Electron microscopic observations and DNA chain fragmentation studies on apoptosis in bone tumor cells induced by ~(153)Sm-EDTMP

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Gasification reactivity of charcoal with CO2. Part I: Conversion and structural phenomena

The gasification reaction of fir charcoal with CO₂ was studied by isothermal thermogravimetric analysis under kinetic control. The derived reaction rate (r=dX/dt) as a function of the converted carbon mass (X) was compared with random pore model predictions and found to be much higher at elevated conversion levels than predicted by theory. Similar enhanced reaction rate behaviour was evidenced after removing the natural alkali catalyst from the charcoal by acid washing, suggesting that with untreated charcoal the late reaction rate contribution stems from both, catalytic and additional structure effects. Literature attributes the unpredicted late reaction rate behaviour to the disintegration of the porous char particle into small fragments, which, in line with percolation theory predictions, seems to occur only after a critical conversion level has been reached. However, our gasification data reveal a gradual rise in the charcoal reactivity thereafter, suggesting a breaking up (embrittlement) of the solid phase accompanied by the exposure of fresh surface area from fracturing. The original random pore model derivation given by Bhatia and Perlmutter is extended to account also for these peculiarities and the resulting kinetic relation described our reaction rate data well over the entire conversion range.     

An enhanced,acoustic emission-based,single-fiber-composite test

In the single-fiber-composite (SFC) test, a fiber imbedded in a matrix is loaded in tension, resulting in a fragmentation of the fiber. In the conventional version of this test, the final fiber fragmentation length distribution is used with a micro-mechanical model to determine the average fiber/matrix interfacial shear stress. In the enhanced version of this test, one also determines the applied stress at each fiber fracture, and from this, one can evaluate the strength of the fiber at short gage lengths. In our measurement system, we utilize an acoustic emission (AE) technique to detect the fiber fractures and to locate the fiber breaks and so determine both the fiber failure stresses as well as the fiber fragmentation lengths while the test is in progress. Critical to the success of this test is a broadband AE system that utilizes point-like AE sensors, procedures for evaluatingin situ, the wavespeed of the first wave arrival and signal processing techniques for determining the arrival time of this signal as precisely as possible for a broad range of wave shapes. Here we describe the application of such an enhanced SFC test procedure to investigate the failure of a Nicalon fiber in an epoxy matrix.     

中国耕地细碎化的理论解析与研究框架

基于演绎推理法和文献研究法,探索耕地细碎化的概念、过程、机制和效应,并构建耕地细碎化研究框架,为耕地细碎化研究提供理论指导。结果表明:①耕地细碎化是耕地在自然-人为双重因素驱动下,耕地地块在形态上不断分割、变小,耕地产权在主体上不断细分、多元的过程,并分别表现为相互关联又有所区别的耕地景观细碎化和耕地权属细碎化; ②耕地细碎化研究应遵循“诊断-机制-效应-治理”的理论框架,耕地细碎化诊断需从形态和权属两方面构建评价指标体系,形成机制可从自然切割力、利用切割力、设施切割力和管理切割力4个方面揭示不同因素的作用机制,效应需揭示不同尺度下耕地细碎化形态和产权的趋势性转折对经济、社会和生态的影响,治理研究应按照“问题识别治理潜力治理路径保障措施”的逻辑顺序构建。     

The Structure of the Irreversibly Bound Adhesion Promoter-Substrate Interfacial Layer of γ-Aminopropylsilanetriol on Crystalline Si, as Measured by XPS and FTIR

The irreversibly bound interfacial layer deposited by the γ-aminopropysilanetriol adhesion promoter onto a crystalline silicon substrate, which remains even after profuse washing, was found by XPS to have resulted from the fragmentation and rearrangement of the original γ-aminopropylsilanetriol molecule. A mechanism is proposed, involving the homolytic scission of the terminal N-C bond. One of the subsequent reactions is believed to involve hydrogen loss by abstraction and the formation of a terminal vinyl group, which bonds to the substrate. Support for this mechanism is found in IR spectroscopy of this layer.     

Viscoelastic and Processing Effects on the Fiber-Matrix Interphase Strength. Part I. The Effects of Loading Rate, Test Temperature, Fiber Sizing and Global Strain Level

The effects of loading rate, fiber sizing, test temperature and global strain level on the adhesion strength between carbon fibers and a thermosetting epoxy (Epon 815) are studied using the single fiber fragmentation test procedure. Analytical methodology describing the viscoelastic behavior observed is also presented. The possibility of rate-temperature-interphase thickness superposition for the interfacial strength function is illustrated based on the analytical models discussed. Experimental data are discussed using Weibull statistics and also presented in the form of percent relative frequency histograms for the fiber fragments in a collective fashion. The use of histograms allows for interpretation of the skewness in the data population.     

复合岩体的TBM破岩机理数值模拟

为了指导TBM刀盘刀具的研制和不同地质条件下刀盘刀具的选型,TBM破岩机理的研究成为核心。在TBM滚刀的作用下,岩体中裂纹的生成、扩展和连接规律是深刻理解TBM破岩机理的前提,因此,TBM滚刀破岩机理的研究具有重要的工程应用价值。目前,TBM滚刀破岩机理的研究主要集中在单一岩体中,但在TBM施工过程中会遇到各种复杂的地质条件。笔者采用离散元方法,研究了复合岩体的破岩机理,复合岩体中岩片的形成不同于单一岩体,其裂纹的最终连接是由起裂于复合岩体交界面上的微裂纹的扩展,将两滚刀之间的赫兹裂纹连接,最终形成岩片。因此,在一定情况下复合岩体更有利于TBM隧道施工。     

数据库系统应用分片中间件

随着国家电网信息化系统一级部署的陆续实施, 业务数据库的表越来越多, 表中的数据量越来越大. 海量数据的存储与访问对数据库造成了相当大的负载, 数据处理能力和访问能力均遭遇瓶颈. 本文针对国家电网一级部署数据量快速增长的特点, 提出了数据分片中间件UAPDS(UAP DB Sharding). UAPDS以集群、分区、分片三层拆分模式, 通过读写分离、单库分表、多库分表等多种解决方案将数据按照一定的规则切分到不同的库或表中, 有效的缓解了对数据库的压力, 提高了数据访问效率, 在实际应用中取得了较好的效果.     

Google map的数据管理和表现机制的讨论研究

Google作为全球最大的搜索引擎,将GoogleMap加入其服务范围内,它集成了全球不同分辨率的遥感图像。Ajax技术改变了传统的客户端与服务器端进行交互的方式,进一步提高了GoogleMap的友好交互界面,增强了其服务质量。