Phosphorus Inputs to Lake Simcoe from 1990 to 2003: Declines in Tributary Loads and Observations on Lake Water Quality

Total phosphorus (TP) inputs to Lake Simcoe have led to hypolimnetic dissolved oxygen (DO) depletion and loss of cold water fish habitat. Since 1990, efforts have been made to reduce the total TP input to the lake below a defined target of 75 t/year, which was predicted to lead to reductions in spring TP concentration and improvements in end-of-summer hypolimnetic DO concentrations. The total TP load to the lake during the most recent period of record (1998/99-2003/04) ranged from 53 to 76 t/yr and averaged 67 t/yr, compared to an average of 114 t/yr estimated between 1990/91 and 1997/98 (range 85-157 t/yr). Reductions in TP loads from the catchment via tributary discharge (∼26 t) accounted for the majority of the decrease in total load between the two time periods. Total P concentrations decreased significantly in four out of six long-term monitored tributaries; however, concentrations in all six tributaries remain above the level recommended to avoid nuisance plant growth (30 μg/L). Although TP loads to the lake are currently below the target 75 t/yr, excessive growths of filamentous algae and macrophytes continue to be a problem in the nearshore zone. End-of-summer minimum hypolimnetic DO concentrations (average 4.3 mg/L, 1998/99-2003/04) remain substantially below the level (7 mg/L) that is considered protective of lake trout. Efforts to reduce TP loads to the lake therefore need to continue.     

Variations in Spectral Slope in Lake Taihu,a Large Subtropical Shallow Lake in China

Spectral slope (S), describing the exponential decrease of the absorption spectrum over a given wavelength range, is an important parameter in the study of of chromophoric dissolved organic matter (CDOM) dynamics, and also an essential input parameter in remote sensing models. Furthermore, S is often used as a proxy for CDOM composition, including the ratio of fulvic to humic acids and molecular weight. The relative broad range in S values reported in the literature can be explained by the different spectral ranges and fitting methods used. A single exponential model is used to fit the S values for 17 investigations involving 458 samples in Lake Taihu from January to October in 2004. The average S value was 15.18 ± 1.39 μm⁻¹ for the range of 280–500 nm, which fell within the range reported in the literature. The frequency distribution of S value basically obeyed a normal distribution. Significant differences in S values between summer and other seasons showed that phytoplankton degradation was one of the important sources of CDOM in summer, whereas CDOM mainly came from the river input in other seasons. Furthermore, the estimated S value decreased with increasing wavelength range used in regression. The maximum and minimum values derived from the regression were 17.89 ± 1.25 μm⁻¹ and 13.62 ± 2.11 μm⁻¹ for the wavelength ranges of 280–380 nm and 400–500 nm, respectively, a decrease of 23.9%. S values significantly decreased with the increase of CDOM absorption coefficients. CDOM absorption coefficients could be more appropriately estimated from exponential model introducing the variation of S with absorption coefficients, making them useful for a remote sensing bio-optical model of Lake Taihu. DOC-specific absorption coefficient a*(λ) and the parameter M describing molecular size of the humic molecules could also be used as a proxy for the sources and types of CDOM. A general relationship was found between S and a*(λ), and M values. S increased with the decrease of DOC-specific absorption coefficient and the increase of M corresponding to the decrease of molecular weight.     

信息融合技术在变压器油气识别故障诊断中的研究

变压器故障分为放电性故障和过热性故障两大类别,它们均会在变压器油中有所反映。本文通过对变压器油中主要气体的分析,判断变压器的故障类型。具体方法是:利用改进算法的BP网络和信息融合技术,以变压器油中五种主要特征气体作为神经网络的输入,以六种变压器状态作为相应的输出,通过加入动量因子,可以提高学习率系数,充分发挥改进算法的BP网络具有自适应学习能力的优势。仿真测试结果表明,本方法能够在较大范围内准确有效地进行变压器的故障诊断。     

炼厂外排污水回用于循环冷却水腐蚀影响因素初探

从单因素、多因素和复杂水系考察了炼厂外排污水回用于循环冷却水腐蚀的影响因素，结果表明，碳钢腐蚀的主要影响因素取决于离子特性、氧化膜的形成和溶解氧的扩散等综合协同作用，其中以离子特性的,影响为最大（如：Cl^-、Ca^2 、CO3^2-的腐蚀性较强）。碳钢腐蚀反应又可由以上三种主要影响因素分为三个反应控制区，而当电导率在0．1－2．0mS/cm范围时，其水质属于腐蚀危险高发区。从而也进一步说明水质的低电导率处理，其防腐效果并不理想，相反在高电导率情况下却表现出相对较好的低腐蚀性能。     

Variability of light absorption properties in optically complex inland waters of Lake Chaohu,China

Absorption coefficients of phytoplankton, colored detrital matter (CDM), non-algal particles (NAP), colored dissolved organic matter (CDOM), and their relative contributions to total non-water absorption (a_t ? w) are essential variables for bio-optical and radiative transfer models. Light absorption properties showed large range and variability sampled at 194 stations throughout Lake Chaohu between May 2013 and April 2015. The a_t ? w was dominated by phytoplankton absorption (a_ph) and NAP absorption (a_d). The contribution of CDOM absorption to a_t ? w was lower than 30%. Phytoplankton and NAP were the primary sources of spatial and vertical variability in absorption properties. Light absorption by CDOM, though significant in magnitude, was relatively constant. CDM absorption (a_dg) was dominated by NAP. The spatial variation of the absorption coefficients from each of the optically active constituents were driven by several main inflow rivers in the western and middle part of Lake Chaohu. Algal blooms and bottom resuspension contributed to vertical variability as observed by phytoplankton and NAP profiles. Specific absorption of phytoplankton had significant spatial and seasonal variations without vertical variation. The spectral slope of absorption showed no significant spatial variability (p > 0.05). Variations of absorption affected different ranges of remote sensing reflectance (R_rs) spectrum, thereby increasing the difficulty of applying the remote sensing algorithm in optically complex waters. Parameters and relationships presented in this study provide useful information for bio-optical models and remote sensing of lakes similar to Lake Chaohu in terms of optical properties.     

纳米二氧化钛胶体对脱墨浆中DCS絮聚去除的GC-MS研究

采用GC-MS表征絮聚前后DCS组分变化的方法研究了纳米TiO2胶体对脱墨浆中DCS絮聚去除的机理.结果表明,该脱墨浆中DCS可硅烷化主要组分为树脂酸、脂肪酸、苯二甲酸酯类物质、2,2-双（4-羟苯基）丙烷和甾醇类等物质;纳米Ti O2胶体对上述多数组分有较强的絮聚去除能力,去除机理主要为“桥连絮聚”作用,且去除效果随组分分子极性增大而增强,随分子结构的位阻屏蔽作用增强而减弱.     

基于决策树支持向量机模型的变压器故障诊断法

根据对变压器常见故障原因和危害程度的分析,构造了电力变压器故障诊断决策树。其判定级别为自上而下,而决策树的每一叶都对应着一种具体的故障模式,并选用不同的支持向量机单元模块作为决策树不同分支中的基本分类器,建立组合支持向量机模型,实现了对故障的多分辨识别,该方法提高了故障分析及预测的准确度。应用结果表明该系统模型是富有成效的。     

Leaching of complex sulphide concentrate in acidic cupric chloride solutions

The chemical analysis of a complex sulphide concentrate by emission spectrometry and X-ray diffraction shows that it contains essentially copper, lead, zinc and iron in the form of chalcopyrite, sphalerite and galena. A small amount of pyrite is also present in the ore but does not be detected with X-ray diffraction. The cupric chloride leaching of the sulphide concentrate at various durations and solid/liquid ratios at 100 ℃ shows that the rate of dissolution of the ore is the fastest in the first several hours, and after 12 h it does not evolve significantly. If oxygen is excluded from the aqueous cupric chloride solution during the leaching experiment at 100 ℃, the pyrite in the ore will not be leached. The determination of principal dissolved metals in the leaching liquor by flame atomic absorption spectrometry, and the chemical analysis of solid residues by emission spectrometry and X-ray diffraction allow to conclude that the rate of dissolution of the minerals contained in the complex sulphide concentrate are in the order of galena 〉 sphalerite 〉 chalcopyrite.     

风速对过饱和总溶解气体释放速率的影响

通过不同风速下的过饱和总溶解气体(TDG)室内释放试验,研究风速对过饱和TDG释放过程的影响,并根据已有释放模型对释放系数进行估算,建立了过饱和TDG释放系数与风速的定量关系式。结果表明在8.5~9.5℃条件下,风速较小时,水体中过饱和TDG释放相当缓慢,随着风速的增大,过饱和TDG的释放速率显著增大;在无风工况下,TDG释放系数为0.005 42 h-1;当风速为1.08~11.33 m/s时,TDG释放系数为0.007 09~0.066 68 h-1;相对释放系数为1~12.303,拟合的相对释放系数与风速的定量关系式计算偏差在-11.76%~10.21%之间。     

淮河流域水质污染时空变异特征分析

选取淮河流域的82个水质监测站,对各站点的1986—2005年水质监测数据进行统计分析,探讨了全流域内水体污染物浓度变化的时空变异特征,为淮河流域水污染治理、水环境保护以及生态修复提供依据。采用时间序列法分析水体污染物浓度的时间变化规律,应用Mann-Kendall检验法对流域范围内水体污染物浓度变化趋势进行了分析。研究结果表明,淮河流域水质变化主要受到入河排污量、上游来水量、闸坝调控方式以及气候条件等方面因素的影响。蚌埠站的水体污染物浓度多年变化规律表明,1995年是水体污染物浓度变化的转折点,1995年前水体污染物浓度不断恶化,1995年后水体污染物浓度逐渐好转。DO浓度的年内变化主要受到水温的影响,表现为冬季浓度高于夏季浓度;CODMn浓度同时受到闸坝调控方式以及区域来水量的影响,汛期浓度低于非汛期。从全流域的水体污染物浓度变化规律看,有机污染物浓度呈显著上升趋势的河段主要分布在淮北支流上,说明在20世纪90年代后期,虽然流域进入相对丰水期以及进行了大规模的水污染联防工作,淮河流域水质污染得到了一定程度的改善。但在2000年后,随着流域内入河污水量和污染物排放量的增加,淮河流域的水质污染依然严重。