Phase composition,microstructure, and properties of Al4O4C–(Al2OC)1-x(AlN)x –Zr2Al3C4–Al2O3 refractories prepared at high temperatures in nitrogen

The novel Al₄O₄C–(Al₂OC)_1-x(AlN)_x–Zr₂Al₃C₄–Al₂O₃ refractories with ultra-low carbon content have been successfully prepared by constructing the core-shell structure of aluminum at 1300–1700°C in nitrogen. The phase composition, microstructure, and properties of the novel refractories are deeply investigated. The cracking temperature on the core-shell structure of aluminum is further explored and the reaction mechanism of Zr₂Al₃C₄ has also added explanation. The results show that the novel refractories have excellent physical properties and cannot be corroded by molten iron. There exist two different Al₂OC solid solutions in the novel refractories, Al₂OC-rich (Al₂OC)_1-x(AlN)_x and AlN-rich (Al₂OC)_1-x(AlN)_x. The temperatures affect their relative content. When temperatures are less than 1600°C, the relative content of Al₂OC-rich (Al₂OC)_1-x(AlN)_x is more than that of AlN-rich (Al₂OC)_1-x(AlN)_x. When temperatures are above 1700°C, the relative content of AlN-rich (Al₂OC)_1-x(AlN)_x is more than that of Al₂OC-rich (Al₂OC)_1-x(AlN)_x. The core-shell structure of aluminum fully ruptures at about 1200°C. Zr₂Al₃C₄ begins to form at about 1000°C and generates in large at 1200°C.     

The effect of particle size distribution on the microstructure and properties of Al2O3 ceramics formed by stereolithography

Stereolithography (SL) shows advantages for preparing alumina-based ceramics with complex structures. The effects of the particle size distribution, which strongly influence the sintering properties in ceramic SL, have not been systematically explored until now. Herein, the influence of the particle size distribution on SL-manufactured alumina ceramics was investigated, including bending strength at room temperature, post-sintering shrinkage, porosity, and microstructural morphology. Seven particle size distributions of alumina ceramics were studied (in μm/μm: 30/5, 20/3, 10/2, 5/2, 5/0.8, 3/0.5, and 2/0.3); a coarse:fine particle ratio of 6:4 was maintained. At the same sintering temperature, the degree of sintering was greater for finer particle sizes. The particle size distribution had a larger influence on flexural strength, porosity and shrinkage than sintering temperature when the particle size distribution difference reached 10-fold but was weaker for 10 μm/2 μm, 5 μm/2 μm and 5 μm/0.8 μm. The sintering shrinkage characteristics of cuboid samples with different particle sizes were studied. The use of coarse particles influenced the accuracy of small-scale samples. When the particle size was comparable to the sample width, such as 30 μm/5 μm and 5 mm, the width shrinkage was consistent with the height shrinkage. When the particle size was much smaller than the sample width, such as 2 μm/0.3 μm and 5 mm, the width shrinkage was consistent with the length shrinkage. The results of this study provide meaningful guidance for future research on applications of SL and precise control of alumina ceramics through particle gradation.     

阴,阳离子聚合物地层内凝胶化改善水驱效果的研究

研究了一杆阴离子聚合物（Ａｃ５３０）和一种阳离子聚合物（Ｍｂ５８１）在水溶液中形成凝胶的条件和过程、凝胶化学结构、形态、稳定性和力学性能。在模拟地层的二维微观模型内观测了两种聚合物驱替渗流、相逼、形成凝胶、凝胶封堵大孔道的机理。在亲水填砂模型内测定了阴、阳离子聚合物凝胶体系降低渗透率的能力。     

Distribution of properties from sampling inhomogeneous materials by line transects

A theory related to the statistics of the structure and properties of inhomogeneous materials has been proposed, dealing with the distribution of properties from sampling of inhomogeneous structures by line transects. It is demonstrated that the empirical cumulative distribution functions of the intercepts from the microstructural constituents and their variances are important fingerprints of the inhomogeneous structures.Simulated sampling of the images of the microstructure by line transects has been proposed as a powerful method for characterization the distribution of properties of inhomogeneous structures. One of the advantages of the method based on the expected values of the order statistics of the intercepts is that the probability bounds of the property are determined without prior knowledge of the functional relationship between the property and the intercepts from the structural constituents.The concept intercept variance has an important application in determining the minimum transect length that stabilizes the variation of the intercept at a low value. Additionally, the concept ‘intercept variance’ can be used for topological optimization of the microstructure regarding the risk of intercepting a large amount of the weaker constituent. Equations regarding the variance of the intercepted fraction characterizing transect lengths with a specified distribution have also been derived.     

试论融资租赁项下的进口贸易

阐述了当前跨国公司在合同中普遍采用的融资租赁的性质及融资租赁项下的进口贸易特点。     

废槽衬的性能研究

研究了废槽衬的外观形貌、微观结构、物相组成、元素含量,并对寿命相同的两种典型废槽衬的性能进行了对比分析,为选择废槽衬的无害化处理工艺提供了基础数据。     

在（311）面上所生长的Al_xGa_（1－x）As／GaAs单量子阱特性

文章报道了用分子束外延（ＭＢＥ）法在６００℃和６５０℃下，在Ｓｉ掺杂的ＧａＡｓ衬底的（３１１）Ａ和（３１１）Ｂ面上成功地生长了高质量的ＡｌｘＧａ１－Ａｓ／ＧａＡｓ单量子阱材料。计算了光荧光（ＰＬ）峰值能量，并与实验作了比较。讨论了（３１１）Ａ和（３１１）Ｂ面上的不同生长特性。     

Study on high-strength composite portland cement with a larger amount of industrial wastes

It is one of important measures for the sustainable development of cement industry to utilize industrial wastes. High-strength composite portland cement with a large amount of granulated blast furnace slag (GBFS), fly ash and limestone was prepared by separate grinding method, optimizing gypsum and using activators. The total amounts of blending materials are between 45% and 65% and the strength grades of cements reach 525 or even 625 according to Chinese national standard for composite portland cement. Besides setting time and strength, the hydration heat, drying shrinkage and sulfate resistance were also determined.     

钙钛矿型钛酸锶的制备、结构与性能

钛酸锶是一种具有重要电性质的陶瓷材料 ,因而在工业上得到了广泛的应用。本文介绍了钛酸锶的几种常见的合成方法 ,并简要的介绍了钛酸锶的结构与性能     

填充料细度对水工沥青混凝土性能的影响

近年来沥青混凝土作为防渗材料，在我国水工建筑中得到了广泛应用。与道路工程的沥青混凝土不同的是，水工沥青混凝土具有良好的粘弹性及抗渗性。目前，国家规范对填充料的细度尚无明确规定，通过调整沥青混凝土的填充料细工，对沥青混凝土的各项性能进行了系统的试验和分析，研究表明：适宜的填充料细度及掺量，能有效地改善沥青混凝土性能，提高其抗渗性。