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1.
Romain Fillières Bouchra Benjelloun-Mlayah Michel Delmas 《Journal of the American Oil Chemists' Society》1995,72(4):427-432
High-performance size-exclusion chromatography (HPSEC) was used to evaluate the influence of different variables affecting
the transesterification of rapeseed oil (RSO) with anhydrous ethanol and sodium ethoxide as catalyst. The effect of temperature,
ethanol/RSO molar ratio, catalyst concentration, and time can be interpreted by observing the variations of the reaction medium
composition. HPSEC has made the quantitation of ethyl esters, mono-, di-, and triglycerides and glycerol possible. The best
results for laboratory-scale reactions were obtained at 80°C with a 6:1 molar ratio of EtOH/RSO and 1% of NaOEt by weight
of RSO. 相似文献
2.
Eddo J. Hoekstra Catherine Simoneau 《Critical reviews in food science and nutrition》2013,53(4):386-402
The release of Bisphenol A (BPA) from polycarbonate baby bottles into food and food simulants is reviewed in the perspective of the current intensive discussions on the risks of this substance. Potential factors that have been reported to influence the release of BPA are reviewed. Unlike most polymers polycarbonate is hydrolyzed under alkaline conditions by scale formation, residual alkaline detergents and boiled water. Data suggest that brushing of the bottle did not raise the release of BPA. Claims that used bottles release more BPA than new bottles and that mineral composition of the aqueous food simulant affect release could not be substantiated. There are indications that aminolysis of polycarbonate by milk and ethanolysis of polycarbonate by 50% ethanol might take place under relevant test conditions.
The relatively few migration data following the test conditions of European food contact material legislation, comply with the specific migration limit. Two test conditions were identified that reflect real use and exposure, and might cause higher release of BPA compared to the test conditions of European food contact material legislation. Further detailed studies are necessary to verify whether these two exposure scenarios are more severe. 相似文献
3.
Hasene Keskin Derya Koçak Yanık Hatice Neval Mucuk Fahrettin Göğüş Sibel Fadıloğlu 《Journal of food science》2016,81(4):C841-C848
2‐Monoacylglycerols (2‐MAG) with a high content of oleic acid at sn‐2 position was synthesized by enzymatic ethanolysis of refined olive pomace oil, which is a byproduct of olive oil processing. Six lipases from different microbial sources were used in the synthesis of 2‐MAG. Immobilized lipase from Candida antarctica gave the highest product yield among the selected lipases. Response surface methodology was applied to optimize reaction conditions; time (4 to 10 h), temperature (45 to 60 °C), enzyme load (10 to 18 wt%), and ethanol:oil molar ratio (30:1 to 60:1). The predicted highest 2‐MAG yield (84.83%) was obtained at 45 °C using 10 (wt%) enzyme load and 50:1 ethanol:oil molar ratio for 5 h reaction time. Experiments to confirm the predicted results at optimum conditions presented a 2‐MAG yield of 82.54%. The purification yield (g 2‐MAG extracted/100 g of total product) was 80.10 and 69.00 for solvent extraction and low‐temperature crystallization, respectively. The purity of the synthesized 2‐MAG was found to be higher than 96%. 相似文献
4.
Pinolenic acid (PLA) concentrate in fatty acid ethyl ester (FAEE) was efficiently produced from pine nut oil via lipase-catalyzed ethanolysis using a recirculating packed bed reactor (RPBR). The effects of reaction temperature, molar ratio, and residence time on the concentration of PLA were explored. Novozym 435 lipase from Candida antarctica showed less selectivity toward PLA esterified at the sn-3 position when temperature was increased from 45 to 55 °C. For the trials of molar ratio between 1: 50 and 1: 100 (pine nut oil to ethanol), there were no significant differences in the yield of PLA. Residence time of substrate in a RPBR affected significantly the PLA content as well as the yield of PLA. Optimal temperature, molar ratio (pine nut oil to ethanol), and residence time for production of PLA concentrate via lipase-catalyzed ethanolysis in a RPBR were 45 °C, 1: 50, and 3 min, respectively. Under these conditions, the maximal PLA content (36.1 mol%) in the concentrate was obtained during the initial 10 min of reaction. 相似文献
5.
Roxana Irimescu Kiyomi Furihata Kazuhiko Hata Yugo Iwasaki Tsuneo Yamane 《Journal of the American Oil Chemists' Society》2001,78(3):285-290
A highly efficient enzymatic method for the synthesis of regioisomerically pure 1,3-dicapryloyl-2-docosahexaenoyl glycerol
(CDC) in two steps was established. 2-Monoglyceride (2-MG) formation by ethanolysis of tridocosahexaenoylglycerol (DDD) with
immobilized Candida antarctica lipase (Novozym 435) as catalyst was the key step of the synthesis. CDC was finally obtained by reesterification of 2-MG
with ethylcaprylate (EtC) catalyzed by Rhizomucor miehei lipase (Lipozyme IM). The regiospecificity of Novozym 435 depended on the type of reaction and the initial composition of
the reaction medium. It displayed strict 1,3-regiospecificity for ethanolysis at a high excess of ethanol in the reaction
mixture although it displayed no regiospecificity in transesterification and esterification reactions. The highest yield of
CDC (85.4%) was obtained by ethanolysis at a 4∶1 weight ratio of ethanol/DDD for 6 h followed by reesterification at a 20∶1
molar ratio of EtC/initial DDD for 1.5 h. The regioisomeric purity of CDC was 100%. Good results were obtained also for the
synthesis of 1,3-dicapryloyl-eicosapentaenoylglycerol (CEC) by the same method: 84.2% yield and 99.8% regioisomeric purity
at the same reactant ratios as above. The yield of the reesterification step and the regioisomeric purity of the product were
influenced by the molar ratio of the reactants for both CDC and CEC syntheses: higher excess of EtC favored higher yields
and regioisomeric purity of the products. 相似文献
6.
Ethanolysis of castor and cottonseed oil: A systematic study using classical catalysts 总被引:1,自引:1,他引:1
Simoni M. Plentz Meneghetti Mario R. Meneghetti Carlos R. Wolf Eid C. Silva Gilvan E. S. Lima Masurquede de A. Coimbra João Inácio Soletti Sandra H. V. Carvalho 《Journal of the American Oil Chemists' Society》2006,83(9):819-822
Several classical catalytic systems for the transesterification reaction have been used to produce FA ethyl esters (FAEE)
from castor and cottonseed oils The effects of the amount and nature of the catalyst, and of the reaction temperature, on
the yields of FAEE were determined. The most efficient transesterification of castor oil was achieved in the presence of methoxide
and acid catalysts, whereas for cottonseed oil, which has a composition that is much more similar to most vegetable oils than
is castor oil, the highest yields of FAEE were obtained following base-catalysed ethanolysis. 相似文献
7.
Lipozyme RMIM催化大豆卵磷脂乙醇解制备溶血卵磷脂 总被引:2,自引:0,他引:2
以大豆卵磷脂为原料,在无溶剂体系中采用Lipozyme RMIM催化大豆卵磷脂乙醇解制备溶血卵磷脂.讨论了底物浓度、加酶量、加水量等因素对醇解反应过程中溶血卵磷脂转化率的影响.确定了合适的反应条件为在30℃下,底物浓度2.00 g/mL,加酶量15%,加水量8%,反应时间32h.经棒状薄层色谱-氢火焰离子化检测器检测可知,在此条件下溶血卵磷脂转化率为92.26%.此外,还定量分析了产物中脂肪酸与脂肪酸乙酯的相对含量,从而判断出反应以醇解为主. 相似文献
8.
Ignacio VieitezMaría J. Pardo Camila da Silva Cristiane BertoldiFernanda de Castilhos J. Vladimir OliveiraMaria A. Grompone Iván Jachmanián 《The Journal of Supercritical Fluids》2011,56(3):271-276
The transesterification of castor oil under supercritical ethanol using a catalyst-free continuous process was investigated. The effect of water concentration on the reaction medium, reaction temperature, pressure, and substrates flow rate were studied. A maximum ester content of 74.2% was achieved when the reactor was operated at 573 K, 20 MPa, substrates flow rate of 0.8 ml min−1, and 5 wt% water concentration in the alcohol. The ester content of the product increased with the operation temperature, but after certain temperature level the converse effect was observed. This adverse effect was attributed to oil degradation, which increased to 88.7% at 648 K (at the flow rate of 0.8 ml min−1). A favorable effect on ester content was observed when the water concentration was increased, unlike the effect of water on the conventional alkali-catalyzed process. 相似文献
9.
以甘油三酯型鱼油为原料,利用天然DHA相对富集于甘油酯2位的特点,以1,3-特异性固定化脂肪酶催化制备Sn-2二十二碳六烯酸甘油单酯(Sn-2 DHA-MAG)。建立了"格氏反应-薄层色谱-高效液相色谱"联用以Sn-2位DHA含量为标准筛选最佳反应原料的方法,随后考察了反应体系,硼酸浓度,反应温度和反应时间等因素以优化反应条件。结果表明,以优选的甘油三酯型鱼油为原料,50 mg/m L硼酸乙醇溶液∶鱼油∶固定化脂肪酶Lipozyme TL IM质量比等于40∶80∶18构建反应体系,在常温下反应4 h,反应产物减压蒸馏后,经硅胶柱层析纯化,所得Sn-2二十二碳六烯酸甘油单酯的纯度达90%以上。 相似文献
10.
Abdelrahman B. Fadhil Islam K. Saeed Liqaa I. Saeed Marwa H. Altamer 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2016,38(19):2883-2890
Fatty acid ethyl ester (FAEE) was developed from chicken waste. A blend of chicken fat and waste chicken oil was used as a feedstock for FAEE preparation via alkali-catalyzed transesterification with ethanol assisted by a co-solvent. Hexane was used as the co-solvent. The influences of alkali catalyst type and concentration, ethanol/blend molar ratio, hexane/ethanol volume ratio, temperature, time, and type of co-solvent on the yield of FAEE were investigated. The best yield of FAEE (96.94%~96.78% w/w ester content) was obtained at 0.75% KOH w/w, 8:1 ethanol/blend molar ratio, 1.5:1 hexane/ethanol volume ratio, 60°C temperature, and 60 min of reaction. The fuel properties of FAEE produced as well as its blends with petro diesel were within the range of those prescribed by ASTM D 6751 standards, indicating its suitability as fuel for combustion engines. It was concluded that the presence of co-solvent increased the yield of FAEE and enhanced its properties compared to FAEE produced via non-solvent processes. The process was found to follow first-order kinetics, and the activation energy was found to be 13.31 kJ/mol. 相似文献