳ)的萃取率随稀释剂介电常数的增加而下降。 相似文献
9.
本文就碳酸饮料瓶用聚酯瓶坯生产过程的三个环节中,因注塑工艺与设备影响所产生的粘度降提出解决方法。 相似文献
10.
《International journal of human-computer studies》2014,72(3):284-297
Analysis of the usability of an interactive system requires both an understanding of how the system is to be used and a means of assessing the system against that understanding. Such analytic assessments are particularly important in safety-critical systems as latent vulnerabilities may exist which have negative consequences only in certain circumstances. Many existing approaches to assessment use tasks or scenarios to provide explicit representation of their understanding of use. These normative user behaviours have the advantage that they clarify assumptions about how the system will be used but have the disadvantage that they may exclude many plausible deviations from these norms. Assessments of how a design fails to support these user behaviours can be a matter of judgement based on individual experience rather than evidence. We present a systematic formal method for analysing interactive systems that is based on constraints rather than prescribed behaviour. These constraints capture precise assumptions about what information resources are used to perform action. These resources may either reside in the system itself or be external to the system. The approach is applied to two different medical device designs, comparing two infusion pumps currently in common use in hospitals. Comparison of the two devices is based on these resource assumptions to assess consistency of interaction within the design of each device. 相似文献