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1.
《Advanced Powder Technology》2020,31(10):4187-4196
Manganese oxide catalysts have been synthesized from the used batteries via hydrometallurgical method and effect of hydrometallurgical parameters such as the effect of acid type (H2SO4, HNO3, HCl), acid concentration (0.5, 1, 1.5, 2 %v/v) and powder to acid ratio (1/50, 1/60, 1/70, 1/80) were in detail investigated. The physico-chemical properties of as-prepared catalysts were characterized by FT-IR, XRD, FESEM, EDX, BET, TEM, and TPR-H2 analysis. The activity of as-prepared catalysts were investigated towards the oxidation of benzene, toluene, and xylene (BTX) in a plasma-catalytic process. The results show that benzene and toluene conversion were almost constant in the range of 97–98% in case of various acid types, acid concentrations and solid to liquid ratios. However, the xylene conversion were varied in case of different hydrometallurgical factors. The highest xylene conversion was obtained in the presence of MnS0.5–60, which was prepared using H2SO4 with concentration of 0.5%v/v and solid to liquid ratio of 1/60. The effect of the input voltage and BTX flow rate on the BTX conversion was also investigated using MnS0.5–60 catalyst in detail.  相似文献   
2.
Activated-carbon-fiber cloth (ACFC) is an alternative adsorbent to granular activated carbon (GAC) for removing and recovering organic vapors from gas streams. Electrothermal desorption (ED) of ACFC provides rapid regeneration while requiring less energy compared to traditional regeneration techniques used with GAC. This paper provides proof-of-concept results from a bench-scale ACFC adsorption system. The automated system captured 1,000 ppmv of hazardous air pollutants/volatile organic compounds (HAPs/VOCs) from air streams and demonstrated the use of ED, using ac voltage, to recover the HAP/VOC as a pure liquid. The desorbed HAP/VOC condensed onto the inner walls of the adsorber and was collected at the bottom of the vessel, without the use of ancillary cooling. Seventy percent of the HAP/VOC was collected per cycle as condensate, with the balance being retained in the regenerated adsorber or recycled to the second adsorber. ED with in-vessel condensation results in minimal N2 consumption and short regeneration cycle times allowing the process to be cost competitive with conventional GAC-based adsorption processes. This technology extends the application of carbon adsorption systems to situations that were previously economically and physically impractical.  相似文献   
3.
减压渣油与FCC油浆共炭化的化学组成变化   总被引:6,自引:2,他引:4  
考察了齐鲁石化胜利炼油厂催化油浆(FCC)和胜利减压渣油(VR)在490℃,0.8MPa下不同混合比的原料和不同反应时间的中间产物的HS、TS、PS、P及其1h中间产物的HS和TS的^1H-NMR。数据结果反映了体系的反应速度。掺入FCC油浆抑制了VR的反应活性,降低了体系的反应速度,增加了基质的溶解度;1h中间产物的组成结构更接近于原料及反应体系的反应性和基质的溶解度;1h中间产物的芳香度越高,取代基越少,侧链越短,基质对VR中的活性反应组分在炭化早期生成的高度缩合物质的溶解度越大。  相似文献   
4.
布里奇曼法生长碲镉汞晶体的固液界面形态研究   总被引:2,自引:0,他引:2  
文中综述了布里奇曼法及加速坩埚旋转技术的布里奇曼法生工碲镉汞晶体过程中固液界面形态的研究结果,简单讨论了固液界面形态对组分分布的影响,并将两种技术所得的组分分布结果进行了比较,在分析影响固液界面形态因素的基础上,认为加速坩埚旋转技术是目前改善固液界面形态的有效方法。  相似文献   
5.
低熔封接玻璃组成及其发展   总被引:25,自引:2,他引:23  
白进伟 《材料导报》2002,16(12):43-46
综述了低熔封接玻璃的组成特点,给出了大量低熔玻璃组成实例,批出了低熔封接玻璃的封接低温化和无铅化发展方向,磷酸盐玻璃是首选组成之一。新的制备工艺和新的玻璃形成体系将对封接玻璃发展起着十分重要的作用。  相似文献   
6.
生物降解气态有机污染物的研究是近年来发展起来的大气污染控制新领域。通过介绍生物降解气态有机污染物的基本原理,探讨石油储运过程中的蒸发油气污染运用生物控制技术的可行性,提出需要解决的问题和研究的重点。  相似文献   
7.
The effects of ion implantation and subsequent annealing on the microstructure of molybdenum have been investigated by transmission electron microscopy. The ions investigated were carbon, nitrogen, and tellurium. The ion-induced damage was found to give rise to grain boundary migration phenomena both during implantation and during subsequent annealing. Precipitation or ordering was found to occur for each ion on annealing.  相似文献   
8.
Ten commercial Cheddar cheeses of variable quality differing in fat content and age were subjected to compositional, proteolytic, lipolytic and sensory analyses. The compositional parameters of the full-fat cheeses were predominantly outside those typically associated with good-quality cheese. Sensory analysis discriminated the full-fat cheeses predominantly by age, with the longer ripened cheeses associated with more negative attributes, some which appeared to be due to excessive lipolysis and/or β-casein breakdown. Both proteolysis and lipolysis appear to be age dependent. The two reduced-fat cheeses were clearly discriminated from the eight full-fat cheeses by sensory analysis that appeared to be due to differences in composition and the extent of lipolysis.  相似文献   
9.
Consumers demand organic products because they believe that the organic products are more flavorful and respectful to the environment and human health. The effects of organic farming on the minerals contents and aroma composition of Clemenules mandarin juices were studied. Minerals (Fe, Cu, Mn, Zn, Ca, Mg, K, and Na) were quantified using atomic absorption-emission spectroscopy, while volatile compounds were extracted using the dynamic headspace technique and were identified and quantified by GC–MS. In general, organic farming produced a mandarin juice with a higher quality than that produced by conventional agricultural practices. Higher concentrations of both minerals and positive volatile compounds were found in the organic juice, while the formation of off-flavors was higher in the conventional juice, although threshold values were not reached.  相似文献   
10.
In this introduction to a special issue of Computers and Composition, the authors critically review current literature on computer-assisted writing pedagogies that grapple with issues of sexuality. Although this body of work is small, it points to provocative ways to develop our students’ critical and rhetorical sensibilities about the constructions of sexuality in our culture. Further, such work innovatively addresses the place of networked communication technologies in the interrogation of such constructions. The authors conclude with both an introduction of the work in this special issue that addresses the intersection of sexuality studies and computer-assisted writing studies and with a call for additional work in this field.  相似文献   
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