Se doped nickel-molybdenum bimetal sulfide with enhanced electrochemical activity for hydrogen evolution reaction

In this work, we synthesized Se doped MoS₂@Ni₃S₂ with nanosheets coated nanorods structure supported on Ni foam (MoNiSeS). Firstly, MoS₂@Ni₃S₂ (MoNiS) nanorods was synthesized by hydrothermal method. After selenization treatment, MoSe₂ successfully formed on the edge of MoS₂ nanosheets and particle Ni₃S₂ transformed into NiSe, in which MoSe₂ and NiSe acted as new phase in MoNiSeS. The obtained MoNiSeS only needs a low overpotential of 68 mV to reach the current density of 10 mA cm^?2, and has a low Tafel plots of 72.77 mV dec^?1 and good electrochemical durability, whose electrochemical activity is much better than that of MoNiS and NiSeS, implying the introduction of Mo and Se is beneficial to improve the electrocatalytic performance of NiS for HER. In addition, the proper amount of Mo source, which has an effect on the morphology of product, has also been investigated. For MoNiSeS, the typical nanosheets coated nanarods expose more active sites and the synergic effects is good to the improvement of the catalytic activity. Meanwhile, WNiSeS has also been prepared using the same method and the corresponding results show that the electrochemical activity of WNiSeS is much better than that of NiSeS, proving the universality of this strategy.     

Fe3O4/PSt/TiO2多层包覆电磁响应微球的制备

首先采用分散聚合法将自制的Fe3O4磁流体和苯乙烯反应合成有磁核的Fe3O4/PSt磁性聚合物微球，然后，用非均匀成核水解反应在Fe3O4/PSt微球外包覆无定形二氧化钛，获得Fe3O4/PSt/TiO2复合微粒。用红外光谱、扫描电镜和热分析对粒子的形貌和结构进行了表征。并测试了微粒的介电性能和磁性，结果表明，所制得复合微粒有良好的电、磁响应性。     

生物包粒的分类与命名——兼论徐州大北望中下寒武统生物包粒特征

对于碳酸盐岩中由生物及生物化学作用形成的具有同心或放射结构的异化颗粒(生物包粒),已为人们所熟悉,但目前还没有统一的分类与命名。本文在研究徐州大北望中下寒武统生物包粒特征的基础上,结合已有研究成果,对由生物及生物化学作用形成的具有同心或放射状内部结构的碳酸盐颗粒,按其粒度和形成颗粒的生物类型不同进行分类命名,提出分类命名的原则。     

Processing of Yttria-Alumina Coated Silicon Nitride Slips by Slip Casting

Si₃N₄powders coated with 6 wt% Y₂O₃and 4 wt% Al₂O₃were prepared by coprecipitation. The resulting powders were dispersed in water at different pH values and with addition of various amounts of ammonium polyacrylate (NH₄PA) to produce 32 vol% slips. The influence of the amount of NH₄PA solution added and pH on the rheological properties of 32 vol% coated Si₃N₄slips were studied. In addition, the sintered density of cast samples was determined and related to the degree of slip dispersion. The adsorption of the NH₄PA on the coated particle surface was rather high and the surface became saturated near 0.86 mg/m²at pH 9.2. High NH₄PA concentrations (1.7–3 wt%) were necessary to obtain well dispersed 32 vol% coated Si₃N₄slips at pH 9.2. The best stabilization was obtained with the addition of 2.3 wt% NH₄PA; in this condition, the viscosity reached a minimum value of 35 mPa.s at 100 s^–1. The slip viscosity increased with increasing pH from 9.2 to 10.2. Slips with low viscosities gave a more dense packing of cast samples and consequently higher sintered density values.     

绿色再生混凝土利用途径与评定思路

就再生混凝土骨料进行深入系统的研究 ,建立了一套与现行评价天然骨料标准相一致的评定方法 ,具有工程实际意义 ,为将来实际应用作好了基础理论研究     

羟基磷灰石涂层人工关节的应用研究

采用人工合成高纯度的羟基磷灰石粉末，喷涂在具有注册证的钛合金和钴铬钼合金人工关节上。通过生物学基础检测、动物实验和临床试用，证明所制作的各种羟基磷灰石涂层人工关节，能诱发骨质生长，起生物固定作用，对治疗丧失功能的骨胳效果甚佳。     

蒸汽凝结水除油试验研究

介绍了利用类萃取技术进行蒸汽凝结水除油的过程。利用具有亲油功能的HOL-100树脂,经过试验和工业应用证明,萃取除油可以达到1．0mg/L以下,可满足炼油化工装置锅炉用水对含油量的要求。HOL-100树脂具有在高温状态下(120℃)除油的特点。通过标定考核,萃取除油技术是一项节能、节水、环保措施,可在中石油和中石化企业推广应用。     

应用焊道长度控制线能量

运用ＨｅｒｂｓｔＦＷ公式原理对国产碱性条件进行了大量试验，建立了焊接线能量（Ｅ），焊条熔化长度（ｌＥ），焊道长度（ｌＲ）的关系式：Ｅ＝８０８Ｄ１．８ｌＥ／ｌＲ。并应用线算图和ＳＨ－ＣＣＴ图对该式施焊结果验证，热影响区的金相组织，硬度基本一致。因此，可以应用焊道长度校核与控制线能量。     

硬脂酸复合薄膜光波导传感器检测苯乙烯

利用旋转甩涂法将亚甲基蓝(MB)掺杂的硬脂酸复合薄膜固定在钾离子(K+)交换玻璃光波导表面,研制了MB-硬脂酸复合薄膜/K+交换玻璃光波导传感器,并对挥发性有机物蒸气进行检测。实验结果表明,在室温下该传感器对低浓度的苯乙烯蒸气具有较好的重复性和选择性响应,能够检测到1×10-7(体积分数)的苯乙烯蒸气,其响应和恢复时间分别为12s和28s。该传感器具有灵敏度高、响应-恢复速度快、可逆性好、成本低、容易制作等特点。     

再生砖混骨料混凝土柱的小偏心受压性能

通过小偏心受压性能试验对比研究3根的天然骨料混凝土柱和3根同强度全再生砖混骨料混凝土柱,强度分别为C25、C30和C35. 对6根柱进行加载试验,分析再生砖混骨料混凝土柱相比于同强度天然骨料混凝土柱在受力过程、破坏特征、变形能力与承载力等方面的差异. 试验发现,再生砖混骨料混凝土柱在小偏心加载至破坏的过程中,具有与天然骨料混凝土柱相似的3个受力阶段,且符合平截面假定. 与同强度的天然骨料混凝土柱相比,变形较大,但再生砖混骨料混凝土柱的极限承载力略高,原因可能在于两者轴心抗压强度的差异.