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1.
The visible light driven Bi2MoO6 photocatalyst doped with different contents of Ag nanoparticles was successfully synthesized by a combination of hydrothermal and sonochemical methods. The as-synthesized samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning and transmission electron microscopy (SEM and TEM) and UV–visible spectroscopy to investigate crystalline structure, morphology, composition and photocatalytic properties. XRD patterns and TEM images of the samples revealed pure phase orthorhombic Bi2MoO6 nanoplates without any detection of Ag dopant due to its low concentration and very tiny particle size. TEM images showed that Ag nanoparticles with the size of 10–15 nm were dispersed randomly on the surface of Bi2MoO6. The XPS analysis of Ag/Bi2MoO6 nanocomposites revealed the presence of additional metallic Ag. Photocatalytic activities of the Ag/Bi2MoO6 nanocomposites were evaluated by determining the degradation of rhodamine B (RhB) under visible light radiation. In this research, the 10 wt% Ag/Bi2MoO6 nanocomposites showed the best photocatalytic activity. The results suggest that the dispersion of Ag nanoparticles on the surface of Bi2MoO6 significantly enhances its photocatalytic activity. 相似文献
2.
3.
本文根据碳氧比测井技术的发展现状,提出5个值得讨论的问题,并较详细地阐述了对这些问题的看法。这5个问题是:碳氧比测井的地质—物理基础、总门本底谱、数字与模拟量传输技术、对仪器幅度稳定性的要求和仪器屏蔽系统设计。 相似文献
4.
S. A. Halsey 《Journal of the Institute of Brewing》1985,91(5):306-312
Both transmission and transflectance near infrared spectroscopy have been evaluated for the rapid analysis of beer components. Results of sufficient accuracy have been obtained for ethanol content and Original Gravity. Application of a first derivative mathematical treatment on the spectral data improved calibration equations. Better accuracy was achieved using the transmission mode compared to that using the transflectance mode. 相似文献
5.
SurfaceChemistryandCatalysisofRareEarthOxidesI.A StudyoftheReactivityofSurfaceHydroxylsonCeO_2andPr_6O_(11)byFT-IRSpectroscopy... 相似文献
6.
J. Sieber D. Broton C. Fales S. Leigh B. MacDonald A. Marlow S. Nettles J. Yen 《Cement and Concrete Research》2002,32(12):1899-1906
The eight portland cements and two calcium aluminate cements in the Standard Reference Material (SRM) 1880 series are among the most popular SRMs in the catalog of the National Institute of Standards and Technology (NIST) Standard Reference Materials Program. Numerous laboratories rely on them for elemental analysis and qualification for ASTM C 114-00 Standard Test Methods for Chemical Analysis of Hydraulic Cement. NIST has collected new candidate materials from around the world and partnered with Construction Technology Laboratories (CTL) in their preparation and certification. This paper describes the procedures taken at NIST and CTL to prepare and test materials for certification including the homogeneity testing, the X-ray fluorescence methods and the statistical data analysis performed for value assignment. 相似文献
7.
To synthesize diamond films by microwave plasma enhanced chemical vapor deposition (MPECVD), the methane concentration (CH4/H2)plays a crucial role. It is well-known that there always exists a critical methane concentration (≤0.6%) only below which
a good quality diamond film can be obtained. In this study, however, the phenomena of diamond synthesis resulting from high
carbon concentration conditions were observed. The molten metals, e.g., Ag, Cu, were used as the deposition substrates on
which crystalline diamonds can be achieved from a methane content of CH4/H2≥6% or even from solid carbon sources. These results suggest that there may exist a low methane content boundary layer (<0.6%)
in the proximity of molten metal surface on which suitable species, CH, CH+, Hα and Hβ are composed for the diamond nucleation and growth similar to the condition as in the conventional low methane contents.
The molten metal inclines to dissolve other forms of carbonaceous materials other than diamond, and thus keeps a much higher
steady supply of carbon atoms that enhances the quality as well as the growth rate of the forming diamonds.
Received: 23 June 2001 / Accepted: 23 July 2001 相似文献
8.
Franz Schauer 《Solar Energy Materials & Solar Cells》2005,87(1-4):235
Basic suppositions and microphysical origin of the occurrence of the space-charge-limited currents (SCLC) are presented in general and for the temperature-modulated space-charge-limited currents (TM-SCLC) in particular. The criteria are given for the spectroscopical method TM-SCLC to be used for localized electron states elucidation in organic semiconducting materials for organic solar cells optimization and modelling. The “visibility “of the localized states by SCLC method, i.e. the power of the SCLC method to distinguish the localized states, is tested by the modelling, varying the temperature, energy position of localized states and their concentration. Generally, it was determined that the SCLC measurements results are more reliable with the increased energy of the states, with their increased concentration and with decreased temperature. The correlation (or its absence) between the measured current and activation energy on applied voltage, expressed by the dependence of preexponential factor of conductivity on activation energy (Meyer–Neldel rule), gives the possibility to determine the energy range where the reconstruction of density of localized states function is reliable. 相似文献
9.
FTIR spectra of CO adsorbed on Pt/KL catalysts show that the relative band intensities and the total dispersion markedly depend on the catalyst preparation method (ion exchange, incipient wetness impregnation or co-impregnation with KCl). The CO stretching frequency of the dominant band for linear CO is shifted to higher wavenumbers, parallel with the proton concentration in the reduced catalyst, which is derived independently from the intensity of the IR bands of the OH groups. The results are in accordance with the model that electron-deficient platinum particles are platinum-proton adducts.On leave from: N.D. Zelinsky Institute of Organic Chemistry, Academy of Sciences, Moscow, USSR. 相似文献
10.
40Cr钢试样经不同热处理后在空气中用CO2连续激光束进行辐照,以穆斯堡尔谱学研究试样在辐照后的组织结构变化。试验结果表明,调质预处理后再进行激光辐照的试样,不仅残作产奥氏体含量较低,而且其中碳的含量最低。 相似文献