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排序方式: 共有2198条查询结果,搜索用时 0 毫秒
1.
Hyun-Goo Kim Wha-Nam Myung K. Sumiyama K. Suzuki 《Journal of Alloys and Compounds》2002,340(1-2):270-274
We report upon the chemical leaching and magnetic properties of nanoscale crystalline Al0.6(Co25Cu75)0.4 alloy powders produced by rod milling. X-Ray diffractometry (XRD), transmission electron microscopy, differential scanning calorimetry, vibrating sample magnetometry, and superconducting quantum interference device magnetometry were used to characterize the as-milled and leached specimens. After 400 h of milling, only the b.c.c. phase of the intermetallic compound γ-Al3.892Cu6.10808 was detected by XRD. After annealing the leached specimen at 600 °C for 1 h, the nanoscale crystalline phase was transformed into the f.c.c. Cu phase, and this was accompanied by a change in the magnetic properties. The peaks of the magnetization shifted towards lower temperature with increasing external field. The temperature behavior at Tf (45 K) for direct current (d.c.) magnetic susceptibility measurements was quite different for field cooling and zero-field cooling. After cooling the leached specimen from 800 °C, magnetization increased gradually. 相似文献
2.
Andrés Rigail-Cedeño 《Polymer》2005,46(22):9378-9384
Cure reactions of the stoichiometric mixtures of diglycidyl ether of bisphenol A (DGEBA) and two very low molecular weight aliphatic polyether diamines (PED) were studied by using fluorescence and mid- and near-IR spectroscopic techniques. As the cure proceeded, the primary amine groups in PED are converted to the secondary and the tertiary amines. Near-IR spectral analysis was used to calculate the concentration of the three amine groups as a function of cure time. The decrease in the fluorescence intensity of DGEBA at about 307 nm was observed due to more effective quenching of the tertiary amine groups in PED, in comparison to the primary and the secondary amine groups. A large decrease in fluorescence intensity at 75 and 95 °C cure was observed. The amount of all the amine species was estimated from NIR spectra to shed light on the cure kinetics of PPO (polypropylene oxide) in comparison with PEO (polyethylene oxide) epoxy, as well as to explain their fluorescence behavior.The fluorescence intensity changes were correlated to the extent of epoxy reaction obtained by mid- and near-IR spectroscopy. 相似文献
3.
Vjacheslav V. Zuev 《Journal of Polymer Research》2008,15(5):351-356
Functionalized polyanilines containing biphenyl, terphenyl, carbazole, anthracene, and 4-n-hexylphenyl moieties were synthesized though the reaction of polyaniline in emeraldine base form with sodium salt of corresponding
vinylketoaromatics with quantitative yields. Polymers were characterized with Fourier transform infrared spectroscopy, proton
nuclear magnetic resonance spectroscopy, and thermogravimetry. The emission characteristics of these polymers in N-methyl-2-pyrrolidone solution were examined. The functionalized polyanilines exhibited an intense green emission. 相似文献
4.
Interfacial hybridization kinetics of oligonucleotides immobilized onto fused silica surfaces 总被引:3,自引:0,他引:3
Jiang Zeng Amer Almadidy James Watterson Ulrich J. Krull 《Sensors and actuators. B, Chemical》2003,90(1-3):68-75
Fused silica optical fibers have been used in an intrinsic mode optical configuration as biosensors for fluorescence based detection of hybridization of nucleic acids. In this work, the kinetics of hybridization of single-stranded oligonucleotides that were covalently immobilized were studied. The probe DNA was dT20, and the target was Fluorescein-labeled non-complementary (dT20) or complementary (dA20) oligonucleotide. Chronofluorimetric monitoring of the adsorption and hybridization processes was used to investigate oligonucleotide films of different density, in different salt concentrations, at temperatures of 25 and 40 °C, with the concentration of the target DNA being 0.005–0.1 μM. Mathematical models based on first- and second-order Langmuir adsorption have been examined to describe both the adsorption and the hybridization processes. Experimental data were processed using the models, and the hybridization kinetics were calculated. Hybridization kinetics on these optical fiber DNA sensors was found to be up to three orders faster than results presented for a number of other experiments using different immobilization chemistries. 相似文献
5.
PMMA/PBA乳胶IPN阻尼材料的研究 总被引:3,自引:0,他引:3
用乳液聚合方法合成了一系列的互穿聚合物网络,其中包括:PMMA/PBA和P(MMA-co-PMA)/PBA乳胶互穿聚合物网络(LIPN),PMMA/PBA乳胶双向互穿聚合物网络(LBIPN)以及PMMA/PBA界面交联互穿聚合物网络(ICLIPN)。动态力学谱和拉伸试验结果表明:(1)PMMA/PBA互穿聚合物网络的两组分相容性和阻尼性能可通过MMA和PMA共聚来改善;(2)双向互穿技术是一种行之 相似文献
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8.
Jeong-Woo Choi Jun Hyo Park Shin Chul Lee Dong-Il Kim Won Hong Lee 《Korean Journal of Chemical Engineering》1995,12(5):528-534
The on-line sensing of viable cell weight in plant cell culture process is applied to analysis and control of process. The
fiber-optic fluorescence sensor was constructed to measure the NADH-dependent fluorescence inNicotiana tabacum plant cell culture and the analysis of fluorescence signal was done to be correlated with the viable cell weight. The structured
kinetic model for cell growth was proposed to estimate the theoretical viable cell weight. The dimensional analysis was proposed
for the interpretation of fluorescence signal, in which the path length, the inner filter effect and the hydrodynamic conditions
were considered as the key factors on fluorescence signal. The dimensional analysis and empirical correlation of fluorescence
signal to viable cell weight was applied to the interpretation of the detected fluorescence signal during cultivation. The
proposed interpretation of fluorescence signal using dimensional analysis was well correlated with the viable cell weight
estimated by the structured kinetic model as well as by empirical correlation. 相似文献
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